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India ink (
British English British English is the set of Variety (linguistics), varieties of the English language native to the United Kingdom, especially Great Britain. More narrowly, it can refer specifically to the English language in England, or, more broadly, to ...
: Indian ink; also Chinese ink) is a simple black or coloured ink once widely used for writing and printing and now more commonly used for
drawing Drawing is a Visual arts, visual art that uses an instrument to mark paper or another two-dimensional surface, or a digital representation of such. Traditionally, the instruments used to make a drawing include pencils, crayons, and ink pens, some ...
and outlining, especially when inking
comic book A comic book, comic-magazine, or simply comic is a publication that consists of comics art in the form of sequential juxtaposed panel (comics), panels that represent individual scenes. Panels are often accompanied by descriptive prose and wri ...
s and
comic strip A comic strip is a Comics, sequence of cartoons, arranged in interrelated panels to display brief humor or form a narrative, often Serial (literature), serialized, with text in Speech balloon, balloons and Glossary of comics terminology#Captio ...
s. India ink is also used in medical applications. Compared to other inks, such as the
iron gall ink Iron gall ink (also known as common ink, standard ink, oak gall ink or iron gall nut ink) is a purple-black or brown-black ink made from iron salts and tannic acids from vegetable sources. It was the standard ink formulation used in Europe for t ...
previously common in Europe, India ink is noted for its deep, rich black color. It is commonly applied with a paintbrush (such as an ink brush) or a
dip pen A dip pen is a writing instrument used to apply ink to paper. It usually consists of a metal nib (pen), nib with a central slit that acts as a capillary action, capillary channel like those of fountain pen nibs, mounted in a handle or holder, ofte ...
. In East Asian traditions such as
ink wash painting Ink wash painting ( zh, t=水墨畫, s=水墨画, p=shuǐmòhuà) is a type of Chinese ink brush painting which uses Wash (visual arts), washes of black ink, such as that used in East Asian calligraphy, in different concentrations. It emerged duri ...
and
Chinese calligraphy Chinese calligraphy is the writing of Chinese characters as an art form, combining purely Visual arts, visual art and interpretation of the literary meaning. This type of expression has been widely practiced in China and has been generally held ...
, India ink is commonly used in a solid form called an
inkstick Inksticks () or ink cakes are a type of solid Chinese ink used traditionally in several Chinese and East Asian art forms such as calligraphy and brush painting. Inksticks are made mainly of soot and animal glue, sometimes with incense or medicina ...
.


Composition

Basic India ink is composed of a variety of fine
soot Soot ( ) is a mass of impure carbon particles resulting from the incomplete combustion of hydrocarbons. Soot is considered a hazardous substance with carcinogenic properties. Most broadly, the term includes all the particulate matter produced b ...
, known as ''
lampblack Carbon black (with subtypes acetylene black, channel black, furnace black, lamp black and thermal black) is a material produced by the incomplete combustion of coal tar, vegetable matter, or petroleum products, including fuel oil, fluid catalyt ...
'', combined with water to form a liquid. No binder material is necessary: the
carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
molecules are in
colloidal A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others exten ...
suspension and form a waterproof layer after drying. A binding agent such as
gelatin Gelatin or gelatine () is a translucent, colorless, flavorless food ingredient, commonly derived from collagen taken from animal body parts. It is brittle when dry and rubbery when moist. It may also be referred to as hydrolyzed collagen, coll ...
or, more commonly,
shellac Shellac () is a resin secreted by the female Kerria lacca, lac bug on trees in the forests of India and Thailand. Chemically, it is mainly composed of aleuritic acid, jalaric acid, shellolic acid, and other natural waxes. It is processed and s ...
may be added to make the ink more durable once dried. India ink is commonly sold in bottled form, as well as a solid form as an
inkstick Inksticks () or ink cakes are a type of solid Chinese ink used traditionally in several Chinese and East Asian art forms such as calligraphy and brush painting. Inksticks are made mainly of soot and animal glue, sometimes with incense or medicina ...
(most commonly, a stick), which must be ground and mixed with water before use. If a binder is used, India ink may be waterproof or non-waterproof.


History

Woods and Woods (2000) state that the process of making India ink was known in China as early as the middle of the 3rd millennium BC, in
Neolithic China This is a list of Neolithic cultures of China that have been unearthed by archaeologists. They are sorted in chronological order from earliest to latest and are followed by a schematic visualization of these cultures. It would seem that the defi ...
, whereas Needham (1985) states that inkmaking commenced perhaps as early as 3 millennia ago in China. India ink was first invented in China,Smith, page 23. but the English term ''India(n) ink'' was coined due to their later trade with India.Gottsegen, page 30. A considerable number of
oracle bones Oracle bones are pieces of ox scapula and turtle plastron which were used in pyromancya form of divinationduring the Late Shang period () in ancient China. '' Scapulimancy'' is the specific term if ox scapulae were used for the divination, '' ...
of the late
Shang dynasty The Shang dynasty (), also known as the Yin dynasty (), was a Chinese royal dynasty that ruled in the Yellow River valley during the second millennium BC, traditionally succeeding the Xia dynasty and followed by the Western Zhou d ...
contain incised characters with black pigment from a carbonaceous material identified as ink. Numerous documents written in ink on precious stones as well as bamboo or wooden tablets dating to the Spring and Autumn,
Warring States The Warring States period in Chinese history (221 BC) comprises the final two and a half centuries of the Zhou dynasty (256 BC), which were characterized by frequent warfare, bureaucratic and military reforms, and struggles for gre ...
, and Qin period have been uncovered. A cylindrical artifact made from black ink has been found in Qin tombs, dating back to the 3rd century BC during the Warring States or dynastic period, from
Yunmeng Yunmeng County () is a county in eastern Hubei province, People's Republic of China. It is administered by Xiaogan City and is located just outside Xiaogan's urban area. History During the Spring and Autumn period of Chinese history (770-476 B ...
, Hubei.Needham (1985). Volume 5, part 1, page 238. India ink has been in use in
India India, officially the Republic of India, is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area; the List of countries by population (United Nations), most populous country since ...
since at least the 4th century BC, where it was called masi, an admixture of several substances. Indian documents written in
Kharosthi Kharosthi script (), also known as the Gandhari script (), was an ancient script originally developed in the Gandhara Region of modern-day Pakistan, between the 5th and 3rd century BCE. used primarily by the people of Gandhara alongside vari ...
with this ink have been unearthed in as far as
Xinjiang Xinjiang,; , SASM/GNC romanization, SASM/GNC: Chinese postal romanization, previously romanized as Sinkiang, officially the Xinjiang Uygur Autonomous Region (XUAR), is an Autonomous regions of China, autonomous region of the China, People' ...
,
China China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
. The practice of writing with ink and a sharp-pointed needle in
Tamil Tamil may refer to: People, culture and language * Tamils, an ethno-linguistic group native to India, Sri Lanka, and some other parts of Asia **Sri Lankan Tamils, Tamil people native to Sri Lanka ** Myanmar or Burmese Tamils, Tamil people of Ind ...
and other Dravidian languages was common practice from antiquity in
South India South India, also known as Southern India or Peninsular India, is the southern part of the Deccan Peninsula in India encompassing the states of Andhra Pradesh, Karnataka, Kerala, Tamil Nadu and Telangana as well as the union territories of ...
, and so several ancient
Buddhist Buddhism, also known as Buddhadharma and Dharmavinaya, is an Indian religion and List of philosophies, philosophical tradition based on Pre-sectarian Buddhism, teachings attributed to the Buddha, a wandering teacher who lived in the 6th or ...
and Jain scripts in India were compiled in ink. In India, the carbon black from which India ink is formulated was obtained indigenously by burning bones, tar, pitch, and other substances. The traditional Chinese method of making ink was to grind a mixture of hide glue,
carbon black Carbon black (with subtypes acetylene black, channel black, furnace black, lamp black and thermal black) is a material produced by the incomplete combustion of coal tar, vegetable matter, or petroleum products, including fuel oil, fluid cataly ...
, lampblack, and bone black pigment with a
mortar and pestle A mortar and pestle is a set of two simple tools used to prepare ingredients or substances by compression (physics), crushing and shear force, grinding them into a fine Paste (rheology), paste or powder in the kitchen, laboratory, and pharmacy. ...
, then pour it into a ceramic dish where it could dry. To use the dry mixture, a wet brush would be applied until it rehydrated, or more commonly in East Asian calligraphy, a dry solid ink stick was rubbed against an inkstone with water. Like Chinese black inks, the black inks of the Greeks and Romans were also stored in solid form before being ground and mixed with water for usage.Needham (1985). Volume 5, part 1, page 236. In contrast to Chinese inks that were permanent, these inks could be washed away with water. Pine soot was traditionally favored in Chinese inkmaking.Needham (1985). Volume 5, part 1, page 240-241. Several studies observed that 14th-century Chinese inks are made from very small and uniform pine soot; in fact the inks are even superior in these aspects to modern soot inks. The author
Song Yingxing Song Yingxing (Traditional Chinese: 宋應星; Simplified Chinese: 宋应星; Wade Giles: Sung Ying-Hsing; 1587–1666 AD) was a Chinese scientist and encyclopedist who lived during the late Ming Dynasty (1368–1644). He was the author of '' ...
(–1660) of the Ming dynasty has described the inkmaking process from pine soot in his work ''Tiangong Kaiwu''. From the
Song dynasty The Song dynasty ( ) was an Dynasties of China, imperial dynasty of China that ruled from 960 to 1279. The dynasty was founded by Emperor Taizu of Song, who usurped the throne of the Later Zhou dynasty and went on to conquer the rest of the Fiv ...
onwards, lampblack also became a favored pigment for the manufacturing of black inks. It was made by combustion in lamps with wicks, using animal, vegetable, and mineral oils. In the Chinese record ''
Tiangong Kaiwu The ''Tiangong Kaiwu'' (), or ''The Exploitation of the Works of Nature'' was a Chinese encyclopedia compiled by Song Yingxing. It was published in May 1637 with funding provided by Song's patron Tu Shaokui.Needham, Volume 5, Part 7, 36.Song, xi ...
'', ink of the period was said to be made from lampblack of which a tenth was made from burning tung oil, vegetable oils, or lard, and nine-tenths was made from burning pine wood.Sung, Sun & Sun, pages 285–287. For the first process, more than one ounce (approx. 30 grams) lampblack of fine quality could be produced from a catty (approx. 0.5 kg) of oil. The lampwick used in the making of lampblack was first soaked in the juice of '' Lithospermum officinale'' before burning. A skillful artisan could tend to 200 lamps at once. For the second process, the ink was derived from pine wood from which the resin had been removed. The pine wood was burnt in a rounded chamber made from bamboo with the chamber surfaces and joints pasted with paper and matting in which there were holes for smoke emission. The ground was made from bricks and mud with channels for smoke built in. After a burn of several days, the resulting pine soot was scraped from the chamber after cooling. The last one or two sections delivered soot of the purest quality for the best inks, the middle section delivered mixed-quality soot for ordinary ink, and the first one or two sections delivered low-grade soot. The low-grade soot was further pounded and ground for printing, while the coarser grade was used for black paint. The pine soot was soaked in water to divide the fine particles that float and the coarser particles that sink. The sized lampblack was then mixed with glue after which the final product was hammered. Precious components such as gold dust or musk essence may be added to either types of inks. In 1738, Jean-Baptiste Du Halde described the Chinese manufacturing process for lampblack from oil as: "They put five or six lighted wicks into a vessel full of oil, and lay upon this vessel an iron cover, made in the shape of a funnel, which must be set at a certain distance so as to receive all the smoke. When it has received enough, they take it off, and with a goose feather gently brush the bottom, letting the soot fall upon a dry sheet of strong paper. It is this that makes their fine and shining ink. The best oil also gives a lustre to the black, and by consequence makes the ink more esteemed and dearer. The lampblack which is not fetched off with the feather, and which sticks very fast to the cover, is coarser, and they use it to make an ordinary sort of ink, after they have scraped it off into a dish." The Chinese had used India ink derived from
pine A pine is any conifer tree or shrub in the genus ''Pinus'' () of the family Pinaceae. ''Pinus'' is the sole genus in the subfamily Pinoideae. ''World Flora Online'' accepts 134 species-rank taxa (119 species and 15 nothospecies) of pines as cu ...
soot prior to the 11th century AD, when the polymath official
Shen Kuo Shen Kuo (; 1031–1095) or Shen Gua, courtesy name Cunzhong (存中) and Art name#China, pseudonym Mengqi (now usually given as Mengxi) Weng (夢溪翁),Yao (2003), 544. was a Chinese polymath, scientist, and statesman of the Song dynasty (960 ...
(1031–1095) of the mid
Song dynasty The Song dynasty ( ) was an Dynasties of China, imperial dynasty of China that ruled from 960 to 1279. The dynasty was founded by Emperor Taizu of Song, who usurped the throne of the Later Zhou dynasty and went on to conquer the rest of the Fiv ...
became troubled by
deforestation Deforestation or forest clearance is the removal and destruction of a forest or stand of trees from land that is then converted to non-forest use. Deforestation can involve conversion of forest land to farms, ranches, or urban use. Ab ...
(due to the demands of
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, ca ...
for the
iron industry Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's ...
) and sought to make ink from a source other than pine soot. He believed that
petroleum Petroleum, also known as crude oil or simply oil, is a naturally occurring, yellowish-black liquid chemical mixture found in geological formations, consisting mainly of hydrocarbons. The term ''petroleum'' refers both to naturally occurring un ...
(which the Chinese called 'rock oil') was produced inexhaustibly within the earth and so decided to make an ink from the soot of burning petroleum, which the later pharmacologist Li Shizhen (1518–1593) wrote was as lustrous as
lacquer Lacquer is a type of hard and usually shiny coating or finish applied to materials such as wood or metal. It is most often made from resin extracted from trees and waxes and has been in use since antiquity. Asian lacquerware, which may be c ...
and was superior to pine soot ink. A common ingredient in India ink, called carbon black, has been used by many ancient historical cultures. For example, the ancient Egyptians and Greeks both had their own recipes for "carbon black". One Greek recipe, from 40 to 90 AD, was written, documented and still exists today. The ink from China was often sought after in the rest of the world, including Europe, due to its quality. For instance, in the 17th century, Louis LeComte said of Chinese ink that "it is most excellent; and they have hitherto vainly tried in France to imitate it." In another instance, in 1735, Jean-Baptiste Du Halde wrote that "the Europeans have endeavored to counterfeit this ink, but without success."Needham (1985). Volume 5, part 1, page 237. These qualities were described by Berthold Laufer: "It produces, first of all, a deep and true black; and second, it is permanent, unchangeable in color, and almost indestructible. Chinese written documents may be soaked in water for several weeks without washing out... In documents written as far back as the
Han dynasty The Han dynasty was an Dynasties of China, imperial dynasty of China (202 BC9 AD, 25–220 AD) established by Liu Bang and ruled by the House of Liu. The dynasty was preceded by the short-lived Qin dynasty (221–206 BC ...
... the ink is as bright and well preserved as though it had been applied but yesterday. The same holds good of the productions of the printer's art. Books of the Yuan, Ming, and Ch'ing dynasties have come down to us with paper and type in a perfect state of composition."


Artistic uses

* India ink is used in many common artist pens, such as Pitt Artist pens. * Many artists who use watercolor paint or other liquid mediums use waterproof India ink for their outlining because the ink does not bleed once it is dry. * Some other artists use both black and colored India ink as their choice medium in place of watercolors. The ink is diluted with water to create a wash, and typically done so in a ceramic bowl. The ink is layered like watercolors, but once dry, the ink is waterproof and cannot be blended. * Ink blotting is a form of art in which the artist places a blob of ink on special paper. Using a blower (a hair dryer will also work), the artist blows the ink around the page, then, if desired, will fold the paper in half to get a mirror-image ink blot on either side of the page, creating a symmetrical image. * Some artists who favor using monochromatic color palettes (one color but in different shades), especially grey tones, often use India ink for its ability to be mixed in water for lighter colors as well as its ability to layer colors without bleeding. * Tattoo artists use India ink as a black ink for tattoos.


Non-art use

* In pathology laboratories, India ink is applied to surgically removed tissue specimens to maintain orientation and indicate tumor resection margins. The painted tissue is sprayed with acetic acid, which acts as a mordant, "fixing" the ink so it does not track. This ink is used because it survives tissue processing, during which tissue samples are bathed in alcohol and xylene and then embedded in paraffin wax. When viewed under the microscope, the ink at the tissue edge informs the pathologist of the surgical resection margin or other point of interest. * Microbiologists use India ink to stain a slide containing micro-organisms. The background is stained while the organisms remain clear. This is called a
negative stain In microscopy, negative staining is an established method, often used in diagnostic microscopy, for contrasting a thin specimen with an optically opaque fluid. In this technique, the background is stained, leaving the actual specimen untouched, ...
. India ink, along with other stains, can be used to determine if a cell has a gelatinous capsule. A common application of this procedure in the clinical microbiology laboratory is to confirm the morphology of the encapsulated yeast '' Cryptococcus'' spp. which cause cryptococcal meningitis. * In microscopy, India Ink is used to circle mounted specimens like diatoms or radiolarians for better finding them on the slide. * Medical researchers use India ink to visualize
blood vessel Blood vessels are the tubular structures of a circulatory system that transport blood throughout many Animal, animals’ bodies. Blood vessels transport blood cells, nutrients, and oxygen to most of the Tissue (biology), tissues of a Body (bi ...
s when viewed under a microscope. * When assaying phagocytosis scientists often use India ink because it is easy to see and easy for cells to take up. * Scientists performing
Western blot The western blot (sometimes called the protein immunoblot), or western blotting, is a widely used analytical technique in molecular biology and immunogenetics to detect specific proteins in a sample of tissue homogenate or extract. Besides detect ...
ting may use India ink to visualize
protein Proteins are large biomolecules and macromolecules that comprise one or more long chains of amino acid residue (biochemistry), residues. Proteins perform a vast array of functions within organisms, including Enzyme catalysis, catalysing metab ...
s separated by
electrophoresis Electrophoresis is the motion of charged dispersed particles or dissolved charged molecules relative to a fluid under the influence of a spatially uniform electric field. As a rule, these are zwitterions with a positive or negative net ch ...
and transferred to a
nitrocellulose Nitrocellulose (also known as cellulose nitrate, flash paper, flash cotton, guncotton, pyroxylin and flash string, depending on form) is a highly flammable compound formed by nitrating cellulose through exposure to a mixture of nitric acid and ...
or
polyvinylidene fluoride Polyvinylidene fluoride or polyvinylidene difluoride (PVDF) is a highly non-reactive thermoplastic fluoropolymer produced by the polymerization of vinylidene difluoride. Its chemical formula is (C2H2F2)''n''. PVDF is a specialty plastic use ...
(PVDF) membrane. * In ophthalmology, it was and still is used to some extent in corneal tattooing. * Once dry, its conductive properties make it useful for electrical connections on difficult substrates, such as glass. Although relatively low in conductivity, surfaces can be made suitable for electroplating, low-frequency shielding, or for creating large conductive geometries for high voltage apparatuses. A piece of paper impregnated with India ink serves as a grid leak resistor in some tube radio circuits. * In 2002, NASA patented a process for polishing aluminium mirror surfaces to optical quality, using India ink as the polishing medium.


See also

* Aquadag *
Atramentum Atramentum or atrament, generally means a very black, usually liquid, substance. For example, an octopus may emit a puff of atrament (see cephalopod ink). In ancient Rome, the term ''atramentum'' signified any black colouring substance used for a ...
*
Ink and wash painting Ink wash painting ( zh, t=水墨畫, s=水墨画, p=shuǐmòhuà) is a type of Chinese ink brush painting which uses washes of black ink, such as that used in East Asian calligraphy, in different concentrations. It emerged during the Tang dynas ...
*
Inkstick Inksticks () or ink cakes are a type of solid Chinese ink used traditionally in several Chinese and East Asian art forms such as calligraphy and brush painting. Inksticks are made mainly of soot and animal glue, sometimes with incense or medicina ...
* Pen and ink * Pen painting


References


Citations


Publications

* * Banerji, Sures Chandra (1989). ''A Companion to Sanskrit Literature''. Motilal Banarsidass. . * Deng, Yinke (2005). ''Ancient Chinese Inventions''. Translated by Wang Pingxing. Beijing: China Intercontinental Press. . * Gottsegen, Mark D. (2006). ''The Painter's Handbook: A Complete Reference''. New York: Watson-Guptill Publications. . * Menzies, Nicholas K. (1994). ''Forest and Land Management in Imperial China''. New York:
St. Martin's Press St. Martin's Press is a book publisher headquartered in Manhattan in New York City. It is headquartered in the Equitable Building (New York City), Equitable Building. St. Martin's Press is considered one of the largest English-language publishe ...
, Inc. . * Needham, Joseph (1985). ''Science and Civilization in China: Volume 5, Chemistry and Chemical Technology, Part 1, Paper and Printing''. Cambridge University Press. * Needham, Joseph (1986). ''Science and Civilization in China: Volume 5, Chemistry and Chemical Technology, Part 7, Military Technology; the Gunpowder Epic''. Taipei: Caves Books, Ltd. * Sircar, D.C. (1996). ''Indian epigraphy''. Motilal Banarsidass. . * Sivin, Nathan (1995). ''Science in Ancient China: Researches and Reflections''. Brookfield, Vermont: Variorum, Ashgate Publishing. * Smith, Joseph A. (1992). ''The Pen and Ink Book: Materials and Techniques for Today's Artist''. New York: Watson-Guptill Publications. . * Sung, Ying-hsing; Sun, E-tu Zen; Sun, Shiou-chuan (1997). ''Chinese Technology in the Seventeenth Century: T'ien-kung K'ai-wu''. Mineola:
Dover Publications Dover Publications, also known as Dover Books, is an American book publisher founded in 1941 by Hayward and Blanche Cirker. It primarily reissues books that are out of print from their original publishers. These are often, but not always, book ...
. . * Woods, Michael; Woods, Mary (2000). ''Ancient Communication: Form Grunts to Graffiti''. Minneapolis: Runestone Press; an imprint of Lerner Publishing Group..... * Woeste S.; Demchick, P. (1991). Appl Environ Microbiol. 57(6): 1858–185
ASM.org



External links

* {{Authority control Visual arts materials Chinese inventions Drawing Indian inventions Inks