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Heulandite is the name of a series of tecto-silicate
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
s of the
zeolite Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These pos ...
group. Prior to 1997, heulandite was recognized as a mineral species, but a reclassification in 1997 by the
International Mineralogical Association Founded in 1958, the International Mineralogical Association (IMA) is an international group of 40 national societies. The goal is to promote the science of mineralogy and to standardize the nomenclature of the 5000 plus known mineral species. Th ...
changed it to a series name, with the mineral species being named: * Heulandite-Ca * Heulandite-Na * Heulandite-K * Heulandite-Sr * Heulandite-Ba (described in 2002). Heulandite-Ca, the most common of these, is a hydrous calcium and
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
silicate In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
, . Small amounts of
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
and
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosphe ...
are usually present replacing part of the calcium.
Strontium Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is ex ...
replaces calcium in the heulandite-Sr variety. The appropriate species name depends on the dominant element. The species are visually indistinguishable, and the series name heulandite is still used whenever testing has not been performed.


Crystallography and properties

Crystals are
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...
. They may have a characteristic coffin-shaped habit, but may also form simple rhombic prisms. Frequently, a crust of fine crystals will form with only the ends of the rhombs visible, making the crystals look like wedges. They have a perfect cleavage parallel to the plane of symmetry, on which the lustre is markedly pearly; on other faces the lustre is of the vitreous type. The mineral is usually colourless or white, but may be orange, brown, yellow, brick-red, or green due to
inclusion Inclusion or Include may refer to: Sociology * Social inclusion, aims to create an environment that supports equal opportunity for individuals and groups that form a society. ** Inclusion (disability rights), promotion of people with disabilitie ...
s of
celadonite Celadonite is a mica group mineral, a phyllosilicate of potassium, iron in both oxidation states, aluminium and hydroxide with formula . It crystallizes in the monoclinic system and usually forms massive aggregates of prismatic crystallites or in ...
. It varies from transparent to translucent. Isomorphous with heulandite is the
strontium Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is ex ...
and
barium Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...
zeolite
brewsterite Brewsterite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, brewsterite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a ser ...
. The Mohs hardness is 3-4, and the specific gravity 2.2. Heulandite is similar to stilbite. The two minerals may, however, be readily distinguished by the fact that in heulandite the acute positive bisectrix of the optic axes emerges perpendicular to the cleavage.


Discovery and occurrence

Heulandite was first separated from stilbite by
August Breithaupt Johann Friedrich August Breithaupt (May 16, 1791 – September 22, 1873) was a German mineralogist and professor at Freiberg Mining Academy in Freiberg, Saxony. Biography He was born in Probstzella. He received his doctorate at the Universities ...
in 1818, and named by him "euzeolite" (meaning beautiful zeolite); independently, in 1822, H. J. Brooke arrived at the same result, giving the name heulandite, after the mineral collector,
John Henry Heuland John Henry Heuland (March 21, 1778 Bayreuth – November 16, 1856 Hastings) was a German born (Johann Heinrich) English mineralogist and dealer. He was a Fellow of the Geological Society of London. His collection is held by the Natural History Mu ...
(1778–1856). Heulandite occurs with stilbite and other zeolites in the amygdaloidal cavities of
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
ic volcanic rocks, and occasionally in
gneiss Gneiss ( ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. Gneiss forms at higher temperatures an ...
and hydrothermal veins. It forms at temperatures below about , and so its presence in
sedimentary rocks Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles t ...
indicates that these have experienced shallow diagenesis. Good specimens have been found in the basalts of
Berufjörður Berufjörður () is a fjord in Eastern Iceland. It is about long and wide. The village Djúpivogur (pop. 456) is located on its western shores. Mt. Búlandstindur which is above sea level is located west of the fjord. Route 1 passes on its s ...
, near
Djúpivogur Djúpivogur () is a small town and municipality (Djúpavogshreppur ) located on a peninsula in the Austurland region in eastern Iceland, near the island of Papey and on the fjord Berufjörður. The municipality was formed by the merger of rural c ...
, in
Iceland Iceland ( is, Ísland; ) is a Nordic island country in the North Atlantic Ocean and in the Arctic Ocean. Iceland is the most sparsely populated country in Europe. Iceland's capital and largest city is Reykjavík, which (along with its s ...
, the
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and the
Deccan Traps The Deccan Traps is a large igneous province of west-central India (17–24°N, 73–74°E). It is one of the largest volcanic features on Earth, taking the form of a large shield volcano. It consists of numerous layers of solidified flood ...
of the Sahyadri Mountains of
Maharashtra Maharashtra (; , abbr. MH or Maha) is a states and union territories of India, state in the western India, western peninsular region of India occupying a substantial portion of the Deccan Plateau. Maharashtra is the List of states and union te ...
near
Mumbai Mumbai (, ; also known as Bombay — the official name until 1995) is the capital city of the Indian state of Maharashtra and the ''de facto'' financial centre of India. According to the United Nations, as of 2018, Mumbai is the second- ...
. Crystals of a brick-red colour are from Campsie Fells in Stirlingshire and the Fassa valley in
Trentino Trentino ( lld, Trentin), officially the Autonomous Province of Trento, is an autonomous province of Italy, in the country's far north. The Trentino and South Tyrol constitute the region of Trentino-Alto Adige/Südtirol, an autonomous region ...
. A variety known as beaumontite occurs as small yellow crystals on syenitic
schist Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes o ...
near
Baltimore Baltimore ( , locally: or ) is the List of municipalities in Maryland, most populous city in the U.S. state of Maryland, fourth most populous city in the Mid-Atlantic (United States), Mid-Atlantic, and List of United States cities by popula ...
,
Maryland Maryland ( ) is a state in the Mid-Atlantic region of the United States. It shares borders with Virginia, West Virginia, and the District of Columbia to its south and west; Pennsylvania to its north; and Delaware and the Atlantic Ocean to ...
.


Notes


References


Mineral GalleriesIMA Zeolite Classification
;Attribution *


External links

{{Commons, Heulandite
Structure type HEU
Tectosilicates Sodium minerals Calcium minerals Aluminium minerals Zeolites Monoclinic minerals Minerals in space group 12 Luminescent minerals