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Hugo M. Rietveld (7 March 1932 – 16 July 2016) was a Dutch crystallographer who is famous for his publication on the full profile refinement method in powder diffraction, which became later known as the Rietveld refinement method. The method is used for the characterisation of crystalline materials from X-ray powder diffraction data. The Rietveld refinement uses a
least squares The method of least squares is a standard approach in regression analysis to approximate the solution of overdetermined systems (sets of equations in which there are more equations than unknowns) by minimizing the sum of the squares of the res ...
approach to refine a theoretical line profile (calculated from a known or postulated crystal structure) until it matches the measured profile. The introduction of this technique which used the full profile instead of individual reflections was a significant step forward in the diffraction analysis of powder samples.


Biography

Rietveld was born in the Hague. After completing Grammar School in the Netherlands he moved to
Australia Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
and studied physics at the University of Western Australia in Perth. In 1964 he obtained his
PhD PHD or PhD may refer to: * Doctor of Philosophy (PhD), an academic qualification Entertainment * '' PhD: Phantasy Degree'', a Korean comic series * ''Piled Higher and Deeper'', a web comic * Ph.D. (band), a 1980s British group ** Ph.D. (Ph.D. albu ...
degree under Edward Norman Maslen with a thesis entitled "The Structure of p-Diphenylbenzene and Other Compounds", a single crystal neutron and
X-ray diffraction X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles ...
study.
Dorothy Hodgkin Dorothy Mary Crowfoot Hodgkin (née Crowfoot; 12 May 1910 – 29 July 1994) was a Nobel Prize-winning British chemist who advanced the technique of X-ray crystallography to determine the structure of biomolecules, which became essential fo ...
was an external examiner on his thesis. This investigation was the first single crystal neutron diffraction study in
Australia Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
and was conducted at the High Flux Australian Reactor (
HIFAR The High Flux Australian Reactor (HIFAR) was Australia's first nuclear reactor. It was built at the Australian Atomic Energy Commission (later ANSTO) Research Establishment at , Sydney. The reactor was in operation between 1958 and 2007, when i ...
) in the Lucas Heights suburb of
Sydney Sydney ( ) is the capital city of the state of New South Wales, and the most populous city in both Australia and Oceania. Located on Australia's east coast, the metropolis surrounds Sydney Harbour and extends about towards the Blue Mountain ...
. In 1964 he became a research officer at the
Energy Research Centre of the Netherlands The Energy Research Centre of the Netherlands (ECN) is one of the largest energy research institute in Europe and holds a strong international position. With and for the market, ECN develops knowledge and technology that enable a transition to a ...
( Energieonderzoek Centrum Nederland, ECN) in Petten, where he worked together with Bert Loopstra and Bob van Laar on the structure solution and refinement of uranates and other ceramic compounds using neutron powder diffraction. In 1967 he implemented the full profile refinement method in a computer program, which he published in his 1969 citation classic. This innovation, however, was only slowly adopted by the community, and so Rietveld in 1974 chose to become head of the library department at Petten.Obituary Hugo Rietveld (1932–2016), ''
loc. cit. {{Italic title ''Loc. cit.'' (Latin, short for ''loco citato'', meaning "in the place cited") is a footnote or endnote term used to repeat the title and page number for a given work (and author). ''Loc. cit.'' is used in place of ibid. when the ref ...
''
He stayed at ECN until he retired in 1992.


Awards

*
The Royal Swedish Academy of Sciences The Royal Swedish Academy of Sciences ( sv, Kungliga Vetenskapsakademien) is one of the royal academies of Sweden. Founded on 2 June 1739, it is an independent, non-governmental scientific organization that takes special responsibility for prom ...
awarded Hugo M. Rietveld, the Aminoff prize in
Stockholm Stockholm () is the Capital city, capital and List of urban areas in Sweden by population, largest city of Sweden as well as the List of urban areas in the Nordic countries, largest urban area in Scandinavia. Approximately 980,000 people liv ...
, 31 March 1995. * Barrett Award on behalf of the Denver X-ray Conference Organizing Committee in Denver, U.S., 6 August 2003. * The Royal Award of Officer in the
Order of Oranje-Nassau The Order of Orange-Nassau ( nl, Orde van Oranje-Nassau, links=no) is a civil and military Dutch order of chivalry founded on 4 April 1892 by the queen regent, Emma of the Netherlands. The order is a chivalric order open to "everyone who has ...
, for his outstanding contribution to the field of
chemistry Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions ...
.
Alkmaar Alkmaar () is a city and municipality in the Netherlands, located in the province of North Holland, about 30 km north of Amsterdam. Alkmaar is well known for its traditional cheese market. For tourists, it is a popular cultural destination. The ...
, Netherlands, 28 October 2004. * Award for Distinguished Powder Diffractionists, awarded by The European Diffraction Conferences, handed out on 30 August 2010 in
Darmstadt Darmstadt () is a city in the States of Germany, state of Hesse in Germany, located in the southern part of the Frankfurt Rhine Main Area, Rhine-Main-Area (Frankfurt Metropolitan Region). Darmstadt has around 160,000 inhabitants, making it th ...
. * Hans-Kühl-Medal 2010, awarded by Gesellschaft Deutscher Chemiker (GDCh), Fachgruppe Bauchemie, handed out on 7 October 2010 in
Dortmund Dortmund (; Westphalian nds, Düörpm ; la, Tremonia) is the third-largest city in North Rhine-Westphalia after Cologne and Düsseldorf, and the eighth-largest city of Germany, with a population of 588,250 inhabitants as of 2021. It is the la ...
.


Further reading

* Young, R. A. (Ed.). (1993). The Rietveld method (Vol. 6). Oxford. Oxford University Press. * * * *


External links


Personal page


References

{{DEFAULTSORT:Rietveld, Hugo 1932 births 2016 deaths Crystallographers Dutch expatriates in Australia 20th-century Dutch physicists Scientists from The Hague University of Western Australia alumni