Gypsum is a soft

sulfate mineral The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary m ...

composed of

calcium sulfate Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, ...

dihydrate, with the

chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ...

. It is widely mined and is used as a

fertilizer A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...

and as the main constituent in many forms of

plaster Plaster is a building material used for the protective or decorative coating of walls and ceilings and for moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of buildings, while "r ...

blackboard A blackboard (also known as a chalkboard) is a reusable writing surface on which text or drawings are made with sticks of calcium sulphate or calcium carbonate, known, when used for this purpose, as chalk. Blackboards were originally made of ...

sidewalk chalk Sidewalk chalk is typically large and thick sticks of chalk ( calcium sulfate, gypsum, rather than calcium carbonate, rock chalk) that come in multiple colors and are mostly used for drawing on pavement or concrete sidewalks, frequently four s ...

, and

drywall Drywall (also called plasterboard, dry lining, wallboard, sheet rock, gypsum board, buster board, custard board, and gypsum panel) is a panel made of calcium sulfate dihydrate (gypsum), with or without additives, typically extruded between thi ...

Alabaster Alabaster is a mineral or rock that is soft, often used for carving, and is processed for plaster powder. Archaeologists and the stone processing industry use the word differently from geologists. The former use it in a wider sense that includes ...

, a fine-grained white or lightly tinted variety of gypsum, has been used for

sculpture Sculpture is the branch of the visual arts that operates in three dimensions. Sculpture is the three-dimensional art work which is physically presented in the dimensions of height, width and depth. It is one of the plastic arts. Durable sc ...

by many cultures including Ancient Egypt,

Mesopotamia Mesopotamia ''Mesopotamíā''; ar, بِلَاد ٱلرَّافِدَيْن or ; syc, ܐܪܡ ܢܗܪ̈ܝܢ, or , ) is a historical region of Western Asia situated within the Tigris–Euphrates river system, in the northern part of the F ...

Ancient Rome In modern historiography, ancient Rome refers to Roman civilisation from the founding of the city of Rome in the 8th century BC to the collapse of the Western Roman Empire in the 5th century AD. It encompasses the Roman Kingdom (753–50 ...

, the

Byzantine Empire The Byzantine Empire, also referred to as the Eastern Roman Empire or Byzantium, was the continuation of the Roman Empire primarily in its eastern provinces during Late Antiquity and the Middle Ages, when its capital city was Constantin ...

, and the

Nottingham alabaster Nottingham alabaster is a term used to refer to the English sculpture industry, mostly of relatively small religious carvings, which flourished from the fourteenth century until the early sixteenth century. Alabaster carvers were at work in Lo ...

s of

Medieval England England in the Middle Ages concerns the history of England during the medieval period, from the end of the 5th century through to the start of the Early Modern period in 1485. When England emerged from the collapse of the Roman Empire, the econ ...

. Gypsum also crystallizes as translucent crystals of selenite. It forms as an

evaporite An evaporite () is a water- soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as oce ...

mineral and as a hydration product of

anhydrite Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with t ...

. The

Mohs scale of mineral hardness The Mohs scale of mineral hardness () is a Qualitative property, qualitative ordinal scale, from 1 to 10, characterizing scratch hardness, scratch resistance of various minerals through the ability of harder material to scratch softer material. ...

defines gypsum as hardness value 2 based on scratch

hardness comparison A variety of hardness-testing methods are available, including the Vickers, Brinell, Rockwell, Meyer and Leeb tests. Although it is impossible in many cases to give an exact conversion, it is possible to give an approximate material-specific com ...

Etymology and history

The word ''

gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and dr ...

'' is derived from the

Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...

word (), "plaster". Because the

quarries A quarry is a type of open-pit mine in which dimension stone, rock, construction aggregate, riprap, sand, gravel, or slate is excavated from the ground. The operation of quarries is regulated in some jurisdictions to reduce their environ ...

of the

Montmartre Montmartre ( , ) is a large hill in Paris's northern 18th arrondissement. It is high and gives its name to the surrounding district, part of the Right Bank. The historic district established by the City of Paris in 1995 is bordered by Rue C ...

district of

Paris Paris () is the capital and most populous city of France, with an estimated population of 2,165,423 residents in 2019 in an area of more than 105 km² (41 sq mi), making it the 30th most densely populated city in the world in 2020. ...

have long furnished burnt gypsum ( calcined gypsum) used for various purposes, this dehydrated gypsum became known as

plaster of Paris Plaster is a building material used for the protective or decorative coating of walls and ceilings and for moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of buildings, while "r ...

. Upon adding water, after a few dozen minutes, plaster of Paris becomes regular gypsum (dihydrate) again, causing the material to harden or "set" in ways that are useful for casting and construction. Gypsum was known in Old English as , "spear stone", referring to its crystalline projections. (Thus, the word

spar SPAR, originally DESPAR, styled as DE SPAR, is a Dutch multinational that provides branding, supplies and support services for independently owned and operated food retail stores. It was founded in the Netherlands in 1932, by Adriaan van Well ...

in mineralogy is by way of comparison to gypsum, referring to any non-ore mineral or crystal that forms in spearlike projections). In the mid-18th century, the German clergyman and agriculturalist Johann Friderich Mayer investigated and publicized gypsum's use as a fertilizer. Gypsum may act as a source of sulfur for plant growth, and in the early 19th century, it was regarded as an almost miraculous fertilizer. American farmers were so anxious to acquire it that a lively smuggling trade with Nova Scotia evolved, resulting in the so-called "Plaster War" of 1820.

Physical properties

Gypsum deformed cristal-MCG 7747-P4150901-black

Gypsum is moderately water-soluble (~2.0–2.5 g/L at 25 °C) and, in contrast to most other salts, it exhibits retrograde solubility, becoming less soluble at higher temperatures. When gypsum is heated in air it loses water and converts first to calcium sulfate hemihydrate, ( bassanite, often simply called "plaster") and, if heated further, to anhydrous

(

). As with

, the solubility of gypsum in saline solutions and in

brine Brine is a high-concentration Solution (chemistry), solution of salt (NaCl) in water (H2O). In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of ...

s is also strongly dependent on

NaCl Sodium chloride , commonly known as salt (although sea salt also contains other chemical salts), is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. With molar masses of 22.99 and 35.45 g/ ...

(common table salt) concentration. The structure of gypsum consists of layers of calcium (Ca²⁺) and sulfate () ions tightly bound together. These layers are bonded by sheets of

anion water In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization i ...

molecules via weaker

hydrogen bond In chemistry, a hydrogen bond (or H-bond) is a primarily electrostatic force of attraction between a hydrogen (H) atom which is covalently bound to a more electronegative "donor" atom or group (Dn), and another electronegative atom bearing ...

ing, which gives the crystal perfect cleavage along the sheets (in the plane).

Crystal varieties

Gypsum occurs in nature as flattened and often

twinned Twinning (making a twin of) may refer to: * In biology and agriculture, producing two offspring (i.e., twins) at a time, or having a tendency to do so; * Twin towns and sister cities, towns and cities involved in town twinning * Twinning inst ...

crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macr ...

s, and transparent, cleavable masses called selenite. Selenite contains no significant

selenium Selenium is a chemical element with the symbol Se and atomic number 34. It is a nonmetal (more rarely considered a metalloid) with properties that are intermediate between the elements above and below in the periodic table, sulfur and telluriu ...

; rather, both substances were named for the ancient Greek word for the

Moon The Moon is Earth's only natural satellite. It is the fifth largest satellite in the Solar System and the largest and most massive relative to its parent planet, with a diameter about one-quarter that of Earth (comparable to the width ...

. Selenite may also occur in a silky, fibrous form, in which case it is commonly called "satin spar". Finally, it may also be granular or quite compact. In hand-sized samples, it can be anywhere from transparent to opaque. A very fine-grained white or lightly tinted variety of gypsum, called

alabaster Alabaster is a mineral or rock that is soft, often used for carving, and is processed for plaster powder. Archaeologists and the stone processing industry use the word differently from geologists. The former use it in a wider sense that includes ...

, is prized for ornamental work of various sorts. In arid areas, gypsum can occur in a flower-like form, typically opaque, with embedded sand grains called desert rose. It also forms some of the largest crystals found in nature, up to long, in the form of selenite.

Occurrence

Gypsum is a common mineral, with thick and extensive

beds in association with

sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particle ...

s. Deposits are known to occur in

strata In geology and related fields, a stratum ( : strata) is a layer of rock or sediment characterized by certain lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by visible surfaces known as e ...

from as far back as the Archaean eon. Gypsum is deposited from lake and sea water, as well as in

hot spring A hot spring, hydrothermal spring, or geothermal spring is a spring produced by the emergence of geothermally heated groundwater onto the surface of the Earth. The groundwater is heated either by shallow bodies of magma (molten rock) or by c ...

s, from

volcanic A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates ...

vapors, and sulfate solutions in

veins Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated ...

Hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

in veins is commonly hydrated to gypsum by groundwater in near-surface exposures. It is often associated with the minerals

halite Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, ...

and

sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formul ...

. Gypsum is the most common sulfate mineral. Pure gypsum is white, but other substances found as impurities may give a wide range of colors to local deposits. Because gypsum dissolves over time in water, gypsum is rarely found in the form of sand. However, the unique conditions of the

White Sands National Park White Sands National Park is an American national park located in the state of New Mexico and completely surrounded by the White Sands Missile Range. The park covers in the Tularosa Basin, including the southern 41% of a field of white sand d ...

in the US state of

New Mexico ) , population_demonym = New Mexican ( es, Neomexicano, Neomejicano, Nuevo Mexicano) , seat = Santa Fe, New Mexico, Santa Fe , LargestCity = Albuquerque, New Mexico, Albuquerque , LargestMetro = Albuquerque metropolitan area, Tiguex , Offi ...

have created a expanse of white gypsum sand, enough to supply the US construction industry with

for 1,000 years. Commercial exploitation of the area, strongly opposed by area residents, was permanently prevented in 1933 when President

Herbert Hoover Herbert Clark Hoover (August 10, 1874 – October 20, 1964) was an American politician who served as the 31st president of the United States from 1929 to 1933 and a member of the Republican Party (United States), Republican Party, holding o ...

declared the gypsum

dune A dune is a landform composed of wind- or water-driven sand. It typically takes the form of a mound, ridge, or hill. An area with dunes is called a dune system or a dune complex. A large dune complex is called a dune field, while broad, fl ...

s a protected

national monument A national monument is a monument constructed in order to commemorate something of importance to national heritage, such as a country's founding, independence, war, or the life and death of a historical figure. The term may also refer to a sp ...

. Gypsum is also formed as a by-product of

sulfide Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds l ...

oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...

, amongst others by

pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue giv ...

, when the sulfuric acid generated reacts with calcium carbonate. Its presence indicates oxidizing conditions. Under reducing conditions, the sulfates it contains can be reduced back to sulfide by

sulfate-reducing bacteria Sulfate-reducing microorganisms (SRM) or sulfate-reducing prokaryotes (SRP) are a group composed of sulfate-reducing bacteria (SRB) and sulfate-reducing archaea (SRA), both of which can perform anaerobic respiration utilizing sulfate () as termin ...

. This can lead to accumulation of elemental

in oil-bearing formations, such as salt domes, where it can be mined using the Frasch process Electric power stations burning coal with flue gas desulfurization produce large quantities of gypsum as a byproduct from the scrubbers. Orbital pictures from the

Mars Reconnaissance Orbiter ''Mars Reconnaissance Orbiter'' (MRO) is a spacecraft designed to study the geology and climate of Mars, provide reconnaissance of future landing sites, and relay data from surface missions back to Earth. It was launched on August 12, 2005, a ...

(MRO) have indicated the existence of gypsum dunes in the northern polar region of Mars, which were later confirmed at ground level by the

Mars Exploration Rover NASA's Mars Exploration Rover (MER) mission was a robotic space mission involving two Mars rovers, '' Spirit'' and '' Opportunity'', exploring the planet Mars. It began in 2003 with the launch of the two rovers to explore the Martian surface ...

(MER) ''

Opportunity Opportunity may refer to: Places * Opportunity, Montana, an unincorporated community, United States * Opportunity, Nebraska, an unincorporated community, United States * Opportunity, Washington, a former census-designated place, United States * ...

''. File:Lechuguilla Chandelier Ballroom.jpg, Large gypsum crystals in

Lechuguilla Cave At , Lechuguilla Cave is the eighth-longest explored cave in the world and the second deepest () in the continental United States. It is most famous for its unusual geology, rare formations, and pristine condition. The cave is named for the can ...

's "chandelier ballroom" File:Cristales cueva de Naica.JPG, Gypsum crystals in the Cave of the Crystals in Mexico (person at lower right for scale) File:GypsumCrystalsLakeLucerno.jpg, Gypsum crystals formed as the water evaporated in

Lake Lucero Lake Lucero is a playa located within that section of the Tularosa Basin that is contained within White Sands National Park in the U.S. state of New Mexico. The playa is noted for the unusually high quantity of water-deposited and wind-deposit ...

, White Sands National Park File:White Gypsum - geograph.org.uk - 2503198.jpg, Gypsum veins in the silts/marls of the Tea Green and Grey Marls, Blue Anchor,

Somerset ( en, All The People of Somerset) , locator_map = , coordinates = , region = South West England , established_date = Ancient , established_by = , preceded_by = , origin = , lord_lieutenant_office =Lord Lieutenant of Somerset , lor ...

, United Kingdom File:Gypsum layers Caprock Canyons 1.JPG, Gypsum veins in Caprock Canyons State Park and Trailway, Texas File:Yardangs in dunes, White Sands National Park, New Mexico, United States.jpg, Dunes made of small crystals of gypsum, White Sands National Park

Mining

Commercial quantities of gypsum are found in the cities of

Araripina Araripina is a Brazilian municipality in the state of Pernambuco. Has an estimated population in 2020 of 84,864 inhabitants according with IBGE. Total area of 1.847,5 km and is located in the state mesoregion of Sertão, at 622 meters ...

and Grajaú in Brazil; in Pakistan, Jamaica, Iran (world's second largest producer), Thailand, Spain (the main producer in Europe), Germany, Italy, England, Ireland, Canada and the United States. Large open pit quarries are located in many places including

Fort Dodge, Iowa Fort Dodge is a city in, and the county seat of, Webster County, Iowa, United States, along the Des Moines River. The population was 24,871 in the 2020 census, a decrease from 25,136 in 2000. Fort Dodge is a major commercial center for North C ...

, which sits on one of the largest deposits of gypsum in the world, and

Plaster City, California Plaster City is an unincorporated community in Imperial County in the U.S. state of California. It is located west of El Centro, at an elevation of 105 feet (32 m). United States Gypsum operates a large gypsum quarry and plant there a ...

, United States, and East Kutai,

Kalimantan Kalimantan () is the Indonesian portion of the island of Borneo. It constitutes 73% of the island's area. The non-Indonesian parts of Borneo are Brunei and East Malaysia. In Indonesia, "Kalimantan" refers to the whole island of Borneo. In 2019, ...

, Indonesia. Several small mines also exist in places such as Kalannie in

Western Australia Western Australia (commonly abbreviated as WA) is a state of Australia occupying the western percent of the land area of Australia excluding external territories. It is bounded by the Indian Ocean to the north and west, the Southern Ocean to ...

, where gypsum is sold to private buyers for additions of calcium and sulfur as well as reduction of aluminum toxicities on

soil Soil, also commonly referred to as earth or dirt, is a mixture of organic matter, minerals, gases, liquids, and organisms that together support life. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former ...

for agricultural purposes. Crystals of gypsum up to long have been found in the caves of the Naica Mine of

Chihuahua Chihuahua may refer to: Places *Chihuahua (state), a Mexican state **Chihuahua (dog), a breed of dog named after the state **Chihuahua cheese, a type of cheese originating in the state **Chihuahua City, the capital city of the state **Chihuahua Mun ...

, Mexico. The crystals thrived in the cave's extremely rare and stable natural environment. Temperatures stayed at , and the cave was filled with mineral-rich water that drove the crystals' growth. The largest of those crystals weighs and is around 500,000 years old. File:Gypsum-24382.jpg, Golden gypsum crystals from

Winnipeg Winnipeg () is the capital and largest city of the province of Manitoba in Canada. It is centred on the confluence of the Red and Assiniboine rivers, near the longitudinal centre of North America. , Winnipeg had a city population of 749 ...

File:WhiteSandsGypsum.jpg, Gypsum

sand Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a soil texture, textur ...

from

Synthesis

Synthetic Synthetic things are composed of multiple parts, often with the implication that they are artificial. In particular, 'synthetic' may refer to: Science * Synthetic chemical or compound, produced by the process of chemical synthesis * Synthetic o ...

gypsum is produced as a waste product or by-product in a range of industrial processes.

Desulfurization

Flue gas desulfurization gypsum (FGDG) is recovered at some coal-fired power plants. The main contaminants are Mg, K, Cl, F, B, Al, Fe, Si, and Se. They come both from the limestone used in desulfurization and from the coal burned. This product is pure enough to replace natural gypsum in a wide variety of fields including drywalls, water treatment, and cement set retarder. Improvements in flue gas desulfurization have greatly reduced the amount of toxic elements present.

Desalination

Gypsum precipitates onto brackish water

membrane A membrane is a selective barrier; it allows some things to pass through but stops others. Such things may be molecules, ions, or other small particles. Membranes can be generally classified into synthetic membranes and biological membranes. ...

s, a phenomenon known as mineral salt scaling, such as during

brackish Brackish water, sometimes termed brack water, is water occurring in a natural environment that has more salinity than freshwater, but not as much as seawater. It may result from mixing seawater (salt water) and fresh water together, as in estuari ...

water

desalination Desalination is a process that takes away mineral components from saline water. More generally, desalination refers to the removal of salts and minerals from a target substance, as in soil desalination, which is an issue for agriculture. Salt ...

of water with high concentrations of

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...

and

sulfate The sulfate or sulphate ion is a polyatomic ion, polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salt (chemistry), ...

. Scaling decreases membrane life and productivity. This is one of the main obstacles in brackish water membrane desalination processes, such as

reverse osmosis Reverse osmosis (RO) is a water purification process that uses a partially permeable membrane to separate ions, unwanted molecules and larger particles from drinking water. In reverse osmosis, an applied pressure is used to overcome osmotic ...

nanofiltration Nanofiltration is a membrane filtration process used most often to soften and disinfect water. Overview Nanofiltration is a membrane filtration-based method that uses nanometer sized pores through which particles smaller than 10 nanometers pa ...

. Other forms of scaling, such as

calcite Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scra ...

scaling, depending on the water source, can also be important considerations in

distillation Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the he ...

, as well as in

heat exchanger A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct conta ...

s, where either the salt

solubility In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solub ...

concentration In chemistry, concentration is the abundance of a constituent divided by the total volume of a mixture. Several types of mathematical description can be distinguished: '' mass concentration'', '' molar concentration'', '' number concentration'' ...

can change rapidly. A new study has suggested that the formation of gypsum starts as tiny crystals of a mineral called bassanite (). This process occurs via a three-stage pathway: # homogeneous nucleation of nanocrystalline bassanite; # self-assembly of bassanite into aggregates, and # transformation of bassanite into gypsum.

Refinery waste

The production of

phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phosph ...

fertilizers requires breaking down calcium-containing

phosphate rock Phosphorite, phosphate rock or rock phosphate is a non-detrital sedimentary rock that contains high amounts of phosphate minerals. The phosphate content of phosphorite (or grade of phosphate rock) varies greatly, from 4% to 20% phosphorus pentoxi ...

with acid, producing calcium sulfate waste known as

phosphogypsum Phosphogypsum (PG) is the calcium sulfate hydrate formed as a by-product of the production of fertilizer from phosphate rock. It is mainly composed of gypsum (CaSO4·2H2O). Although gypsum is a widely used material in the construction industry, p ...

(PG). This form of gypsum is contaminated by impurities found in the rock, namely

fluoride Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts ...

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is o ...

, radioactive elements such as

radium Radium is a chemical element with the symbol Ra and atomic number 88. It is the sixth element in group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, but it readily reacts with nitrogen (rathe ...

, and heavy metal elements such as

cadmium Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Like zinc, it demonstrates oxidation state +2 in most of ...

. Similarly, production of

titanium dioxide Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is a white solid that is insoluble ...

produces titanium gypsum (TG) due to neutralization of excess acid with lime. The product is contaminated with silica, fluorides, organic matters, and alkalis. Impurities in refinery gypsum waste have, in many cases, prevented them from being used as normal gypsum in fields such as construction. As a result, waste gypsum is stored in stacks indefinitely, with significant risk of leaching their contaminants into water and soil. To reduce the accumulation and ultimately clear out these stacks, research is underway to find more applications for such waste products.

Occupational safety

People can be exposed to gypsum in the workplace by breathing it in, skin contact, and eye contact. Calcium sulfate ''per se'' is nontoxic and is even approved as a food additive, but as powdered gypsum, it can irritate skin and mucous membranes.

United States

The

Occupational Safety and Health Administration The Occupational Safety and Health Administration'' (OSHA ) is a large regulatory agency of the United States Department of Labor that originally had federal visitorial powers to inspect and examine workplaces. Congress established the agenc ...

(OSHA) has set the legal limit (

permissible exposure limit The permissible exposure limit (PEL or OSHA PEL) is a legal limit in the United States for exposure of an employee to a chemical substance or physical agent such as high level noise. Permissible exposure limits are established by the Occupational ...

) for gypsum exposure in the workplace as TWA 15 mg/m³ for total exposure and TWA 5 mg/m³ for respiratory exposure over an 8-hour workday. The

National Institute for Occupational Safety and Health The National Institute for Occupational Safety and Health (NIOSH, ) is the United States federal agency responsible for conducting research and making recommendations for the prevention of work-related injury and illness. NIOSH is part of the ...

(NIOSH) has set a

recommended exposure limit A recommended exposure limit (REL) is an occupational exposure limit that has been recommended by the United States National Institute for Occupational Safety and Health. The REL is a level that NIOSH believes would be protective of worker safet ...

(REL) of TWA 10 mg/m³ for total exposure and TWA 5 mg/m³ for respiratory exposure over an 8-hour workday.

Uses

Geography of Ohio - DPLA - aaba7b3295ff6973b6fd1e23e33cde14 (page 96) (cropped2)

Gypsum is used in a wide variety of applications:

Construction industry

* Gypsum board is primarily used as a finish for walls and ceilings, and is known in construction as plasterboard, "sheetrock", or drywall. Gypsum provides a degree of fire-resistance to these materials and glass fibers are added to their composition to accentuate this effect. Gypsum has little heat conductivity, giving its plaster some insulative properties. *

Gypsum block Gypsum block is a massive lightweight building material composed of solid gypsum, for building and erecting lightweight, fire-resistant, non-load bearing interior walls, partition walls, cavity walls, skin walls, and pillar casing indoors. Gyps ...

s are used like concrete blocks in building construction. *

Gypsum mortar Mortar is a workable paste which hardens to bind building blocks such as stones, bricks, and concrete masonry units, to fill and seal the irregular gaps between them, spread the weight of them evenly, and sometimes to add decorative colors or pa ...

is an ancient mortar used in building construction. *A component of

Portland cement Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th cen ...

used to prevent flash setting (too rapid hardening) of

concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most ...

Agriculture

Fertilizer A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...

: In the late 18th and early 19th centuries, Nova Scotia gypsum, often referred to as plaster, was a highly sought fertilizer for wheat fields in the United States. Gypsum provides two of the secondary plant macronutrients, calcium and sulfur. Unlike limestone, it generally does not affect soil pH. * Reclamation of

saline soils Soil salinity is the salt content in the soil; the process of increasing the salt content is known as salinization. Salts occur naturally within soils and water. Salination can be caused by natural processes such as mineral weathering or by t ...

, regardless of pH. When gypsum is added to sodic (saline) and

acidic soil Soil pH is a measure of the acidity or basicity (alkalinity) of a soil. Soil pH is a key characteristic that can be used to make informative analysis both qualitative and quantitatively regarding soil characteristics. pH is defined as the neg ...

, the highly

soluble In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solub ...

form of boron ( sodium metaborate) is converted to the less soluble

calcium metaborate Calcium is a chemical element with the Symbol (chemistry), symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties ...

. Exchangeable sodium percentage is also reduced by gypsum application. The

Zuiderzee Works The Zuiderzee Works ( nl, Zuiderzeewerken) is a man-made system of dams and dikes, land reclamation and water drainage work, in total the largest hydraulic engineering project undertaken by the Netherlands during the twentieth century. The pro ...

uses gypsum for the recovered land. *Other

soil conditioner A soil conditioner is a product which is added to soil to improve the soil’s physical qualities, usually its fertility (ability to provide nutrition for plants) and sometimes its mechanics. In general usage, the term "soil conditioner" is often ...

uses: Gypsum reduces aluminium and boron toxicity in acidic soils. It also improves soil structure, improving water absorption and aeration. *A wood substitute in the ancient world: For example, when wood became scarce due to deforestation on

Bronze Age The Bronze Age is a historic period, lasting approximately from 3300 BC to 1200 BC, characterized by the use of bronze, the presence of writing in some areas, and other early features of urban civilization. The Bronze Age is the second pri ...

Crete Crete ( el, Κρήτη, translit=, Modern: , Ancient: ) is the largest and most populous of the Greek islands, the 88th largest island in the world and the fifth largest island in the Mediterranean Sea, after Sicily, Sardinia, Cypru ...

, gypsum was employed in building construction at locations where wood was previously used. *Soil

water potential Water potential is the potential energy of water per unit volume relative to pure water in reference conditions. Water potential quantifies the tendency of water to move from one area to another due to osmosis, gravity, mechanical pressure and ...

monitoring: a gypsum block can be inserted into soil, its electrical resistance measured to derive soil moisture.

Modeling, sculpture and art

Plaster Plaster is a building material used for the protective or decorative coating of walls and ceilings and for moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of buildings, while "r ...

for casting moulds and modeling. *As

, a material for sculpture, it was used especially in the ancient world before steel was developed, when its relative softness made it much easier to carve. During the

Middle Ages In the history of Europe, the Middle Ages or medieval period lasted approximately from the late 5th to the late 15th centuries, similar to the post-classical period of global history. It began with the fall of the Western Roman Empire ...

and

Renaissance The Renaissance ( , ) , from , with the same meanings. is a period in European history marking the transition from the Middle Ages to modernity and covering the 15th and 16th centuries, characterized by an effort to revive and surpass id ...

, it was preferred even to

marble Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or dolomite. Marble is typically not foliated (layered), although there are exceptions. In geology, the term ''marble'' refers to metamorpho ...

. *In the medieval period,

scribe A scribe is a person who serves as a professional copyist, especially one who made copies of manuscripts before the invention of automatic printing. The profession of the scribe, previously widespread across cultures, lost most of its promi ...

s and illuminators used it as an ingredient in

gesso Gesso (; "chalk", from the la, gypsum, from el, γύψος) is a white paint mixture consisting of a binder mixed with chalk, gypsum, pigment, or any combination of these. It is used in painting as a preparation for any number of substrates suc ...

, which was applied to illuminated letters and gilded with gold in illuminated manuscripts.

Food and drink

tofu Tofu (), also known as bean curd in English, is a food prepared by coagulating soy milk and then pressing the resulting curds into solid white blocks of varying softness; it can be ''silken'', ''soft'', ''firm'', ''extra firm'' or ''super fi ...

(soy bean curd) coagulant, making it ultimately a significant source of dietary

. *Adding

hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion (mechanical), abrasion. In general, different materials differ in their hardn ...

to water used for

brewing Brewing is the production of beer by steeping a starch source (commonly cereal grains, the most popular of which is barley) in water and fermenting the resulting sweet liquid with yeast. It may be done in a brewery by a commercial brewer, ...

. *Used in baking as a dough conditioner, reducing stickiness, and as a baked-goods source of dietary calcium. The primary component of mineral yeast food. *Used in mushroom cultivation to stop grains from clumping together.

Medicine and cosmetics

for surgical splints. *Impression plasters in dentistry.

Other

*An alternative to iron oxide in some thermite mixes. *Tests have shown that gypsum can be used to remove pollutants such as

lead Lead is a chemical element with the Symbol (chemistry), symbol Pb (from the Latin ) and atomic number 82. It is a heavy metals, heavy metal that is density, denser than most common materials. Lead is Mohs scale of mineral hardness#Intermediate ...

arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, bu ...

from contaminated waters.

Gallery

File:Gypsum-71006.jpg, Green gypsum crystals from Pernatty Lagoon, Mt Gunson,

South Australia South Australia (commonly abbreviated as SA) is a state in the southern central part of Australia. It covers some of the most arid parts of the country. With a total land area of , it is the fourth-largest of Australia's states and territories ...

- its green color is due to presence of

copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish ...

ions. File:Gypsum-162462.jpg, Unusual selenite gypsum from the Red River, Winnipeg, Manitoba, Canada File:Gypsum-47190.jpg, Classic "ram's horn" gypsum from

Santa Eulalia, Chihuahua Santa Eulalia is a town and seat of the municipality of Aquiles Serdán, in the northern Mexican state of Chihuahua. In 2010, the town had a population of 7,135, up from 2,089 in 2005. Founded in 1652 by Diego del Castillo Diego is a Spa ...

, Mexico, 7.5×4.3×3.8 cm File:Roses des Sables Tunisie.jpg, Desert rose, 47 cm long File:Gypsum-53691.jpg, Gypsum from Pernatty Lagoon, Mt Gunson, Stuart Shelf area, Andamooka Ranges - Lake Torrens area, South Australia, Australia File:Copper-Gypsum-203925.jpg, Gypsum with crystalline

native copper Native copper is an uncombined form of copper that occurs as a natural mineral. Copper is one of the few metallic elements to occur in native form, although it most commonly occurs in oxidized states and mixed with other elements. Native copp ...

inside File:Gypsum J1.jpg, Gypsum from Swan Hill, Victoria, Australia. The coloring is due to the copper oxide File:Gypsum-21996.jpg, Waterclear twined crystal of the form known as "Roman sword". Fuentes de Ebro, Zaragoza (Spain) File:Botryogen-Gypsum-199664.jpg, Bright, cherry-red gypsum crystals 2.5 cm in height colored by rich inclusions of the rare mineral botryogen File:Gypse Naica.jpg, Gypsum from Naica, Mun. de Saucillo, Chihuahua, Mexico File:Gypsum-251118.jpg, Golden color gem, "fishtail"-twinned crystals of gypsum sitting atop a "ball" of gypsum which is composed of several single bladed crystals

References

External links

WebMineral data
* * {{Authority control Calcium minerals Sulfate minerals Sedimentary rocks Evaporite Alchemical substances Monoclinic minerals Minerals in space group 15 Alabaster Luminescent minerals Industrial minerals