The ground state of a
quantum-mechanical system is its
stationary state
A stationary state is a quantum state with all observables independent of time. It is an eigenvector of the energy operator (instead of a quantum superposition of different energies). It is also called energy eigenvector, energy eigenstate, ener ...
of lowest
energy
In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of heat ...
; the energy of the ground state is known as the
zero-point energy
Zero-point energy (ZPE) is the lowest possible energy that a quantum mechanical system may have. Unlike in classical mechanics, quantum systems constantly fluctuate in their lowest energy state as described by the Heisenberg uncertainty pri ...
of the system. An
excited state
In quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum). Excitation refers to ...
is any state with energy greater than the ground state. In
quantum field theory
In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines classical field theory, special relativity, and quantum mechanics. QFT is used in particle physics to construct physical models of subatomic particles and ...
, the ground state is usually called the
vacuum state
In quantum field theory, the quantum vacuum state (also called the quantum vacuum or vacuum state) is the quantum state with the lowest possible energy. Generally, it contains no physical particles. The word zero-point field is sometimes used as ...
or the
vacuum
A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or "void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often dis ...
.
If more than one ground state exists, they are said to be
degenerate. Many systems have degenerate ground states. Degeneracy occurs whenever there exists a
unitary operator
In functional analysis, a unitary operator is a surjective bounded operator on a Hilbert space that preserves the inner product. Unitary operators are usually taken as operating ''on'' a Hilbert space, but the same notion serves to define the co ...
that acts non-trivially on a ground state and
commutes with the
Hamiltonian
Hamiltonian may refer to:
* Hamiltonian mechanics, a function that represents the total energy of a system
* Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system
** Dyall Hamiltonian, a modified Hamiltonian ...
of the system.
According to the
third law of thermodynamics
The third law of thermodynamics states, regarding the properties of closed systems in thermodynamic equilibrium: This constant value cannot depend on any other parameters characterizing the closed system, such as pressure or applied magnetic fiel ...
, a system at
absolute zero
Absolute zero is the lowest limit of the thermodynamic temperature scale, a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value, taken as zero kelvin. The fundamental particles of nature have minimum vibratio ...
temperature
Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measurement, measured with a thermometer.
Thermometers are calibrated in various Conversion of units of temperature, temp ...
exists in its ground state; thus, its
entropy
Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynam ...
is determined by the degeneracy of the ground state. Many systems, such as a perfect
crystal lattice
In geometry and crystallography, a Bravais lattice, named after , is an infinite array of discrete points generated by a set of discrete translation operations described in three dimensional space by
: \mathbf = n_1 \mathbf_1 + n_2 \mathbf_2 + n_ ...
, have a unique ground state and therefore have zero entropy at absolute zero. It is also possible for the highest excited state to have
absolute zero
Absolute zero is the lowest limit of the thermodynamic temperature scale, a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value, taken as zero kelvin. The fundamental particles of nature have minimum vibratio ...
temperature for systems that exhibit
negative temperature
Certain systems can achieve negative thermodynamic temperature; that is, their temperature can be expressed as a negative quantity on the Kelvin or Rankine scales. This should be distinguished from temperatures expressed as negative numbers on ...
.
Absence of nodes in one dimension
In one dimension, the ground state of the
Schrödinger equation
The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the ...
can be proven to have no
nodes.
[
See, for example, Published as ]
Derivation
Consider the average energy of a state with a node at ; i.e., . The average energy in this state would be
where is the potential.
With
integration by parts
In calculus, and more generally in mathematical analysis, integration by parts or partial integration is a process that finds the integral of a product of functions in terms of the integral of the product of their derivative and antiderivative. ...
:
Hence in case that
is equal to ''zero'', one gets:
Now, consider a small interval around
; i.e.,