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Gum base is the non-nutritive, non-digestible, water-insoluble masticatory delivery system used to carry sweeteners, flavors, and any other substances in
chewing gum Chewing gum is a soft, cohesive substance designed to be chewed without being swallowed. Modern chewing gum is composed of gum base, sweeteners, softeners/plasticizers, flavors, colors, and, typically, a hard or powdered polyol coating. Its tex ...
and
bubble gum Bubble gum (or bubblegum) is a type of chewing gum, designed to be inflated out of the mouth as a bubble. Composition In modern chewing gum, if natural rubber such as chicle is used, it must pass several purity and cleanliness tests. However, ...
. It provides all the basic textural and masticatory properties of gum. The actual composition of a gum base is usually a
trade secret A trade secret is a form of intellectual property (IP) comprising confidential information that is not generally known or readily ascertainable, derives economic value from its secrecy, and is protected by reasonable efforts to maintain its conf ...
. In the United States, the
FDA The United States Food and Drug Administration (FDA or US FDA) is a federal agency of the Department of Health and Human Services. The FDA is responsible for protecting and promoting public health through the control and supervision of food ...
allows 46 different chemicals under the umbrella of "gum base". These chemicals are grouped into the following categories. * Synthetic coagulated or concentrated latices: Polymers such as butadiene-styrene,
polyvinyl acetate Polyvinyl acetate (PVA, PVAc, poly(ethenyl ethanoate)), commonly known as wood glue (a term that may also refer to other types of glues), PVA glue, white glue, carpenter's glue, school glue, or Elmer's Glue in the US, is a widely available adh ...
,
polyethylene Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging (plastic bags, plastic films, geomembranes and containers including bott ...
,
paraffin Paraffin may refer to: Substances * Paraffin wax, a white or colorless soft solid (also in liquid form) that is used as a lubricant and for other applications * Liquid paraffin (drug), a very highly refined mineral oil used in cosmetics and for med ...
, and petroleum waxes are the most commonly used gum bases on the market today. They are petroleum-derived polymers which are designed to maximize elasticity and incorporate other components of the gum base as well as flavors and sweeteners in their chemical matrix. * Plasticizing materials (softeners): These materials generally help to emulsify various chemical components that do not always bind to each other. They are generally medium-sized molecules and are frequently esters of tree resins and rosins. * Terpene resins: This specific subcategory is not fundamentally different from materials in the first two categories except it is a specific substance that can be produced both naturally and artificially. * Preservatives: The most common antioxidant preservative in gum, BHT, functions by scavenging
free radicals In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired electron, unpaired valence electron. With some exceptions, these unpaired electrons make radicals highly chemical reaction, chemi ...
(which spoil food) and sequestering them behind its sterically hindering ''tert''-butyl groups. * Natural coagulated or concentrated latices of vegetable origin: These include many of the resins such as
chicle Chicle () is a natural gum traditionally used in making chewing gum and other products. It is collected from several species of Mesoamerican trees in the genus '' Manilkara'', including '' M. zapota'', '' M. chicle'', '' M. staminodella'', and ...
that were traditionally chewed as gum. It also includes natural waxes like
beeswax Bee hive wax complex Beeswax (also known as cera alba) is a natural wax produced by honey bees of the genus ''Apis''. The wax is formed into scales by eight wax-producing glands in the abdominal segments of worker bees, which discard it in o ...
and
latex Latex is an emulsion (stable dispersion) of polymer microparticles in water. Latices are found in nature, but synthetic latices are common as well. In nature, latex is found as a wikt:milky, milky fluid, which is present in 10% of all floweri ...
(natural rubber). These natural sources of gum base have largely been replaced by synthetic, petroleum-derived gum bases. Gum bases for chewing gum are different from those for bubble gum. A bubble gum base is formulated with the ability to blow bubbles; it contains higher levels of
elastomers An elastomer is a polymer with viscoelasticity (i.e. both viscosity and Elasticity (physics), elasticity) and with weak intermolecular forces, generally low Young's modulus (E) and high failure strain compared with other materials. The term, a ...
or higher molecular weight polymers for this purpose. Gum bases for
antacid An antacid is a substance which neutralization (chemistry), neutralizes gastric acid, stomach acidity and is used to relieve heartburn, indigestion, or an upset stomach. Some antacids have been used in the treatment of constipation and diarrhe ...
use
calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
as a filler, while gum bases for acid flavored gum use
talc Talc, or talcum, is a clay mineral composed of hydrated magnesium silicate, with the chemical formula . Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant ...
as a filler, since acids can react with
calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
to produce carbon dioxide gas, which is undesirable. Bubble gum usually contains 15–20% gum base, while chewing gum contains 20–25% gum base and sugar-free chewing gum contains 25–30% gum base. Researchers at the University of Illinois at Urbana–Champaign and at Wm. Wrigley Jr. Company are studying the possibility of making gum base with biodegradable zein (corn protein).Time-intensity study of corn zein chewing gum
Large chewing gum manufacturers generally produce their own gum base in-house while small chewing gum producers usually buy gum base from third-party suppliers.{{cn, date=July 2024


Composition and manufacture

Another way to categorize the various components of gum bases is by their utility in the base. *
Elastomers An elastomer is a polymer with viscoelasticity (i.e. both viscosity and Elasticity (physics), elasticity) and with weak intermolecular forces, generally low Young's modulus (E) and high failure strain compared with other materials. The term, a ...
: provide the elasticity or bounce, and can be natural
latex Latex is an emulsion (stable dispersion) of polymer microparticles in water. Latices are found in nature, but synthetic latices are common as well. In nature, latex is found as a wikt:milky, milky fluid, which is present in 10% of all floweri ...
es (e.g. couma macrocarpa (also called leche caspi or sorva),
loquat The loquat (''Eriobotrya japonica'', Chinese: 枇杷; Pinyin: pípá) is a large evergreen shrub or tree grown commercially for its orange fruit. It is also cultivated as an ornamental plant. The loquat is in the family Rosaceae, subfamily Spi ...
(also called nispero),
tunu Tunu, in Danish Østgrønland ("East Greenland"), was one of the three counties (''amter'') of Greenland until 31 December 2008. The county seat was at the main settlement, Tasiilaq. The county's population in 2005 was around 3,800. The county ...
, jelutong, or
chicle Chicle () is a natural gum traditionally used in making chewing gum and other products. It is collected from several species of Mesoamerican trees in the genus '' Manilkara'', including '' M. zapota'', '' M. chicle'', '' M. staminodella'', and ...
(which is still commercially produced), or synthetic rubbers (e.g. styrene-butadiene rubber,
butyl rubber Butyl rubber, sometimes just called butyl, is a synthetic rubber, a copolymer of isobutylene with isoprene. The abbreviation IIR stands for isobutylene isoprene rubber. Polyisobutylene, also known as "PIB" or polyisobutene, (C4H8)n, is the homop ...
, polyisobutylene). *
Resins A resin is a solid or highly viscous liquid that can be converted into a polymer. Resins may be biological or synthetic in origin, but are typically harvested from plants. Resins are mixtures of organic compounds, predominantly terpenes. Comm ...
: provide a cohesive body or strength, and are most often glycerol esters of gum, terpene resins, and/or
polyvinyl acetate Polyvinyl acetate (PVA, PVAc, poly(ethenyl ethanoate)), commonly known as wood glue (a term that may also refer to other types of glues), PVA glue, white glue, carpenter's glue, school glue, or Elmer's Glue in the US, is a widely available adh ...
. *
Waxes Waxes are a diverse class of organic compounds that are lipophilic, malleable solids near ambient temperatures. They include higher alkanes and lipids, typically with melting points above about 40 °C (104 °F), melting to give low ...
: act as softening agents and are most usually
paraffin Paraffin may refer to: Substances * Paraffin wax, a white or colorless soft solid (also in liquid form) that is used as a lubricant and for other applications * Liquid paraffin (drug), a very highly refined mineral oil used in cosmetics and for med ...
or microcrystalline wax. *
Fat In nutrition science, nutrition, biology, and chemistry, fat usually means any ester of fatty acids, or a mixture of such chemical compound, compounds, most commonly those that occur in living beings or in food. The term often refers specif ...
s: behave as
plasticizers A plasticizer (British English, UK: plasticiser) is a substance that is added to a material to make it softer and more flexible, to increase its plasticity (physics), plasticity, to decrease its viscosity, and/or to decrease friction during its ...
and mainly come from hydrogenated vegetable oils. *
Emulsifiers An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable) owing to liquid-liquid phase separation. Emulsions are part of a more general class of two-phase systems of matter called colloids. Although ...
: help to hydrate, the most common being
lecithin Lecithin ( ; from the Ancient Greek "yolk") is a generic term to designate any group of yellow-brownish fatty substances occurring in animal and plant tissues which are amphiphilic – they attract both water and fatty substances (and so ar ...
or glycerol monostearate. *
Fillers In animal feed, a filler is an ingredient added to provide dietary fiber, bulk or some other non-nutritive purpose. Products like corn fiber (corncobs), fruit fibers (pulp), rice bran, and whole grains are possible fillers. Purpose As source ...
: impart texture and the most commonly used are
calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
or
talc Talc, or talcum, is a clay mineral composed of hydrated magnesium silicate, with the chemical formula . Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant ...
. *
Antioxidants Antioxidants are Chemical compound, compounds that inhibit Redox, oxidation, a chemical reaction that can produce Radical (chemistry), free radicals. Autoxidation leads to degradation of organic compounds, including living matter. Antioxidants ...
: protect from oxidation and extend shelf-life; the most common type is BHT. Old gum bases were based on either natural elastomers such as
latex Latex is an emulsion (stable dispersion) of polymer microparticles in water. Latices are found in nature, but synthetic latices are common as well. In nature, latex is found as a wikt:milky, milky fluid, which is present in 10% of all floweri ...
es, vegetable gums like
chicle Chicle () is a natural gum traditionally used in making chewing gum and other products. It is collected from several species of Mesoamerican trees in the genus '' Manilkara'', including '' M. zapota'', '' M. chicle'', '' M. staminodella'', and ...
,
spruce gum Spruce gum is a chewing material made from the resin of spruce trees. In North America, spruce resin was chewed by Native Americans and was later introduced to the early American pioneers and was sold commercially by the 19th century, by John B. ...
, and mastic gum, or alternatively on waxes, e.g.
paraffin wax Paraffin wax (or petroleum wax) is a soft colorless solid derived from petroleum, coal, or oil shale that consists of a mixture of hydrocarbon molecules containing between 20 and 40 carbon atoms. It is solid at room temperature and melting poi ...
and
beeswax Bee hive wax complex Beeswax (also known as cera alba) is a natural wax produced by honey bees of the genus ''Apis''. The wax is formed into scales by eight wax-producing glands in the abdominal segments of worker bees, which discard it in o ...
, but today synthetic rubbers are preferred.


See also

* Gums and Stabilisers for the Food Industry, a conference series about title subject *
Bubblegum Bubble gum (or bubblegum) is a type of chewing gum, designed to be inflated out of the mouth as a bubble. Composition In modern chewing gum, if natural rubber such as chicle is used, it must pass several purity and cleanliness tests. However, ...
*
Chewing gum Chewing gum is a soft, cohesive substance designed to be chewed without being swallowed. Modern chewing gum is composed of gum base, sweeteners, softeners/plasticizers, flavors, colors, and, typically, a hard or powdered polyol coating. Its tex ...
* Functional chewing gum * Chewing gum industry * List of chewing gum brands


References


Formulation and Production of Chewing and Bubble Gum
', edited by Doug Fritz, pp 93–118, Olivias's Publications Ltd, London, UK, 2006 Confectionery Chewing gum