HOME

TheInfoList



OR:

In fluid thermodynamics, a heat transfer fluid is a
gas Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...
or liquid that takes part in
heat transfer Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, ...
by serving as an intermediary in
cooling Cooling is removal of heat, usually resulting in a lower temperature and/or phase change. Temperature lowering achieved by any other means may also be called cooling.ASHRAE Terminology, https://www.ashrae.org/technical-resources/free-resources/as ...
on one side of a
process A process is a series or set of activities that interact to produce a result; it may occur once-only or be recurrent or periodic. Things called a process include: Business and management *Business process, activities that produce a specific se ...
, transporting and storing
thermal energy The term "thermal energy" is used loosely in various contexts in physics and engineering. It can refer to several different well-defined physical concepts. These include the internal energy or enthalpy of a body of matter and radiation; heat, de ...
, and heating on another side of a process. Heat transfer fluids are used in countless applications and industrial processes requiring heating or cooling, typically in a closed circuit and in continuous cycles. Cooling water, for instance, cools an engine, while heating water in a
hydronic Hydronics () is the use of liquid water or gaseous water (steam) or a water solution (usually glycol with water) as heat-transfer medium in heating and cooling systems. The name differentiates such systems from oil and refrigerant systems. H ...
heating system heats the radiator in a room. Water is the most common heat transfer fluid because of its economy, high
heat capacity Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat to be supplied to an object to produce a unit change in its temperature. The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity ...
and favorable transport properties. However, the useful temperature range is restricted by
freezing Freezing is a phase transition where a liquid turns into a solid when its temperature is lowered below its freezing point. In accordance with the internationally established definition, freezing means the solidification phase change of a liquid ...
below 0 °C and boiling at elevated temperatures depending on the system
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and e ...
.
Antifreeze An antifreeze is an additive which lowers the freezing point of a water-based liquid. An antifreeze mixture is used to achieve freezing-point depression for cold environments. Common antifreezes also increase the boiling point of the liquid, all ...
additives can alleviate the freezing problem to some extent. However, many other heat transfer fluids have been developed and used in a huge variety of applications. For higher temperatures,
oil An oil is any nonpolar chemical substance that is composed primarily of hydrocarbons and is hydrophobic (does not mix with water) & lipophilic (mixes with other oils). Oils are usually flammable and surface active. Most oils are unsaturated ...
or synthetic
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
- or silicone-based fluids offer lower
vapor pressure Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phas ...
.
Molten salt Molten salt is salt which is solid at standard temperature and pressure but enters the liquid phase due to elevated temperature. Regular table salt has a melting point of 801 °C (1474°F) and a heat of fusion of 520 J/g.Journal of Chemical T ...
s and molten
metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
s can be used for transferring and storing heat at temperatures above 300 to 400 °C where organic fluids start to decompose. Gases such as
water vapor (99.9839 °C) , - , Boiling point , , - , specific gas constant , 461.5 J/( kg·K) , - , Heat of vaporization , 2.27 MJ/kg , - , Heat capacity , 1.864 kJ/(kg·K) Water vapor, water vapour or aqueous vapor is the gaseous p ...
,
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
,
argon Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as ...
,
helium Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
and
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
have been used as heat transfer fluids where liquids are not suitable. For gases the pressure typically needs to be elevated to facilitate higher flow rates with low pumping power. In order to prevent overheating, fluid flows inside a system or a device so as to transfer the heat outside that particular device or system. They generally have a high boiling point and a high
heat capacity Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat to be supplied to an object to produce a unit change in its temperature. The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity ...
. High boiling point prevents the heat transfer liquids from vaporising at high temperatures. High heat capacity enables a small amount of the refrigerant to transfer a large amount of heat very efficiently. It must be ensured that the heat transfer liquids used should not have a low boiling point. This is because a low boiling point will result in vaporisation of the liquid at low temperatures when they are used to exchange heat with hot substances. This will produce vapors of the liquid in the machine itself where they are used. Also, the heat transfer fluids should have high heat capacity. The heat capacity denotes the amount of heat the fluid can hold without changing its temperature. In case of liquids, it also shows the amount of heat the liquid can hold before its temperature reaches its boiling point and ultimately vaporises. If the fluid has low heat capacity, then it will mean that a large amount of the fluid will be required to exchange a relatively small amount of heat. This will increase the cost of using heat transfer fluids and will reduce the efficiency of the process. In case of liquid heat transfer fluids, usage of their small quantity will result in their vaporisation which can be dangerous for the equipment where they are used. The equipment will be designed for liquids but their vaporisation will include vapors in the flow channel. Also gases occupy larger volume than liquids at the same pressure. The production of vapors will increase the pressure on the walls of the pipe/channel where it will be flowing. This may cause the flow channel to rupture.


Characteristics of heat transfer fluids

Low
viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the inte ...
will help in easy flow of the fluid. It will further reduce the pumping costs. The fluid chosen should not
corrode Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engin ...
the walls of the pipe through which it flows. This will reduce the maintenance costs of the equipment as fewer replacement of the pipes will be required. High thermal conductivity and thermal diffusivity will increase the rate of heat transfer through the fluid. The fluid should have high boiling and low freezing points. This will help the fluid to stay in the same phase while exchanging heat. This will also lower the equipment design complications.


Compounds

The list of commonly used heat-transferring fluids: *
Water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
**
Water vapor (99.9839 °C) , - , Boiling point , , - , specific gas constant , 461.5 J/( kg·K) , - , Heat of vaporization , 2.27 MJ/kg , - , Heat capacity , 1.864 kJ/(kg·K) Water vapor, water vapour or aqueous vapor is the gaseous p ...
*
Air The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing f ...
* Mono-ethylene glycol *
Propylene glycol Propylene glycol (IUPAC name: propane-1,2-diol) is a viscous, colorless liquid, which is nearly odorless but possesses a faintly sweet taste. Its chemical formula is CH3CH(OH)CH2OH. Containing two alcohol groups, it is classed as a diol. It i ...
* Silicone oil


See also

*
Coolant A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosi ...
* Nanofluid#Smart cooling nanofluids *
Heat-transfer oil An oil is any nonpolar chemical substance that is composed primarily of hydrocarbons and is hydrophobic (does not mix with water) & lipophilic (mixes with other oils). Oils are usually flammable and surface active. Most oils are unsaturated ...
(
oil cooling Oil cooling is the use of engine oil as a coolant, typically to remove surplus heat from an internal combustion engine. The hot engine transfers heat to the oil which then usually passes through a heat-exchanger, typically a type of radiator kn ...
,
oil heater An oil heater, also known as an oil-filled heater, oil-filled radiator, or column heater, is a common form of convection heater used in domestic heating. Although filled with oil, it is electrically heated and does not involve burning any oil ...
)


References


Further reading

*{{cite book , last=Singh , first=Jasbir , date=1985 , title=Heat Transfer Fluids and Systems for Process and Energy Applications , url= , location=New York , publisher=Marcel Dekker , page= , isbn=0-8247-7191-5 , author-link= Heat transfer Fluid dynamics