Holmium Sesquisulfide
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Holmium(III) sulfide is the
sulfide Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...
of holmium, with the chemical formula of . Like other rare earth sulfides, it is used as a high-performance inorganic pigment.


Preparation

Holmium(III) sulfide can be obtained by the reaction of holmium(III) oxide and
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The unde ...
at 1325 °C. :


Properties

Holmium(III) sulfide has orange-yellow crystals in the monoclinic crystal system, with the space group ''P''21/''m'' (No. 11). Under high pressure, holmium(III) sulfide can form in the
cubic Cubic may refer to: Science and mathematics * Cube (algebra), "cubic" measurement * Cube, a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex ** Cubic crystal system, a crystal system w ...
and
orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a r ...
crystal systems.


References

{{inorganic-compound-stub Holmium compounds Sesquisulfides