Gilbert Newton Lewis
(October 23
[ or October 25, 1875 – March 23, 1946)] was an American physical chemist
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mech ...
and a Dean of the College of Chemistry at University of California, Berkeley
The University of California, Berkeley (UC Berkeley, Berkeley, Cal, or California) is a public land-grant research university in Berkeley, California. Established in 1868 as the University of California, it is the state's first land-grant un ...
. Lewis was best known for his discovery of the covalent bond
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between ato ...
and his concept of electron pair
In chemistry, an electron pair or Lewis pair consists of two electrons that occupy the same molecular orbital but have opposite spins. Gilbert N. Lewis introduced the concepts of both the electron pair and the covalent bond in a landmark paper he ...
s; his Lewis dot structures
Lewis structures, also known as Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDS), are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons th ...
and other contributions to valence bond theory
In chemistry, valence bond (VB) theory is one of the two basic theories, along with molecular orbital (MO) theory, that were developed to use the methods of quantum mechanics to explain chemical bonding. It focuses on how the atomic orbitals of ...
have shaped modern theories of chemical bond
A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules and crystals. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of ...
ing. Lewis successfully contributed to chemical thermodynamics
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurem ...
, photochemistry
Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet ( wavelength from 100 to 400 nm), visible light (400� ...
, and isotope separation
Isotope separation is the process of concentrating specific isotopes of a chemical element by removing other isotopes. The use of the nuclides produced is varied. The largest variety is used in research (e.g. in chemistry where atoms of "marker" ...
, and is also known for his concept of acids and bases. Lewis also researched on relativity and quantum physics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, qua ...
, and in 1926 he coined the term "photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they alwa ...
" for the smallest unit of radiant energy.
G. N. Lewis was born in 1875 in Weymouth, Massachusetts ("To Work Is to Conquer")
, image_map = Norfolk County Massachusetts incorporated and unincorporated areas Weymouth highlighted.svg
, mapsize = 250px
, map_caption = Location in Norfolk County in Massa ...
. After receiving his PhD in chemistry
Chemistry is the scientific study of the properties and behavior of matter. It is a natural science that covers the elements that make up matter to the compounds made of atoms, molecules and ions: their composition, structure, proper ...
from Harvard University
Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of highe ...
and studying abroad in Germany and the Philippines
The Philippines (; fil, Pilipinas, links=no), officially the Republic of the Philippines ( fil, Republika ng Pilipinas, links=no),
* bik, Republika kan Filipinas
* ceb, Republika sa Pilipinas
* cbk, República de Filipinas
* hil, Republ ...
, Lewis moved to California
California is a state in the Western United States, located along the Pacific Coast. With nearly 39.2million residents across a total area of approximately , it is the most populous U.S. state and the 3rd largest by area. It is also the m ...
in 1912 to teach chemistry at the University of California, Berkeley, where he became the Dean of the College of Chemistry and spent the rest of his life. As a professor, he incorporated thermodynamic principles into the chemistry curriculum and reformed chemical thermodynamics
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurem ...
in a mathematically rigorous manner accessible to ordinary chemists. He began measuring the free energy values related to several chemical processes, both organic and inorganic. In 1916, he also proposed his theory of bonding and added information about electrons in the periodic table
The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of ch ...
of the chemical element
A chemical element is a species of atoms that have a given number of protons in their atomic nucleus, nuclei, including the pure Chemical substance, substance consisting only of that species. Unlike chemical compounds, chemical elements canno ...
s. In 1933, he started his research on isotope separation. Lewis worked with hydrogen and managed to purify a sample of heavy water. He then came up with his theory of acids and bases, and did work in photochemistry
Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet ( wavelength from 100 to 400 nm), visible light (400� ...
during the last years of his life.
Though he was nominated 41 times, G. N. Lewis never won the Nobel Prize in Chemistry
)
, image = Nobel Prize.png
, alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "M ...
, resulting in a major Nobel Prize controversy. On the other hand, Lewis mentored and influenced numerous Nobel laureates at Berkeley including Harold Urey
Harold Clayton Urey ( ; April 29, 1893 – January 5, 1981) was an American physical chemist whose pioneering work on isotopes earned him the Nobel Prize in Chemistry in 1934 for the discovery of deuterium. He played a significant role in th ...
(1934 Nobel Prize), William F. Giauque
William Francis Giauque (;''The Columbia Electronic Encyclopedia'', 2004. May 12, 1895 – March 28, 1982) was a Canadian-born American chemist and Nobel laureate recognized in 1949 for his studies in the properties of matter at temperatures cl ...
(1949 Nobel Prize), Glenn T. Seaborg (1951 Nobel Prize), Willard Libby
Willard Frank Libby (December 17, 1908 – September 8, 1980) was an American physical chemist noted for his role in the 1949 development of radiocarbon dating, a process which revolutionized archaeology and palaeontology. For his contribution ...
(1960 Nobel Prize), Melvin Calvin (1961 Nobel Prize) and so on, turning Berkeley into one of the world's most prestigious centers for chemistry. On March 23, 1946, Lewis was found dead in his Berkeley laboratory where he had been working with hydrogen cyanide
Hydrogen cyanide, sometimes called prussic acid, is a chemical compound with the formula HCN and structure . It is a colorless, extremely poisonous, and flammable liquid that boils slightly above room temperature, at . HCN is produced on a ...
; many postulated that the cause of his death was suicide. After Lewis' death, his children followed their father's career in chemistry, and the Lewis Hall on the Berkeley campus is named after him.
Biography
Early life
Lewis was born in 1875 and raised in Weymouth, Massachusetts ("To Work Is to Conquer")
, image_map = Norfolk County Massachusetts incorporated and unincorporated areas Weymouth highlighted.svg
, mapsize = 250px
, map_caption = Location in Norfolk County in Massa ...
, where there exists a street named for him, G.N. Lewis Way, off Summer Street. Additionally, the wing of the new Weymouth High School Chemistry department has been named in his honor. Lewis received his primary education at home from his parents, Frank Wesley Lewis, a lawyer of independent character, and Mary Burr White Lewis. He read at age three and was intellectually precocious. In 1884 his family moved to Lincoln, Nebraska
Lincoln is the capital city of the U.S. state of Nebraska and the county seat of Lancaster County. The city covers with a population of 292,657 in 2021. It is the second-most populous city in Nebraska and the 73rd-largest in the United ...
, and in 1889 he received his first formal education at the university preparatory school.
In 1893, after two years at the University of Nebraska
A university () is an institution of higher (or tertiary) education and research which awards academic degrees in several academic disciplines. Universities typically offer both undergraduate and postgraduate programs. In the United State ...
, Lewis transferred to Harvard University
Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of highe ...
, where he obtained his B.S. in 1896. After a year of teaching at Phillips Academy
("Not for Self") la, Finis Origine Pendet ("The End Depends Upon the Beginning") Youth From Every Quarter Knowledge and Goodness
, address = 180 Main Street
, city = Andover, Massachusetts, Andover
, stat ...
in Andover
Andover may refer to:
Places Australia
*Andover, Tasmania
Canada
* Andover Parish, New Brunswick
* Perth-Andover, New Brunswick
United Kingdom
* Andover, Hampshire, England
** RAF Andover, a former Royal Air Force station
United States
* Andov ...
, Lewis returned to Harvard to study with the physical chemist T. W. Richards and obtained his Ph.D. in 1899 with a dissertation on electrochemical potential
In electrochemistry, the electrochemical potential (ECP), ', is a thermodynamic measure of chemical potential that does not omit the energy contribution of electrostatics. Electrochemical potential is expressed in the unit of J/ mol.
Introductio ...
s. After a year of teaching at Harvard, Lewis took a traveling fellowship to Germany, the center of physical chemistry
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistica ...
, and studied with Walther Nernst
Walther Hermann Nernst (; 25 June 1864 – 18 November 1941) was a German chemist known for his work in thermodynamics, physical chemistry, electrochemistry, and solid state physics. His formulation of the Nernst heat theorem helped pave the w ...
at Göttingen
Göttingen (, , ; nds, Chöttingen) is a university city in Lower Saxony, central Germany, the capital of the eponymous district. The River Leine runs through it. At the end of 2019, the population was 118,911.
General information
The ori ...
and with Wilhelm Ostwald
Friedrich Wilhelm Ostwald (; 4 April 1932) was a Baltic German chemist and philosopher. Ostwald is credited with being one of the founders of the field of physical chemistry, with Jacobus Henricus van 't Hoff, Walther Nernst, and Svante Arrhen ...
at Leipzig
Leipzig ( , ; Upper Saxon: ) is the most populous city in the German state of Saxony. Leipzig's population of 605,407 inhabitants (1.1 million in the larger urban zone) as of 2021 places the city as Germany's eighth most populous, as ...
. While working in Nernst's lab, Lewis apparently developed a lifelong enmity with Nernst. In the following years, Lewis started to criticize and denounce his former teacher on many occasions, calling Nernst's work on his heat theorem "''a regrettable episode in the history of chemistry''". A Swedish
Swedish or ' may refer to:
Anything from or related to Sweden, a country in Northern Europe. Or, specifically:
* Swedish language, a North Germanic language spoken primarily in Sweden and Finland
** Swedish alphabet, the official alphabet used by ...
friend of Nernst's, Wilhelm Palmær, was a member of the Nobel Chemistry Committee. There is evidence that he used the Nobel nominating and reporting procedures to block a Nobel Prize
The Nobel Prizes ( ; sv, Nobelpriset ; no, Nobelprisen ) are five separate prizes that, according to Alfred Nobel's will of 1895, are awarded to "those who, during the preceding year, have conferred the greatest benefit to humankind." Alfr ...
for Lewis in thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws ...
by nominating Lewis for the prize three times, and then using his position as a committee member to write negative reports.
Harvard, Manila, and MIT
After his stay in Nernst's lab, Lewis returned to Harvard in 1901 as an instructor for three more years. He was appointed instructor in thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws ...
and electrochemistry
Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an out ...
. In 1904 Lewis was granted a leave of absence and became Superintendent of Weights and Measures for the Bureau of Science in Manila
Manila ( , ; fil, Maynila, ), officially the City of Manila ( fil, Lungsod ng Maynila, ), is the capital of the Philippines, and its second-most populous city. It is highly urbanized and, as of 2019, was the world's most densely populated ...
, Philippines
The Philippines (; fil, Pilipinas, links=no), officially the Republic of the Philippines ( fil, Republika ng Pilipinas, links=no),
* bik, Republika kan Filipinas
* ceb, Republika sa Pilipinas
* cbk, República de Filipinas
* hil, Republ ...
. The next year he returned to Cambridge, Massachusetts
Cambridge ( ) is a city in Middlesex County, Massachusetts, United States. As part of the Boston metropolitan area, the cities population of the 2020 U.S. census was 118,403, making it the fourth most populous city in the state, behind Boston, ...
when the Massachusetts Institute of Technology
The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of th ...
(MIT) appointed him to a faculty position, in which he had a chance to join a group of outstanding physical chemists under the direction of Arthur Amos Noyes
Arthur Amos Noyes (September 13, 1866 – June 3, 1936) was an American chemist, inventor and educator. He received a PhD in 1890 from Leipzig University under the guidance of Wilhelm Ostwald.
He served as the acting president of MIT between ...
. He became an assistant professor in 1907, associate professor in 1908, and full professor in 1911.
University of California, Berkeley
G. N. Lewis left MIT in 1912 to become a professor of physical chemistry and Dean of the College of Chemistry at the University of California, Berkeley
The University of California, Berkeley (UC Berkeley, Berkeley, Cal, or California) is a public land-grant research university in Berkeley, California. Established in 1868 as the University of California, it is the state's first land-grant un ...
. On June 21, 1912, he married Mary Hinckley Sheldon, daughter of a Harvard professor of Romance languages
The Romance languages, sometimes referred to as Latin languages or Neo-Latin languages, are the various modern languages that evolved from Vulgar Latin. They are the only extant subgroup of the Italic languages in the Indo-European language ...
. They had two sons, both of whom became chemistry professors, and a daughter. In 1913, he joined the Alpha Chi Sigma
Alpha Chi Sigma () is a professional fraternity specializing in the fields of the chemical sciences. It has both collegiate and professional chapters throughout the United States consisting of both men and women and numbering more than 70,000 me ...
at Berkeley, the professional chemistry fraternity.
While at Berkeley, Lewis mentored and influenced numerous future Nobel laureates including Harold Urey
Harold Clayton Urey ( ; April 29, 1893 – January 5, 1981) was an American physical chemist whose pioneering work on isotopes earned him the Nobel Prize in Chemistry in 1934 for the discovery of deuterium. He played a significant role in th ...
(1934 Nobel Prize), William F. Giauque
William Francis Giauque (;''The Columbia Electronic Encyclopedia'', 2004. May 12, 1895 – March 28, 1982) was a Canadian-born American chemist and Nobel laureate recognized in 1949 for his studies in the properties of matter at temperatures cl ...
(1949 Nobel Prize), Glenn T. Seaborg (1951 Nobel Prize), Willard Libby
Willard Frank Libby (December 17, 1908 – September 8, 1980) was an American physical chemist noted for his role in the 1949 development of radiocarbon dating, a process which revolutionized archaeology and palaeontology. For his contribution ...
(1960 Nobel Prize), Melvin Calvin (1961 Nobel Prize) and so on. Due to his efforts, the College of Chemistry at Berkeley became one of the top chemistry centers in the world. In 1913, he was elected to the National Academy of Sciences
The National Academy of Sciences (NAS) is a United States nonprofit, non-governmental organization. NAS is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy of Engineering (NAE) and the Nat ...
. He resigned in 1934, refusing to state the cause for his resignation; it has been speculated that it was due to a dispute over the internal politics of that institution or to the failure of those he had nominated to be elected. His decision to resign may have been sparked by resentment over the award of the 1934 Nobel Prize for chemistry to his student, Harold Urey
Harold Clayton Urey ( ; April 29, 1893 – January 5, 1981) was an American physical chemist whose pioneering work on isotopes earned him the Nobel Prize in Chemistry in 1934 for the discovery of deuterium. He played a significant role in th ...
, for the discovery of deuterium
Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one ...
, a prize Lewis almost certainly felt he should have shared for his work on purification and characterization of heavy water.
Death
On 23 March 1946, a graduate student found Lewis's lifeless body under a laboratory workbench at Berkeley. Lewis had been working on an experiment with liquid hydrogen cyanide
Hydrogen cyanide, sometimes called prussic acid, is a chemical compound with the formula HCN and structure . It is a colorless, extremely poisonous, and flammable liquid that boils slightly above room temperature, at . HCN is produced on a ...
, and deadly fumes from a broken line had leaked into the laboratory. The coroner ruled that the cause of death was coronary artery disease
Coronary artery disease (CAD), also called coronary heart disease (CHD), ischemic heart disease (IHD), myocardial ischemia, or simply heart disease, involves the reduction of blood flow to the heart muscle due to build-up of atherosclerotic pl ...
, because of a lack of any signs of cyanosis,[Coffey (2008): 310-15.] but some believe that it may have been a suicide. Berkeley Emeritus Professor William Jolly, who reported the various views on Lewis's death in his 1987 history of UC Berkeley's College of Chemistry, ''From Retorts to Lasers'', wrote that a higher-up in the department believed that Lewis had committed suicide.
If Lewis's death was indeed a suicide, a possible explanation was depression brought on by a lunch with Irving Langmuir
Irving Langmuir (; January 31, 1881 – August 16, 1957) was an American chemist, physicist, and engineer. He was awarded the Nobel Prize in Chemistry in 1932 for his work in surface chemistry.
Langmuir's most famous publication is the 1919 ar ...
. Langmuir and Lewis had a long rivalry, dating back to Langmuir's extensions of Lewis's theory of the chemical bond. Langmuir had been awarded the 1932 Nobel Prize in chemistry for his work on surface chemistry
Surface science is the study of physical and chemical phenomena that occur at the interface of two phases, including solid–liquid interfaces, solid– gas interfaces, solid–vacuum interfaces, and liquid– gas interfaces. It includes the fi ...
, while Lewis had not received the Prize despite having been nominated 41 times. On the day of Lewis's death, Langmuir and Lewis had met for lunch at Berkeley, a meeting that Michael Kasha recalled only years later. Associates reported that Lewis came back from lunch in a dark mood, played a morose game of bridge with some colleagues, then went back to work in his lab. An hour later, he was found dead. Langmuir's papers at the Library of Congress
The Library of Congress (LOC) is the research library that officially serves the United States Congress and is the ''de facto'' national library of the United States. It is the oldest federal cultural institution in the country. The libra ...
confirm that he had been on the Berkeley campus that day to receive an honorary degree. Lewis is buried in Golden Gate National Cemetery.
Lewis Hall at Berkeley, built in 1948, is named in his honor.
Scientific achievements
Thermodynamics
Most of Lewis’ lasting interests originated during his Harvard years. The most important was thermodynamics, a subject in which Richards was very active at that time. Although most of the important thermodynamic relations were known by 1895, they were seen as isolated equations, and had not yet been rationalized as a logical system, from which, given one relation, the rest could be derived. Moreover, these relations were inexact, applying only to ideal chemical systems. These were two outstanding problems of theoretical thermodynamics. In two long and ambitious theoretical papers in 1900 and 1901, Lewis tried to provide a solution. Lewis introduced the thermodynamic concept of activity and coined the term "fugacity
In chemical thermodynamics, the fugacity of a real gas is an effective partial pressure which replaces the mechanical partial pressure in an accurate computation of the chemical equilibrium constant. It is equal to the pressure of an ideal gas whic ...
". His new idea of fugacity, or "escaping tendency", was a function with the dimensions of pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country a ...
which expressed the tendency of a substance to pass from one chemical phase to another. Lewis believed that fugacity was the fundamental principle from which a system of real thermodynamic relations could be derived. This hope was not realized, though fugacity did find a lasting place in the description of real gases.
Lewis’ early papers also reveal an unusually advanced awareness of J. W. Gibbs's and P. Duhem's ideas of free energy and thermodynamic potential
A thermodynamic potential (or more accurately, a thermodynamic potential energy)ISO/IEC 80000-5, Quantities an units, Part 5 - Thermodynamics, item 5-20.4 Helmholtz energy, Helmholtz functionISO/IEC 80000-5, Quantities an units, Part 5 - Thermod ...
. These ideas were well known to physicists and mathematicians, but not to most practical chemists, who regarded them as abstruse and inapplicable to chemical systems. Most chemists relied on the familiar thermodynamics of heat (enthalpy) of Berthelot, Ostwald, and Van ’t Hoff, and the calorimetric school. Heat of reaction is not, of course, a measure of the tendency of chemical changes to occur, and Lewis realized that only free energy and entropy could provide an exact chemical thermodynamics. He derived free energy from fugacity; he tried, without success, to obtain an exact expression for the entropy
Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodyna ...
function, which in 1901 had not been defined at low temperatures. Richards too tried and failed, and not until Nernst succeeded in 1907 was it possible to calculate entropies unambiguously. Although Lewis’ fugacity-based system did not last, his early interest in free energy and entropy proved most fruitful, and much of his career was devoted to making these useful concepts accessible to practical chemists.
At Harvard, Lewis also wrote a theoretical paper on the thermodynamics of blackbody radiation
Black-body radiation is the thermal electromagnetic radiation within, or surrounding, a body in thermodynamic equilibrium with its environment, emitted by a black body (an idealized opaque, non-reflective body). It has a specific, continuous spe ...
in which he postulated that light has a pressure. He later revealed that he had been discouraged from pursuing this idea by his older, more conservative colleagues, who were unaware that Wilhelm Wien
Wilhelm Carl Werner Otto Fritz Franz Wien (; 13 January 1864 – 30 August 1928) was a German physicist who, in 1893, used theories about heat and electromagnetism to deduce Wien's displacement law, which calculates the emission of a blackbod ...
and others were successfully pursuing the same line of thought. Lewis’ paper remained unpublished; but his interest in radiation and quantum theory, and (later) in relativity, sprang from this early, aborted effort. From the start of his career, Lewis regarded himself as both chemist and physicist.
Valence theory
About 1902 Lewis started to use unpublished drawings of cubical atoms in his lecture notes, in which the corners of the cube represented possible electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary particles because they have n ...
positions. Lewis later cited these notes in his classic 1916 paper on chemical bonding, as being the first expression of his ideas.
A third major interest that originated during Lewis’ Harvard years was his valence theory. In 1902, while trying to explain the laws of valence to his students, Lewis conceived the idea that atoms were built up of a concentric series of cubes with electrons at each corner. This “cubic atom” explained the cycle of eight elements in the periodic table and was in accord with the widely accepted belief that chemical bonds were formed by transfer of electrons to give each atom a complete set of eight. This electrochemical theory of valence found its most elaborate expression in the work of Richard Abegg in 1904, but Lewis’ version of this theory was the only one to be embodied in a concrete atomic model. Again Lewis’ theory did not interest his Harvard mentors, who, like most American chemists of that time, had no taste for such speculation. Lewis did not publish his theory of the cubic atom, but in 1916 it became an important part of his theory of the shared electron pair bond.
In 1916, he published his classic paper on chemical bonding "''The Atom and the Molecule''" in which he formulated the idea of what would become known as the covalent bond
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between ato ...
, consisting of a shared pair
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between ato ...
of electrons, and he defined the term odd molecule (the modern term is free radical
A daughter category of ''Ageing'', this category deals only with the biological aspects of ageing.
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Ailments of unknown cause
Biogerontology
Biological processes
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) when an electron is not shared. He included what became known as Lewis dot structures as well as the cubical atom model. These ideas on chemical bond
A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules and crystals. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of ...
ing were expanded upon by Irving Langmuir
Irving Langmuir (; January 31, 1881 – August 16, 1957) was an American chemist, physicist, and engineer. He was awarded the Nobel Prize in Chemistry in 1932 for his work in surface chemistry.
Langmuir's most famous publication is the 1919 ar ...
and became the inspiration for the studies on the nature of the chemical bond by Linus Pauling
Linus Carl Pauling (; February 28, 1901August 19, 1994) was an American chemist, biochemist, chemical engineer, peace activist, author, and educator. He published more than 1,200 papers and books, of which about 850 dealt with scientific topi ...
.
Acids and bases
In 1923, he formulated the electron-pair theory of acid–base reaction
An acid–base reaction is a chemical reaction that occurs between an acid and a base. It can be used to determine pH via titration. Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their appl ...
s. In this theory of acid
In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a se ...
s and bases, a "Lewis acid" is an ''electron-pair acceptor'' and a "Lewis base" is an ''electron-pair donor''. This year he also published a monograph on his theories of the chemical bond.
Based on work by J. Willard Gibbs
Josiah Willard Gibbs (; February 11, 1839 – April 28, 1903) was an American scientist who made significant theoretical contributions to physics, chemistry, and mathematics. His work on the applications of thermodynamics was instrumental in t ...
, it was known that chemical reactions proceeded to an equilibrium determined by the free energy of the substances taking part. Lewis spent 25 years determining free energies of various substances. In 1923 he and Merle Randall
Merle Randall (January 29, 1888 – March 17, 1950) was an American physical chemist famous for his work with Gilbert N. Lewis, over a period of 25 years, in measuring reaction heat of chemical compounds and determining their corresponding free ...
published the results of this study, which helped formalize modern chemical thermodynamics
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurem ...
.
Heavy water
Lewis was the first to produce a pure sample of deuterium oxide ( heavy water) in 1933 and the first to study survival and growth of life forms in heavy water. By accelerating deuteron
Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one n ...
s (deuterium nuclei) in Ernest O. Lawrence's cyclotron
A cyclotron is a type of particle accelerator invented by Ernest O. Lawrence in 1929–1930 at the University of California, Berkeley, and patented in 1932. Lawrence, Ernest O. ''Method and apparatus for the acceleration of ions'', filed: Jan ...
, he was able to study many of the properties of atomic nuclei. During the 1930s, he was mentor to Glenn T. Seaborg, who was retained for post-doctoral work as Lewis' personal research assistant. Seaborg went on to win the 1951 Nobel Prize
The Nobel Prizes ( ; sv, Nobelpriset ; no, Nobelprisen ) are five separate prizes that, according to Alfred Nobel's will of 1895, are awarded to "those who, during the preceding year, have conferred the greatest benefit to humankind." Alfr ...
in Chemistry and have the element seaborgium
Seaborgium is a synthetic chemical element with the symbol Sg and atomic number 106. It is named after the American nuclear chemist Glenn T. Seaborg. As a synthetic element, it can be created in a laboratory but is not found in nature. It is al ...
named in his honor while he was still alive.
O4 Tetraoxygen
In 1924, by studying the magnetic
Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particl ...
properties of solutions of oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
in liquid
A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, ...
nitrogen
Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
, Lewis found that O4 molecules were formed. This was the first evidence for tetratomic oxygen.
Relativity and quantum physics
In 1908 he published the first of several papers on relativity, in which he derived the mass
Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a physical body, until the discovery of the atom and particle physics. It was found that different atoms and different ele ...
-energy
In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of ...
relationship in a different way from Albert Einstein
Albert Einstein ( ; ; 14 March 1879 – 18 April 1955) was a German-born theoretical physicist, widely acknowledged to be one of the greatest and most influential physicists of all time. Einstein is best known for developing the theor ...
's derivation. In 1909, he and Richard C. Tolman
Richard Chace Tolman (March 4, 1881 – September 5, 1948) was an American mathematical physicist and physical chemist who made many contributions to statistical mechanics. He also made important contributions to theoretical cosmology in t ...
combined his methods with special relativity
In physics, the special theory of relativity, or special relativity for short, is a scientific theory regarding the relationship between space and time. In Albert Einstein's original treatment, the theory is based on two postulates:
# The law ...
. In 1912 Lewis and Edwin Bidwell Wilson
Edwin Bidwell Wilson (April 25, 1879 – December 28, 1964) was an American mathematician, statistician, physicist and general polymath. He was the sole protégé of Yale University physicist Josiah Willard Gibbs and was mentor to MIT economist ...
presented a major work in mathematical physics that not only applied synthetic geometry
Synthetic geometry (sometimes referred to as axiomatic geometry or even pure geometry) is the study of geometry without the use of coordinates or formulae. It relies on the axiomatic method and the tools directly related to them, that is, compass ...
to the study of spacetime
In physics, spacetime is a mathematical model that combines the three dimensions of space and one dimension of time into a single four-dimensional manifold. Spacetime diagrams can be used to visualize relativistic effects, such as why differ ...
, but also noted the identity of a spacetime squeeze mapping
In linear algebra, a squeeze mapping, also called a squeeze transformation, is a type of linear map that preserves Euclidean area of regions in the Cartesian plane, but is ''not'' a rotation or shear mapping.
For a fixed positive real number , th ...
and a Lorentz transformation
In physics, the Lorentz transformations are a six-parameter family of Linear transformation, linear coordinate transformation, transformations from a Frame of Reference, coordinate frame in spacetime to another frame that moves at a constant velo ...
.
In 1926, he coined the term "photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they alwa ...
" for the smallest unit of radiant energy (light). Actually, the outcome of his letter to ''Nature
Nature, in the broadest sense, is the physical world or universe. "Nature" can refer to the phenomena of the physical world, and also to life in general. The study of nature is a large, if not the only, part of science. Although humans are ...
'' was not what he had intended. In the letter, he proposed a photon being a structural element, not energy
In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of ...
. He insisted on the need for a new variable, ''the number of photons''. Although his theory differed from the quantum theory of light introduced by Albert Einstein
Albert Einstein ( ; ; 14 March 1879 – 18 April 1955) was a German-born theoretical physicist, widely acknowledged to be one of the greatest and most influential physicists of all time. Einstein is best known for developing the theor ...
in 1905, his name was adopted for what Einstein had called a light quantum (Lichtquant in German).
Other achievements
In 1921, Lewis was the first to propose an empirical equation describing the failure of strong electrolytes to obey the law of mass action
In chemistry, the law of mass action is the proposition that the rate of the chemical reaction is directly proportional to the product of the activities or concentrations of the reactants. It explains and predicts behaviors of solutions in dy ...
, a problem that had perplexed physical chemists for twenty years. His empirical equations for what he called ionic strength
The ionic strength of a solution is a measure of the concentration of ions in that solution. Ionic compounds, when dissolved in water, dissociate into ions. The total electrolyte concentration in solution will affect important properties such a ...
were later confirmed to be in accord with the Debye–Hückel equation
The chemists Peter Debye and Erich Hückel noticed that solutions that contain ionic solutes do not behave ideally even at very low concentrations. So, while the concentration of the solutes is fundamental to the calculation of the dynamics of a ...
for strong electrolytes, published in 1923.
Over the course of his career, Lewis published on many other subjects besides those mentioned in this entry, ranging from the nature of light
Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 t ...
quanta to the economics
Economics () is the social science that studies the production, distribution, and consumption of goods and services.
Economics focuses on the behaviour and interactions of economic agents and how economies work. Microeconomics anal ...
of price stabilization. In the last years of his life, Lewis and graduate student Michael Kasha
Michael Kasha (December 6, 1920 – June 12, 2013) was an American physical chemist and molecular spectroscopist who was one of the original founders of the Institute of Molecular Biophysics at Florida State University .
Education and early wo ...
, his last research associate, established that phosphorescence
Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluo ...
of organic
Organic may refer to:
* Organic, of or relating to an organism, a living entity
* Organic, of or relating to an anatomical organ
Chemistry
* Organic matter, matter that has come from a once-living organism, is capable of decay or is the product ...
molecules involves emission of light from one electron in an excited triplet state
In quantum mechanics, a triplet is a quantum state of a system with a spin of quantum number =1, such that there are three allowed values of the spin component, = −1, 0, and +1.
Spin, in the context of quantum mechanics, is not a mechanical r ...
(a state in which two electrons have their spin vector
In geometry and physics, spinors are elements of a complex numbers, complex vector space that can be associated with Euclidean space. Like Euclidean vector, geometric vectors and more general tensors, spinors linear transformation, transform lin ...
s oriented in the ''same'' direction, but in different orbitals) and measured the paramagnetism
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior ...
of this triplet state.
See also
*History of molecular theory
In chemistry, the history of molecular theory traces the origins of the concept or idea of the existence of strong chemical bonds between two or more atoms.
The modern concept of molecules can be traced back towards pre-scientific and Greek ph ...
References
Further reading
*Coffey, Patrick (2008) ''Cathedrals of Science: The Personalities and Rivalries That Made Modern Chemistry''. Oxford University Press.
External links
*
Key Participants: G. N. Lewis
- ''Linus Pauling and the Nature of the Chemical Bond: A Documentary History''
*Eric Scerri, ''The Periodic Table, Its Story and Its Significance'', Oxford University Press, 2007, see chapter 8 especially
National Academy of Sciences Biographical Memoir
{{DEFAULTSORT:Lewis, Gilbert N.
Members of the United States National Academy of Sciences
American physical chemists
Thermodynamicists
American relativity theorists
Harvard University alumni
Massachusetts Institute of Technology alumni
UC Berkeley College of Chemistry faculty
Foreign Members of the Royal Society
Honorary Members of the USSR Academy of Sciences
1875 births
1946 deaths
People from Weymouth, Massachusetts
University of Nebraska alumni