Hawaiite is an

olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickl ...

basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...

with a composition between

alkali basalt Alkali basalt or alkali olivine basalt is a dark-colored, porphyritic volcanic rock usually found in oceanic and continental areas associated with volcanic activity, such as oceanic islands, continental rifts and volcanic fields. Alkali basalt ...

and

mugearite Mugearite () is a type of oligoclase-bearing basalt, comprising olivine, apatite, and opaque oxides. The main feldspar in mugearite is oligoclase. Mugearite is a sodium-rich member of the alkaline magma series. In the TAS classification of volc ...

. It was first used as a name for some lavas found on the island of

Hawaii Hawaii ( ; haw, Hawaii or ) is a state in the Western United States, located in the Pacific Ocean about from the U.S. mainland. It is the only U.S. state outside North America, the only state that is an archipelago, and the only stat ...

. It occurs during the later stages of volcanic activity on oceanic islands such as Hawaii, which happens to be when the alkaline metals are most present. In

gemology Gemology or gemmology is the science dealing with natural and artificial gemstone materials. It is a geoscience and a branch of mineralogy. Some jewelers (and many non-jewelers) are academically trained gemologists and are qualified to identif ...

, hawaiite is a

colloquial Colloquialism (), also called colloquial language, everyday language or general parlance, is the linguistic style used for casual (informal) communication. It is the most common functional style of speech, the idiom normally employed in conver ...

term for Hawaii-originated

peridot Peridot ( /ˈpɛr.ɪˌdɒt, -ˌdoʊ/ ''PERR-ih-dot, -⁠doh''), sometimes called chrysolite, is a deep yellowish-green transparent variety of olivine. Peridot is one of the few gemstones that only occurs in one color. Peridot can be found in ...

, which is a

gem A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, a ...

-quality form of the mineral

Description

Hawaiite is an

aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This geolog ...

(fine-grained)

volcanic rock Volcanic rock (often shortened to volcanics in scientific contexts) is a rock formed from lava erupted from a volcano. In other words, it differs from other igneous rock by being of volcanic origin. Like all rock types, the concept of volcanic r ...

produced by rapid cooling of

lava Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or un ...

moderately poor in

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...

and enriched in

alkali metal oxide The alkali metals react with oxygen to form several different compounds: suboxides, oxides, peroxides, sesquioxides, superoxides, and ozonides. They all react violently with water. Alkali metal suboxides * Hexarubidium monoxide (Rb6O) h * Non ...

s (

potassium oxide Potassium oxide ( K O) is an ionic compound of potassium and oxygen. It is a base. This pale yellow solid is the simplest oxide of potassium. It is a highly reactive compound that is rarely encountered. Some industrial materials, such as fertili ...

plus

sodium oxide Sodium oxide is a chemical compound with the formula Na2 O. It is used in ceramics and glasses. It is a white solid but the compound is rarely encountered. Instead "sodium oxide" is used to describe components of various materials such as glass ...

). It is often impractical to determine the

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...

composition of such a fine-grained rock, and so hawaiite is defined chemically. Under the

TAS classification The TAS classification can be used to assign names to many common types of volcanic rocks based upon the relationships between the combined alkali content and the silica content. These chemical parameters are useful, because the relative proportio ...

, hawaiite is sodic

trachybasalt Trachybasalt is a volcanic rock with a composition between trachyte and basalt. It resembles basalt but has a high content of alkali metal oxides. Minerals in trachybasalt include alkali feldspar, calcic plagioclase, olivine, clinopyroxene and li ...

, with a silica content close to 49 wt%, a total alkali metal oxide content close to 6%, and wt% > wt% + 2. This places hawaiite in the S1 field of the TAS diagram. Hawaiite is not a recognized rock type in the

QAPF classification A QAPF diagram is a double ternary diagram which is used to classify igneous rocks based on mineralogic composition. The acronym QAPF stands for "Quartz, Alkali feldspar, Plagioclase, Feldspathoid (Foid)". These are the mineral groups used for ...

igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...

, which is based on the relative proportions of

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...

, alkali feldspar, and

plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more prope ...

in the mineral composition. However, hawaiite is composed mostly of

andesine Andesine is a silicate mineral, a member of the plagioclase feldspar solid solution series. Its chemical formula is ( Ca, Na)( Al, Si)4 O8, where Ca/(Ca + Na) (% anorthite) is between 30–50%. The formula may be written as Na0.7-0.5Ca0.3-0.5Al ...

(plagioclase feldspar with an

albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate ...

content of 50% to 70%) and

pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...

with smaller amounts of

. This would fall into the

andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predomi ...

/basalt field of the QAPF diagram.

Occurrence

Hawaiite is erupted in the late stages of ocean island volcanism, forming part of the

alkaline magma series The alkaline magma series is a chemically distinct range of magma compositions that describes the evolution of an alkaline mafic magma into a more evolved, silica-rich end member. Geochemical characterization Rocks in the alkaline magma series a ...

characteristic of such eruptions. It is preceded by silica-poor ankaramite and followed by intermediate-silica

as the magma evolves by crystallization in the underlying

magma chamber A magma chamber is a large pool of liquid rock beneath the surface of the Earth. The molten rock, or magma, in such a chamber is less dense than the surrounding country rock, which produces buoyant forces on the magma that tend to drive it upw ...

. These rocks form an ''alkalic cap'' over the older rocks of the island. Hawaiite can occur at earlier stages in the evolution of some volcanoes in other tectonic settings, for example during the middle stage of volcanic activity in the Kekuknai volcanic massif (in

Kamchatka The Kamchatka Peninsula (russian: полуостров Камчатка, Poluostrov Kamchatka, ) is a peninsula in the Russian Far East, with an area of about . The Pacific Ocean and the Sea of Okhotsk make up the peninsula's eastern and wes ...

, Russia) that formed in a volcanic back-arc basin. Other settings in which hawaiite and other alkaline volcanic rocks are found include regions of continental extension, such as the

Basin and Range Province The Basin and Range Province is a vast physiographic region covering much of the inland Western United States and northwestern Mexico. It is defined by unique basin and range topography, characterized by abrupt changes in elevation, alternating ...

of western North America and the

Red Sea Rift The Red Sea Rift is a spreading center between two tectonic plates, the African Plate and the Arabian Plate. It extends from the Dead Sea Transform fault system, and ends at an intersection with the Aden Ridge and the East African Rift, forming ...

References

Basalt Mafic rocks Aphanitic rocks {{volcanology-stub