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Hexamolybdenum is a
molybdenum Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with lea ...
dominant
alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, ...
discovered during a nanomineralogy investigation of the
Allende meteorite The Allende meteorite is the largest carbonaceous chondrite ever found on Earth. The fireball was witnessed at 01:05 on February 8, 1969, falling over the Mexican state of Chihuahua. After it broke up in the atmosphere, an extensive search for ...
. Hexamolybdenum was discovered in a small ultra
refractory In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, ...
inclusion Inclusion or Include may refer to: Sociology * Social inclusion, aims to create an environment that supports equal opportunity for individuals and groups that form a society. ** Inclusion (disability rights), promotion of people with disabiliti ...
within the Allende meteorite. This inclusion has been named ACM-1. Hexamolybdenum is
hexagonal In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°. Regular hexagon A '' regular hexagon'' has ...
, with a calculated
density Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...
of 11.90 g/cm3. The new mineral was found along with
allendeite Allendeite, Sc4Zr3O12, is an oxide mineral. Allendeite was discovered in a small ultrarefractory inclusion within the Allende meteorite. This inclusion has been named ACM-1. It is one of several scandium rich minerals that have been found in me ...
. These minerals, are believed to demonstrate conditions during the early stages of the
Solar System The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar S ...
, as is the case with many CV3
carbonaceous chondrites Carbonaceous chondrites or C chondrites are a class of chondritic meteorites comprising at least 8 known groups and many ungrouped meteorites. They include some of the most primitive known meteorites. The C chondrites represent only a small propo ...
such as the Allende meteorite. Hexamolybdenum lies on a continuum of high-temperature alloys that are found in meteorites and allows a link between
osmium Osmium (from Greek grc, ὀσμή, osme, smell, label=none) is a chemical element with the symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition metal in the platinum group that is found as a trace element in alloys, mos ...
,
ruthenium Ruthenium is a chemical element with the Symbol (chemistry), symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is inert to ...
, and
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
rich meteoritic alloys. The name hexamolybdenum refers to the
crystal symmetry In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns th ...
(primitive hexagonal) and the molybdenum rich composition. The Allende meteorite fell in 1969 near Pueblito de Allende,
Chihuahua Chihuahua may refer to: Places *Chihuahua (state), a Mexican state **Chihuahua (dog), a breed of dog named after the state **Chihuahua cheese, a type of cheese originating in the state **Chihuahua City, the capital city of the state **Chihuahua Mun ...
,
Mexico Mexico (Spanish: México), officially the United Mexican States, is a country in the southern portion of North America. It is bordered to the north by the United States; to the south and west by the Pacific Ocean; to the southeast by Guatema ...
.


Occurrence

Hexamolybdenum was found as nano-crystals in an ultrarefractory inclusion in the Allende meteorite. The Allende meteorite has shown to be full of new minerals, after nearly forty years it has produced one in ten of the now known minerals in meteorites. This CV3
carbonaceous chondrite Carbonaceous chondrites or C chondrites are a class of chondritic meteorites comprising at least 8 known groups and many ungrouped meteorites. They include some of the most primitive known meteorites. The C chondrites represent only a small prop ...
was the largest ever recovered on earth and is referred to as the best-studied meteorite in history. The inclusion has only been viewed via
electron microscopy An electron microscope is a microscope that uses a beam of accelerated electrons as a source of illumination. As the wavelength of an electron can be up to 100,000 times shorter than that of visible light photons, electron microscopes have a hi ...
. The hexamolybdenum specimen was lost during an attempted ion probe analysis of a bordering grain. Other specimens can be found, however, in the Smithsonian Institution's National Museum of Natural History Allende section USNM 3509HC12 and in section USNM 7590 of NWA 1934, another VC3 chondrite. It has also been reported from the NWA 1934 CV3 carbonaceous chondrite meteorite from the
Erfoud Erfoud ( ber, ⴰⵔⴼⵓⴷ, Latn, ber, Arfud; ar, أرفود) is an oasis town in the Sahara Desert, in the Drâa-Tafilalet region, eastern Morocco. It is divided into several districts: Hay Salam, Hay Jdid, Hay Ziz, Hay el Bathaa, Hay Annah ...
region of
Morocco Morocco (),, ) officially the Kingdom of Morocco, is the westernmost country in the Maghreb region of North Africa. It overlooks the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to ...
and in the Danubian placer of
Straubing Straubing () is an independent city in Lower Bavaria, southern Germany. It is seat of the district of Straubing-Bogen. Annually in August the Gäubodenvolksfest, the second largest fair in Bavaria, is held. The city is located on the Danube form ...
,
Bavaria Bavaria ( ; ), officially the Free State of Bavaria (german: Freistaat Bayern, link=no ), is a state in the south-east of Germany. With an area of , Bavaria is the largest German state by land area, comprising roughly a fifth of the total lan ...
.


Chemical composition

Hexamolybdenum is an (molybdenum,
ruthenium Ruthenium is a chemical element with the Symbol (chemistry), symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is inert to ...
,
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
,
iridium Iridium is a chemical element with the symbol Ir and atomic number 77. A very hard, brittle, silvery-white transition metal of the platinum group, it is considered the second-densest naturally occurring metal (after osmium) with a density of ...
,
osmium Osmium (from Greek grc, ὀσμή, osme, smell, label=none) is a chemical element with the symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition metal in the platinum group that is found as a trace element in alloys, mos ...
) alloy.


Appearance

Color Color (American English) or colour (British English) is the visual perceptual property deriving from the spectrum of light interacting with the photoreceptor cells of the eyes. Color categories and physical specifications of color are associ ...
, streak, luster,
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
, tenacity, cleavage,
fracture Fracture is the separation of an object or material into two or more pieces under the action of stress. The fracture of a solid usually occurs due to the development of certain displacement discontinuity surfaces within the solid. If a displa ...
,
density Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...
, and
refractive index In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, or ...
could not be observed because the grain size was too small and the section bearing the mineral was optically thick.


See also

*
Classification of minerals The classification of minerals is a process of determining to which of several groups minerals belong based on their chemical characteristics. Since the 1950s, this classification has been carried out by the International Mineralogical Association, ...
*
List of minerals This is a list of minerals for which there are articles on Wikipedia. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a m ...


References

{{Reflist, 30em Natural materials Hexagonal minerals Minerals in space group 194 Native element minerals Molybdenum minerals