Hindered amine light stabilizers (HALS) are chemical compounds containing an
amine
In chemistry, amines (, ) are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (), wherein one or more hydrogen atoms have been replaced by a substituen ...
functional group
In organic chemistry, a functional group is a substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the rest ...
that are used as
stabilizers in plastics and polymers. These compounds are typically derivatives of
tetramethylpiperidine and are primarily used to protect the polymers from the effects of
photo-oxidation
In polymer chemistry photo-oxidation (sometimes: oxidative photodegradation) is the degradation of a polymer surface due to the combined action of light and oxygen. It is the most significant factor in the weathering of plastics. Photo-oxidatio ...
; as opposed to other forms of
polymer degradation
Polymer degradation is the reduction in the physical properties of a polymer, such as strength, caused by changes in its chemical composition. Polymers and particularly plastics are subject to degradation at all stages of their product life cycle ...
such as
ozonolysis
In organic chemistry, ozonolysis is an organic reaction where the unsaturated bonds of alkenes (), alkynes (), or azo compounds () are cleaved with ozone (). Alkenes and alkynes form organic compounds in which the multiple carbon–carbon b ...
.
They are also increasingly being used as thermal stabilizers, particularly for low and moderate level of heat, however during the high temperature processing of polymers (e.g.
injection moulding
Injection moulding (U.S. spelling: injection molding) is a manufacturing process for producing parts by injecting molten material into a mould, or mold. Injection moulding can be performed with a host of materials mainly including metals (for ...
) they remain less effective than traditional phenolic antioxidants.
Mechanism of action
HALS do not absorb UV radiation, but act to inhibit degradation of the polymer by continuously and cyclically removing
free radical
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s that are produced by photo-oxidation of the polymer. The overall process is sometimes referred to as the Denisov cycle, after Evguenii T. Denisov and is exceedingly complex. Broadly, HALS react with the initial polymer peroxy radical (ROO•) and alkyl polymer radicals (R•) formed by the reaction of the polymer and oxygen, preventing further radical oxidation. By these reactions HALS are oxidised to their corresponding
aminoxyl radical
Aminoxyl denotes a Radical (chemistry), radical functional group with general structure R2N–O•. It is commonly known as a nitroxyl radical or a nitroxide, however IUPAC discourages the use of these terms, as they erroneously suggest the presenc ...
s (R
2NO• c.f.
TEMPO
In musical terminology, tempo (Italian, 'time'; plural ''tempos'', or ''tempi'' from the Italian plural) is the speed or pace of a given piece. In classical music, tempo is typically indicated with an instruction at the start of a piece (often ...
), however they are able to return to their initial amine form via a series of additional radical reactions. HALS's high efficiency and longevity are due to this cyclic process wherein the HALS are regenerated rather than consumed during the stabilization process.
![UV-Stabilisator-Nitroxyradikal](https://upload.wikimedia.org/wikipedia/commons/3/36/UV-Stabilisator-Nitroxyradikal.png)
The structure of the HALS makes them resistant to side reactions. The use of a hindered amine possessing no alpha-hydrogens prevents the HALS being converted into a
nitrone species and piperidines are resistant to intramolecular
Cope reaction
The Cope reaction or Cope elimination, developed by Arthur C. Cope, is an elimination reaction of the N-oxide to form an alkene and a hydroxylamine.
Mechanism and applications
The reaction mechanism involves an intramolecular 5-membered cyclic t ...
s.
In commercial HALS the reactive piperidine group is usually bonded to bulky chemical scaffold, in order to reduce its volatility during the melt processing of plastic.
Application
Even though HALS are extremely effective in
polyolefin
A polyolefin is a type of polymer with the general formula (CH2CHR)n where R is an alkyl group. They are usually derived from a small set of simple olefins (alkenes). Dominant in a commercial sense are polyethylene and polypropylene. More speciali ...
s,
polyethylene
Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging ( plastic bags, plastic films, geomembranes and containers including bo ...
and
polyurethane
Polyurethane (; often abbreviated PUR and PU) refers to a class of polymers composed of organic chemistry, organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethan ...
, they are ineffective in
polyvinyl chloride (PVC). It is thought that their ability to form nitroxyl radicals is disrupted due them being readily protonated by
HCl HCL may refer to:
Science and medicine
* Hairy cell leukemia, an uncommon and slowly progressing B cell leukemia
* Harvard Cyclotron Laboratory, from 1961 to 2002, a proton accelerator used for research and development
* Hollow-cathode lamp, a spe ...
released by
dehydrohalogenation
In chemistry, dehydrohalogenation is an elimination reaction which removes a hydrogen halide from a substrate. The reaction is usually associated with the synthesis of alkenes, but it has wider applications.
Dehydrohalogenation from alkyl halid ...
of PVC.
References
{{Reflist
Amines
Plastics additives