Hornfels is the group name for a set of
contact metamorphic
Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of che ...
rocks that have been baked and hardened by the heat of
intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are due to fine grained non-aligned crystals with platy or prismatic
habits
A habit (or wont as a humorous and formal term) is a routine of behavior that is repeated regularly and tends to occur subconsciously. , characteristic of metamorphism at high temperature but without accompanying deformation.
The term is derived from the German word ''Hornfels'', meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern
England
England is a country that is part of the United Kingdom. It shares land borders with Wales to its west and Scotland to its north. The Irish Sea lies northwest and the Celtic Sea to the southwest. It is separated from continental Europe b ...
as
whetstones.
Most hornfels are fine-grained, and while the original rocks (such as
sandstone
Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks.
Most sandstone is composed of quartz or feldspar (both silicates) ...
,
shale
Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
,
slate
Slate is a fine-grained, foliated, homogeneous metamorphic rock derived from an original shale-type sedimentary rock composed of clay or volcanic ash through low-grade regional metamorphism. It is the finest grained foliated metamorphic rock. ...
and
limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
) may have been more or less fissile owing to the presence of bedding or
cleavage planes, this structure is effaced or rendered inoperative in the hornfels. Though many hornfels show vestiges of the original bedding,
they break across this as readily as along it; in fact, they tend to separate into cubical fragments rather than into thin plates. Sheet minerals may be abundant but are aligned at random.
Hornfels most commonly form in the
aureole
An aureola or aureole (diminutive of Latin ''aurea'', "golden") is the radiance of luminous cloud which, in paintings of sacred personages, surrounds the whole figure.
In Romance languages, the noun Aureola is usually more related to the d ...
of
granitic
A granitoid is a generic term for a diverse category of coarse-grained igneous rocks that consist predominantly of quartz, plagioclase, and alkali feldspar. Granitoids range from plagioclase-rich tonalites to alkali-rich syenites and from quart ...
intrusions in the upper or middle crust. Hornfels formed from contact metamorphism by volcanic activity very close to the surface can produce unusual and distinctive minerals.
Changes in composition caused by fluids give off by the magmatic body (
metasomatism
Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is the replacement of one rock by another of different mineralogical and chemical com ...
) sometimes takes place.
The ''hornfels facies'' is the
metamorphic facies
A metamorphic facies is a set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures.Essentials of Geology, 3rd Edition, Stephen Marshak The assemblage is typical of what is formed in conditions corresponding ...
which occupies the lowest pressure portion of the metamorphic pressure-temperature space.
[Blatt and Tracy, p.378-380, 512]
The most common hornfels (the
biotite
Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more alumino ...
hornfels) are dark-brown to black with a somewhat velvety
luster owing to the abundance of small
crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
s of shining black
mica
Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is ...
. The
lime
Lime commonly refers to:
* Lime (fruit), a green citrus fruit
* Lime (material), inorganic materials containing calcium, usually calcium oxide or calcium hydroxide
* Lime (color), a color between yellow and green
Lime may also refer to:
Botany ...
hornfels are often white, yellow, pale-green, brown and other colors. Green and dark-green are the prevalent tints of the hornfels produced by the alteration of
igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...
s.
Although for the most part the constituent grains are too small to be determined by the unaided eye, there are often larger crystals (
porphyroblast
A porphyroblast is a large mineral crystal in a metamorphic rock which has grown within the finer grained matrix. Porphyroblasts are commonly euhedral crystals, but can also be partly to completely irregular in shape.
The most common porphyrobl ...
s) of
cordierite
Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: to . A high-temperatu ...
,
garnet
Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different s ...
or
andalusite
Andalusite is an aluminium nesosilicate mineral with the chemical formula Al2SiO5. This mineral was called andalousite by Delamétehrie, who thought it came from Andalusia, Spain. It soon became clear that it was a locality error, and that the spe ...
scattered through the fine matrix, and these may become very prominent on the
weathered
''Weathered'' is the third studio album by American rock band Creed, released on November 20, 2001. It was the last Creed album to be released until '' Full Circle'' came out in October 2009, with Creed disbanding in June 2004. It is the only Cr ...
faces of the rock.
[Yardley 1989, p.161]
Structure
The structure of the hornfels is very characteristic. Very rarely do any of the minerals show crystalline form, but the small grains fit closely together like the fragments of a mosaic; they are usually of nearly equal dimensions. This has been called pflaster or pavement structure from the resemblance to rough pavement work. Each
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
may also enclose particles of the others; in the
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
, for example, small crystals of
graphite
Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on large ...
, biotite,
iron oxide
Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
s, sillimanite or feldspar may appear in great numbers. Often the whole of the grains are rendered semi-opaque in this way. The minutest crystals may show traces of crystalline outlines; undoubtedly they are of new formation and have originated ''in situ''. This leads us to believe that the whole rock has been
recrystallized at a high temperature and in the solid state so that there was little freedom for the mineral
molecule
A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioch ...
s to build up well-individualized crystals. The regeneration of the rock has been sufficient to efface most of the original structures and to replace the former minerals more-or-less completely by new ones. But crystallization has been hampered by the solid condition of the mass and the new minerals are formless and have been unable to reject impurities, but have grown around them.
Compositions of hornfels
Pelitic
Clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4).
Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...
s, sedimentary slates and shales yield biotite hornfels in which the most conspicuous mineral is biotite mica, the small scales of which are transparent under the microscope and have a dark reddish-brown color and strong
dichroism
In optics, a dichroic material is either one which causes visible light to be split up into distinct beams of different wavelengths (colours) (not to be confused with dispersion), or one in which light rays having different polarizations are abs ...
. There is also quartz, and often a considerable amount of feldspar, while graphite,
tourmaline
Tourmaline ( ) is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is a gemstone and can be found in a wide variety of colors.
The ...
and iron oxides frequently occur in lesser quantity. In these biotite hornfels the minerals, which consist of aluminium silicates, are commonly found; they are usually andalusite and
sillimanite
Sillimanite is an aluminosilicate mineral with the chemical formula Al2SiO5. Sillimanite is named after the American chemist Benjamin Silliman (1779–1864). It was first described in 1824 for an occurrence in Chester, Connecticut.
Occurrence
S ...
, but
kyanite
Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally ...
appears also in hornfels, especially in those that have a
schist
Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes o ...
ose character. The andalusite may be pink and is then often
pleochroic
Pleochroism (from Greek πλέων, ''pléōn'', "more" and χρῶμα, ''khrôma'', "color") is an optical phenomenon in which a substance has different colors when observed at different angles, especially with polarized light.
Backgroun ...
in thin sections, or it may be white with the cross-shaped dark enclosures of the matrix that are characteristic of
chiastolite
Chiastolite ( ) is a variety of the mineral andalusite with the chemical composition Al2SiO5. It is noted for distinctive cross-shaped black inclusions of graphite. The presence of the cross caused this mineral be used as a gem. Chiastolite spe ...
. Sillimanite usually forms exceedingly minute needles embedded in quartz.
In the rocks of this group cordierite also occurs, not rarely, and may have the outlines of imperfect hexagonal prisms that are divided up into six sectors when seen in polarized light. In biotite hornfels, a faint striping may indicate the original bedding of the unaltered rock and corresponds to small changes in the nature of the
sediment
Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand an ...
deposited. More commonly there is a distinct spotting, visible on the surfaces of the hand specimens. The spots are round or elliptical, and may be paler or darker than the rest of the rock.
In some cases they are rich in graphite or carbonaceous matter;
in others they are full of brown mica; some spots consist of rather coarser grains of quartz than occur in the matrix. The frequency with which this feature reappears in the less altered slates and hornfels is rather remarkable, especially as it seems certain that the spots are not always of the same nature or origin. Tourmaline hornfels are found sometimes near the margins of tourmaline granites; they are black with small needles of
schorl
Tourmaline ( ) is a crystalline Silicate mineral, silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is a gemstone and can be found in a wide variety o ...
that under the microscope are dark brown and richly pleochroic. As the tourmaline contains
boron
Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has th ...
, there must have been some permeation of vapors from the granite into the sediments. Rocks of this group are often seen in the Cornish
tin
Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal.
Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, t ...
-mining districts, especially near the lodes.
Carbonate
A second great group of hornfels are the
calc–silicate hornfels that arise from the thermal alteration of impure
limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
. The purer beds
recrystallize as
marble
Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or Dolomite (mineral), dolomite. Marble is typically not Foliation (geology), foliated (layered), although there are exceptions. In geology, the ...
s, but where there has been originally an admixture of
sand
Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a textural class of s ...
or clay lime-bearing silicates are formed, such as
diopside
Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
,
epidote
Epidote is a calcium aluminium iron sorosilicate mineral.
Description
Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in habi ...
,
garnet
Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different s ...
,
sphene
Titanite, or sphene (from the Greek ''sphenos'' (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals in ...
,
vesuvianite
Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. It was first discovered within ...
and
scapolite
The scapolites (Gr. σκάπος, rod, and λίθος, stone) are a group of rock-forming silicate minerals composed of aluminium, calcium, and sodium silicate with chlorine, carbonate and sulfate. The two endmembers are meionite () and marialit ...
; with these
phlogopite
Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica.
Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3O ...
, various feldspars,
pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic Luster (mineralogy), lust ...
s, quartz and
actinolite
Actinolite is an amphibole silicate mineral with the chemical formula .
Etymology
The name ''actinolite'' is derived from the Greek word ''aktis'' (), meaning "beam" or "ray", because of the mineral's fibrous nature.
Mineralogy
Actinolite is ...
often occur. These rocks are fine-grained, and though often banded, are tough and much harder than the original limestones. They are excessively variable in their mineralogical composition, and very often alternate in thin seams with biotite hornfels and indurated
quartzite
Quartzite is a hard, non- foliated metamorphic rock which was originally pure quartz sandstone.Essentials of Geology, 3rd Edition, Stephen Marshak, p 182 Sandstone is converted into quartzite through heating and pressure usually related to tect ...
s. When perfused with boric and fluoric vapors from the granite they may contain much
axinite
Axinite is a brown to violet-brown, or reddish-brown bladed group of minerals composed of calcium aluminium boro-silicate, . Axinite is pyroelectric and piezoelectric.
The axinite group includes:
*Axinite-(Fe) or ferroaxinite, Ca2Fe2+Al2BOSi4O15( ...
,
fluorite
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.
The Mohs sca ...
and
datolite
Datolite is a calcium boron hydroxide nesosilicate, Ca B Si O4(O H). It was first observed by Jens Esmark in 1806, and named by him from δατεῖσθαι, "to divide," and λίθος, "stone," in allusion to the granular structure
of the massi ...
, but the altiminous silicates are absent from these rocks.
Mafic
From
diabase
Diabase (), also called dolerite () or microgabbro,
is a mafic, holocrystalline, subvolcanic rock equivalent to volcanic basalt or plutonic gabbro. Diabase dikes and sills are typically shallow intrusive bodies and often exhibit fine-graine ...
s,
basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
s,
andesite
Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predomi ...
s and other igneous rocks a third type of hornfels is produced. They consist essentially of feldspar with hornblende (generally of brown color) and pale pyroxene. Sphene, biotite and iron oxides are the other common constituents, but these rocks show much variety of composition and structure. Where the original mass was decomposed and contained calcite,
zeolite
Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These pos ...
s,
chlorite
The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous ac ...
and other secondary minerals either in veins or in cavities, there are usually rounded areas or irregular streaks containing a suite of new minerals, which may resemble those of the calcium-silicate hornfelses above described. The original
porphyritic
Porphyritic is an adjective used in geology to describe igneous rocks with a distinct difference in the size of mineral crystals, with the larger crystals known as phenocrysts. Both extrusive and intrusive rocks can be porphyritic, meaning all ...
, fluidal, vesicular or fragmental structures of the igneous rock are clearly visible in the less advanced stages of hornfelsing, but become less evident as the alteration progresses.
In some districts hornfelsed rocks occur that have acquired a schistose structure through shearing, and these form transitions to schists and
gneiss
Gneiss ( ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. Gneiss forms at higher temperatures an ...
es that contain the same minerals as the hornfels, but have a schistose instead of a hornfels structure. Among these may be mentioned cordierite and sillimanite gneisses, andalusite and kyanite mica-schists, and those schistose calcite-silicate rocks that are known as
cipolins. That these are sediments that have undergone thermal alteration is generally admitted, but the exact conditions under which they were formed are not always clear. The essential features of hornfelsing are ascribed to the action of heat,
pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and e ...
and permeating vapors, regenerating a rock mass without the production of fusion (at least on a large scale). It has been argued, however, that often there is extensive chemical change owing to the introduction of matter from the granite into the rocks surrounding it. The formation of new feldspar in the hornfelses is pointed out as evidence of this. While this felspathization may have occurred in a few localities, it seems conspicuously absent from others. Most authorities at the present time regard the changes as being purely of a physical and not of a chemical nature.
Hornfels metamorphic facies
The hornfels facies occupies the portion of the metamorphic pressure-temperature space of lowest pressure and low to high temperature. It is subdivided into a low-temperature regime of
albite
Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate. I ...
-
epidote
Epidote is a calcium aluminium iron sorosilicate mineral.
Description
Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in habi ...
hornfels, a medium-temperature regime of
hornblende
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks ...
hornfels, a high-temperature regime of
pyroxene
The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
hornfels, and an ultra-high-temperature sanidinite regime. The latter is sometimes regarded as a separate facies. Maximum pressures are around 2 kbar and temperatures are around 300-500 C for the albite-epidote hornfels facies, 500-650 C for the hornblende hornfels facies, 650-800 C for the pyroxene hornfels facies, and above 800 C for the sanidinite facies.
The actual minerals present in each facies depends on the composition of the
protolith
A protolith () is the original, unmetamorphosed rock from which a given metamorphic rock is formed.
For example, the protolith of a slate is a shale or mudstone. Metamorphic rocks can be derived from any other kind of non-metamorphic rock and thu ...
. For a mafic protolith, the albite-epidote hornfels facies is characterized by albite and epidote or
zoisite
Zoisite, first known as saualpite, after its type locality, is a calcium aluminium hydroxy sorosilicate belonging to the epidote group of minerals. Its chemical formula is Ca2 Al3( Si O4)(Si2O7)O(O H).
Zoisite occurs as prismatic, orthorhombi ...
with minor
actinolite
Actinolite is an amphibole silicate mineral with the chemical formula .
Etymology
The name ''actinolite'' is derived from the Greek word ''aktis'' (), meaning "beam" or "ray", because of the mineral's fibrous nature.
Mineralogy
Actinolite is ...
and
chlorite
The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous ac ...
. This gives way to hornblende,
plagioclase
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more prope ...
, pyroxene, and
garnet
Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different s ...
in the hornblende hornfels facies, which in turn gives way to
orthopyroxene
The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
,
augite
Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.
Characteristics
Augite is a solid solution in the pyroxene group. ...
, plagioclase, and characteristic trace garnet in the pyroxene hornfels facies and sanidinite facies, the latter two being indistinguishable for this composition of protolith.
For an ultramafic protolith, the albite-epidote facies is characterized by
serpentine,
talc
Talc, or talcum, is a Clay minerals, clay mineral, composed of hydrated magnesium silicate with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thi ...
,
tremolite
Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and ferro ...
, and chlorite, giving way to
forsterite
Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthor ...
, orthopyroxene, hornblende, chlorite, and characteristic minor aluminum
spinel
Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals.
Properties
S ...
and
magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With the ...
in the hornblende facies, which in turn gives way to forsterite, orthopyroxene, augite, plagioclase, and aluminum spinel in the pyroxene hornfels facies. The sanidinite facies for this composition differs from the pyroxene hornfels facies only in the disappearance of aluminum spinel.
For a pelitic protolith, the sequence is
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
, plagioclase,
muscovite
Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavage ...
, chlorite, and
cordierite
Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: to . A high-temperatu ...
in the albite-epidote facies; quartz, plagioclase, muscovite, biotite, cordierite, and
andalusite
Andalusite is an aluminium nesosilicate mineral with the chemical formula Al2SiO5. This mineral was called andalousite by Delamétehrie, who thought it came from Andalusia, Spain. It soon became clear that it was a locality error, and that the spe ...
in the hornblende hornfels facies; and quartz, plagioclase, orthoclase, andalusite,
sillimanite
Sillimanite is an aluminosilicate mineral with the chemical formula Al2SiO5. Sillimanite is named after the American chemist Benjamin Silliman (1779–1864). It was first described in 1824 for an occurrence in Chester, Connecticut.
Occurrence
S ...
, cordierite, and orthopyroxene in the pyroxene hornfels facies. The sanidinite facies features quartz, plagioclase, sillimanite, cordierite, orthopyroxene,
sapphirine
Sapphirine is a rare mineral, a silicate of magnesium and aluminium with the chemical formula ( (with iron as a major impurity). Named for its sapphire-like colour, sapphirine is primarily of interest to researchers and collectors: well-formed c ...
, and aluminum spinel.
For a calcareous protolith, the sequence is
calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
,
dolomite Dolomite may refer to:
*Dolomite (mineral), a carbonate mineral
*Dolomite (rock), also known as dolostone, a sedimentary carbonate rock
*Dolomite, Alabama, United States, an unincorporated community
*Dolomite, California, United States, an unincor ...
, quartz, tremolite, talc, and forsterite for the albite-epidote hornfels facies; calcite, dolomite, quartz, tremolite,
diopside
Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
, and forsterite for the hornblende hornfels facies; calcite, quartz, diposide, forsterite, and
wollastonite
Wollastonite is a calcium inosilicate mineral ( Ca Si O3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature a ...
for the pyroxene hornfels facies; and calcite, quartz, diopside, forsterite, wollastonite,
monticellite
Monticellite and kirschsteinite (commonly also spelled kirschteinite Klein and Hurlbut ''Manual of Mineralogy'' 20th ed., p. 373) are gray silicate minerals of the olivine group with compositions Ca Mg Si O4 and Ca FeSiO4, respectively. Most mon ...
, and
akermanite for the sanidinite facies.
Acoustic properties
Hornfels have the ability to resonate when struck. Michael Tellinger had described these stones in
South Africa
South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring countri ...
also known as "ring-stones" due to their ability to ring like a bell. The
Musical Stones of Skiddaw The Musical Stones of Skiddaw are a number of lithophones built across two centuries around the town of Keswick, northern England, using hornfels, a stone from the nearby Skiddaw mountain, which is said to have a superior tone and longer ring than ...
are an example of a
lithophone
A lithophone is a musical instrument consisting of a rock or pieces of rock which are struck to produce musical notes. Notes may be sounded in combination (producing harmony) or in succession (melody). It is an idiophone comparable to instrumen ...
made from hornfels.
See also
*
References
External links
{{commons category inline, Hornfels
Metamorphic rocks