Gum Arabic Tree
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Gum arabic, also known as gum sudani, acacia gum, Arabic gum, gum acacia, acacia, Senegal gum, Indian gum, and by other names, is a
natural gum Natural gums are polysaccharides of natural origin, capable of causing a large increase in a solution's viscosity, even at small concentrations. They are mostly botanical gums, found in the woody elements of plants or in seed coatings. Human u ...
originally consisting of the hardened sap of two species of the ''
Acacia ''Acacia'', commonly known as the wattles or acacias, is a large genus of shrubs and trees in the subfamily Mimosoideae of the pea family Fabaceae. Initially, it comprised a group of plant species native to Africa and Australasia. The genus na ...
'' tree, ''
Senegalia senegal ''Senegalia senegal'' (also known as ''Acacia senegal'') is a small thorny deciduous tree from the genus ''Senegalia'', which is known by several common names, including gum acacia, gum arabic tree, Sudan gum and Sudan gum arabic. In parts of In ...
'' and ''
Vachellia seyal ''Vachellia seyal'', the red acacia, known also as the shittah tree (the source of shittim wood), is a thorny, 6– to 10-m-high (20 to 30 ft) tree with a pale greenish or reddish bark. At the base of the feathery leaves, two straight, light ...
.'' The term "gum arabic" does not legally indicate a particular botanical source, however. The gum is harvested commercially from wild trees, mostly in
Sudan Sudan ( or ; ar, السودان, as-Sūdān, officially the Republic of the Sudan ( ar, جمهورية السودان, link=no, Jumhūriyyat as-Sūdān), is a country in Northeast Africa. It shares borders with the Central African Republic t ...
(80%) and throughout the
Sahel The Sahel (; ar, ساحل ' , "coast, shore") is a region in North Africa. It is defined as the ecoclimatic and biogeographic realm of transition between the Sahara to the north and the Sudanian savanna to the south. Having a hot semi-arid c ...
, from Senegal to Somalia. The name "gum Arabic" (''al-samgh al-'arabi'') was used in the Middle East at least as early as the 9th century. Gum arabic first found its way to Europe via Arabic ports, so retained its name. Gum arabic is a complex
mixture In chemistry, a mixture is a material made up of two or more different chemical substances which are not chemically bonded. A mixture is the physical combination of two or more substances in which the identities are retained and are mixed in the ...
of
glycoprotein Glycoproteins are proteins which contain oligosaccharide chains covalently attached to amino acid side-chains. The carbohydrate is attached to the protein in a cotranslational or posttranslational modification. This process is known as glycos ...
s and
polysaccharide Polysaccharides (), or polycarbohydrates, are the most abundant carbohydrates found in food. They are long chain polymeric carbohydrates composed of monosaccharide units bound together by glycosidic linkages. This carbohydrate can react with wa ...
s, predominantly polymers of
arabinose Arabinose is an aldopentose – a monosaccharide containing five carbon atoms, and including an aldehyde (CHO) functional group. For biosynthetic reasons, most saccharides are almost always more abundant in nature as the "D"-form, or structurally ...
and galactose. It is soluble in water, edible, and used primarily in the
food industry The food industry is a complex, global network of diverse businesses that supplies most of the food consumed by the world's population. The food industry today has become highly diversified, with manufacturing ranging from small, traditiona ...
and soft-drink industry as a stabilizer, with
E number E numbers ("E" stands for "Europe") are codes for substances used as food additives, including those found naturally in many foods such as vitamin C, for use within the European Union (EU) and European Free Trade Association (EFTA). Commonly ...
E414 (I414 in the US). Gum arabic is a key ingredient in traditional lithography and is used in printing,
paint Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...
s,
glue Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advant ...
s,
cosmetic Cosmetic may refer to: *Cosmetics, or make-up, substances to enhance the beauty of the human body, apart from simple cleaning *Cosmetic, an adjective describing beauty, aesthetics, or appearance, especially concerning the human body *Cosmetic, a t ...
s, and various industrial applications, including viscosity control in
ink Ink is a gel, sol, or solution that contains at least one colorant, such as a dye or pigment, and is used to color a surface to produce an image, text, or design. Ink is used for drawing or writing with a pen, brush, reed pen, or quill. Thi ...
s and in textile industries, though less expensive materials compete with it for many of these roles.


Definition

Gum arabic was defined by the 31st Codex Committee for Food Additives, held at The Hague from 19 to 23 March 1999, as the dried exudate from the trunks and branches of ''Acacia senegal'' or ''Vachellia (Acacia) seyal'' in the family Fabaceae (Leguminosae). A 2017 safety re-evaluation by the Panel on Food Additives and Nutrient Sources of the European Food Safety Authority (EFSA) said that although the above definition holds true for most internationally-traded samples, the term "gum arabic" does not indicate a particular botanical source; in a few cases, so‐called "gum arabic" may not even have been collected from ''Acacia'' (in the broad sense) species, instead coming from e.g. '' Combretum'' or '' Albizia''.


Health benefits

Gum arabic is a rich source of dietary fibers and in addition to its widespread use in food and pharmaceutical industries as a safe thickener, emulsifier, and stabilizer, it also possesses a broad range of health benefits that have been evidently proved through several ''in vitro'' and ''in vivo'' studies. Gum arabic is not degraded in the stomach but fermented in the large intestine into a number of short chain fatty acids. It is regarded as a prebiotic that enhances the growth and proliferation of the beneficial intestinal microbiota and therefore its intake is associated with many useful health effects. These health benefits include: * Improved absorption of calcium from the gastrointestinal tract * Anti-diabetic * Anti-obesity (gum arabic lowers the
body mass index Body mass index (BMI) is a value derived from the mass (weight) and height of a person. The BMI is defined as the body mass divided by the square of the body height, and is expressed in units of kg/m2, resulting from mass in kilograms and he ...
and body fat percentage) * Lipid lowering potential (gum arabic decreases total cholesterol, LDL, and triglyceride) * Antioxidant activities * Kidney and liver support * Immune function ''via'' modulating the release of some inflammatory mediators * Prebiotic improving the intestinal barrier function, preventing colon cancer, and alleviating symptoms of irritable bowel diseases * In rats, a protective effect on the intestine against the adverse actions of the NSAID drug meloxicam


Uses

Gum arabic's
mixture In chemistry, a mixture is a material made up of two or more different chemical substances which are not chemically bonded. A mixture is the physical combination of two or more substances in which the identities are retained and are mixed in the ...
of polysaccharides and glycoproteins gives it the properties of a glue and binder that is edible by humans. Other substances have replaced it where toxicity is not an issue, as the proportions of the various chemicals in gum arabic vary widely and make it unpredictable. Still, it remains an important ingredient in
soft drink A soft drink (see § Terminology for other names) is a drink that usually contains water (often carbonated), a sweetener, and a natural and/or artificial flavoring. The sweetener may be a sugar, high-fructose corn syrup, fruit juice, a su ...
syrup and "hard" gummy candies such as gumdrops, marshmallows, and M&M's chocolate candies. For
artist An artist is a person engaged in an activity related to creating art, practicing the arts, or demonstrating an art. The common usage in both everyday speech and academic discourse refers to a practitioner in the visual arts only. However, th ...
s, it is the traditional binder in watercolor
paint Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...
and in photography for gum printing, and it is used as a binder in pyrotechnic compositions. Pharmaceutical drugs and cosmetics also use the gum as a binder,
emulsifier An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable) owing to liquid-liquid phase separation. Emulsions are part of a more general class of two-phase systems of matter called colloids. Altho ...
, and suspending agent or viscosity-increasing agent. Wine makers have used gum arabic as a wine
fining agent Finings are substances that are usually added at or near the completion of the processing of brewing wine, beer, and various nonalcoholic juice beverages. They are used to remove organic compounds, either to improve clarity or adjust flavor or a ...
. It is an important ingredient in
shoe polish Shoe polish (or boot polish) is a waxy paste, cream, or liquid that is used to polish, shine, and waterproof leather shoes or boots to extend the footwear's life and restore its appearance. Shoe polishes are distinguished by their textures, ...
, and can be used in making homemade incense cones. It is also used as a lickable
adhesive Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advant ...
, for example on postage stamps,
envelopes An envelope is a common packaging item, usually made of thin, flat material. It is designed to contain a flat object, such as a letter or card. Traditional envelopes are made from sheets of paper cut to one of three shapes: a rhombus, a shor ...
, and
cigarette papers Rolling paper is a specialty paper used for making cigarettes (commercially manufactured filter cigarettes and individually made roll-your-own cigarettes). Rolling papers are packs of several cigarette-size sheets, often folded inside a cardbo ...
. Lithographic printers employ it to keep the non-image areas of the plate receptive to water. This treatment also helps to stop oxidation of aluminium printing plates in the interval between processing of the plate and its use on a printing press.


Food

Gum arabic is used in the food industry as a stabiliser, emulsifying agent, and thickening agent in icing, fillings, soft candy, chewing gum, and other
confectionery Confectionery is the art of making confections, which are food items that are rich in sugar and carbohydrates. Exact definitions are difficult. In general, however, confectionery is divided into two broad and somewhat overlapping categories ...
, and to bind the sweeteners and flavourings in soft drinks. A solution of sugar and gum arabic in water, gomme syrup, is sometimes used in cocktails to prevent the sugar from crystallising and provide a smooth texture. Gum arabic is a complex
polysaccharide Polysaccharides (), or polycarbohydrates, are the most abundant carbohydrates found in food. They are long chain polymeric carbohydrates composed of monosaccharide units bound together by glycosidic linkages. This carbohydrate can react with wa ...
and soluble
dietary fibre Dietary fiber (in British English fibre) or roughage is the portion of plant-derived food that cannot be completely broken down by human digestive enzymes. Dietary fibers are diverse in chemical composition, and can be grouped generally by the ...
that is generally recognized as safe for human consumption. An indication of harmless
flatulence Flatulence, in humans, is the expulsion of gas from the intestines via the anus, commonly referred to as farting. "Flatus" is the medical word for gas generated in the stomach or bowels. A proportion of intestinal gas may be swallowed environm ...
occurs in some people taking large doses of 30 g (1 oz) or more per day. It is not degraded in the intestine, but fermented in the colon under the influence of microorganisms; it is a prebiotic (as distinct from a probiotic). No regulatory or scientific consensus has been reached about its
caloric value Caloric is a brand of kitchen appliances, which dates back to 1903. History Caloric Corporation began as the Klein Stove Company in Philadelphia in 1890. The Caloric brand was introduced in 1903. It was reorganized in 1946 as the Caloric Stove C ...
; an upper limit of 2 kcal/g was set for rats, but this is not valid for humans. The US
FDA The United States Food and Drug Administration (FDA or US FDA) is a federal agency of the Department of Health and Human Services. The FDA is responsible for protecting and promoting public health through the control and supervision of food s ...
initially set a value of 4 kcal/g for food labelling, but in Europe no value was assigned for soluble dietary fibre. A 1998 review concluded that "based on present scientific knowledge, only an arbitrary value can be used for regulatory purposes". In 2008, the USFDA sent a letter of no objection in response to an application to reduce the rated caloric value of gum arabic to 1.7 kcal/g.


Painting and art

Gum arabic is used as a binder for watercolor painting because it dissolves easily in water. Pigment of any color is suspended within the acacia gum in varying amounts, resulting in watercolor paint. Water acts as a vehicle or a diluent to thin the watercolor paint and helps to transfer the paint to a surface such as paper. When all moisture evaporates, the acacia gum typically does not bind the pigment to the paper surface, but is totally absorbed by deeper layers. If little water is used, after evaporation, the acacia gum functions as a true binder in a paint film, increasing luminosity and helping prevent the colors from lightening. Gum arabic allows more subtle control over washes, because it facilitates the dispersion of the pigment particles. In addition, acacia gum slows evaporation of water, giving slightly longer working time. The addition of a little gum arabic to watercolor pigment and water allows for easier lifting of pigment from paper, thus can be a useful tool when lifting out color when painting in watercolor.


Ceramics

Gum arabic has a long history as additives to ceramic glazes. It acts as a binder, helping the glaze adhere to the clay before it is fired, thereby minimising damage by handling during the manufacture of the piece. As a secondary effect, it also acts as a
deflocculant Flocculation, in the field of chemistry, is a process by which colloidal particles come out of suspension to sediment under the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from p ...
, increasing the fluidity of the glaze mixture, but also making it more likely to sediment out into a hard cake if not used for a while. The gum is normally made up into a solution in hot water (typically 10–25 g/L; ¼ to ½ oz per pint), and then added to the glaze solution after any ball milling in concentrations from 0.02% to 3.0% of gum arabic to the dry weight of the glaze. On firing, the gum burns out at a low temperature, leaving no residues in the glaze. More recently, particularly in commercial manufacturing, gum arabic is often replaced by more refined and consistent alternatives, such as
carboxymethyl cellulose Carboxymethyl cellulose (CMC) or cellulose gum is a cellulose derivative with carboxymethyl groups (-CH2-COOH) bound to some of the hydroxyl groups of the glucopyranose monomers that make up the cellulose backbone. It is often used as its sodiu ...
.


Photography

The historical photography process of gum bichromate photography uses gum arabic mixed with
ammonium The ammonium cation is a positively-charged polyatomic ion with the chemical formula or . It is formed by the protonation of ammonia (). Ammonium is also a general name for positively charged or protonated substituted amines and quaternary a ...
or potassium dichromate and pigment to create a coloured photographic emulsion that becomes relatively insoluble in water upon exposure to ultraviolet light. In the final print, the acacia gum permanently binds the pigments onto the paper.


Printmaking

Gum arabic is also used to protect and etch an image in lithographic processes, both from traditional stones and aluminum plates. In lithography, gum by itself may be used to etch very light tones, such as those made with a number-five crayon. Phosphoric, nitric, or tannic acid is added in varying concentrations to the acacia gum to etch the darker tones up to dark blacks. The etching process creates a gum adsorb layer within the matrix that attracts water, ensuring that the oil-based ink does not stick to those areas. Gum is also essential to what is sometimes called paper lithography, printing from an image created by a laser printer or photocopier.


Pyrotechnics

Gum arabic is also used as a water-soluble binder in fireworks composition.


Fuel charcoal

Gum arabic is used as a binding agent in the making of
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...
as a fuel. Charcoal made from the taifa plant is powdery, and so in order to form charcoal cakes, gum arabic is mixed with this powder and allowed to dry. Fuel charcoal made from taifa and gum arabic is used for cooking food in Senegal and a few other African countries.


Composition

Arabinogalactan is a biopolymer consisting of arabinose and galactose monosaccharides. It is a major component of many plant gums, including gum arabic. 8-5' Noncyclic diferulic acid has been identified as covalently linked to carbohydrate moieties of the arabinogalactan-protein fraction.


Production

While gum arabic has been harvested in Arabia,
Sudan Sudan ( or ; ar, السودان, as-Sūdān, officially the Republic of the Sudan ( ar, جمهورية السودان, link=no, Jumhūriyyat as-Sūdān), is a country in Northeast Africa. It shares borders with the Central African Republic t ...
, and West Asia since antiquity, sub-Saharan acacia gum has a long history as a prized export. The gum exported came from the band of acacia trees that once covered much of the Sahel region, the southern littoral of the Sahara Desert that runs from the Atlantic Ocean to the Red Sea. Today, the main populations of gum-producing ''Acacia'' species are found in
Mauritania Mauritania (; ar, موريتانيا, ', french: Mauritanie; Berber: ''Agawej'' or ''Cengit''; Pulaar: ''Moritani''; Wolof: ''Gànnaar''; Soninke:), officially the Islamic Republic of Mauritania ( ar, الجمهورية الإسلامية ...
, Senegal, Mali, Burkina Faso, Niger, Nigeria,
Chad Chad (; ar, تشاد , ; french: Tchad, ), officially the Republic of Chad, '; ) is a landlocked country at the crossroads of North and Central Africa. It is bordered by Libya to the north, Sudan to the east, the Central African Republic ...
, Cameroon, Sudan,
Eritrea Eritrea ( ; ti, ኤርትራ, Ertra, ; ar, إرتريا, ʾIritriyā), officially the State of Eritrea, is a country in the Horn of Africa region of Eastern Africa, with its capital and largest city at Asmara. It is bordered by Ethiopia ...
, Somalia, Ethiopia, Kenya, and Tanzania. ''Acacia'' is tapped for gum by stripping bits off the bark, from which gum then exudes. Traditionally harvested by seminomadic desert pastoralists in the course of their transhumance cycle, acacia gum remains a main export of several African nations, including Mauritania, Niger, Chad, and Sudan. Total world gum arabic exports are today (2019) estimated at 160,000 tonnes, having recovered from 1987 to 1989 and 2003–2005 crises caused by the destruction of trees by the desert locust.


History


Political aspects


West Africa

In 1445, Prince
Henry the Navigator ''Dom'' Henrique of Portugal, Duke of Viseu (4 March 1394 – 13 November 1460), better known as Prince Henry the Navigator ( pt, Infante Dom Henrique, o Navegador), was a central figure in the early days of the Portuguese Empire and in the 15t ...
set up a trading post on
Arguin Arguin ( ar, أرغين, pt, Arguim) is an island off the western coast of Mauritania in the Bay of Arguin. It is approximately in size, with extensive and dangerous reefs around it. The island is now part of the Banc d'Arguin National Park. H ...
Island (off the coast of modern Mauritania), which acquired acacia gum and
slaves Slavery and enslavement are both the state and the condition of being a slave—someone forbidden to quit one's service for an enslaver, and who is treated by the enslaver as property. Slavery typically involves slaves being made to perf ...
for Portugal. With the merger of the Portuguese and Spanish crowns in 1580, the Spaniards became the dominant influence along the coast. In 1638, however, they were replaced by the Dutch, who were the first to begin exploiting the acacia gum trade. Produced by the acacia trees of
Trarza Trarza ( ar, ولاية الترارزة) is a region in southwest Mauritania. Its capital is Rosso. Other major cities and towns include Mederdra and Boutilimit. Trarza borders the regions of Inchiri and Adrar to the north, Brakna to the east, an ...
and Brakna, this acacia gum was considered superior to that previously obtained in Arabia. By 1678, the French had driven out the Dutch and established a permanent settlement at Saint Louis at the mouth of the Senegal River. Gum Arabic came to play an essential role in textile printing and therefore in pre-industrial economies of France, Great-Britain and other European countries. Throughout the 18th century, their competition over the commodity was so fierce, that some have referred to it as the gum wars. For much of the 18th and 19th centuries, gum arabic was the major export from French and British trading colonies in modern Senegal and Mauritania. West Africa had become the sole supplier of world acacia gum by the 18th century, and its export at the French colony of Saint-Louis doubled in the decade of 1830 alone. A threat to bypass Saint-Louis by sending gum to the British traders at
Portendick Portendick is an abandoned coastal city in western Mauritania. It was located in the Ouad Naga Department of Trarza Region. During the 17th and 18th centuries, Portendick had a significant port for the gum arabic Gum arabic, also known as ...
, and taxes, eventually brought the Emirate of Trarza into direct conflict with the French. In the 1820s, the French launched the
Franco-Trarzan War of 1825 The Franco-Trarzan War of 1825 was a conflict between the forces of the new emir of Trarza, Muhammad al Habib, and France, ruled at the time by Charles X and the ultra comte de Villèle. In 1825, Muhammad attempted to establish control over the ...
. The new emir, Muhammad al Habib, had signed an agreement with the Waalo Kingdom, directly to the south of the river. In return for an end to raids in Waalo territory, the Emir took the heiress of Waalo as a bride. The prospect that Trarza might inherit control of both banks of the Senegal struck at the security of French traders, and the French responded by sending a large expeditionary force that crushed Muhammad's army. The war incited the French to expand to the north of the Senegal River for the first time, heralding French direct involvement in the interior of West Africa. Africa continued to export gum arabic in large quantities—from the Sahel areas of
French West Africa French West Africa (french: Afrique-Occidentale française, ) was a federation of eight French colonial territories in West Africa: Mauritania, Senegal, French Sudan (now Mali), French Guinea (now Guinea), Ivory Coast, Upper Volta (now Burki ...
(modern Senegal, Mauritania, Mali, Burkina Faso, and Niger) and French Equatorial Africa (modern Chad) until these nations gained their independence in 1959–61.


Sudan

Hundreds of thousands of Sudanese people are dependent on gum arabic for their livelihoods. After market reforms, Sudan's exports of gum arabic are now (2019) at about 160,000 tonnes. The production of gum arabic is heavily controlled by the Sudanese government.


Pharmacology

Gum arabic slows the rate of absorption of some drugs, including amoxicillin, from the gut.


Symbolic value

In the work of Shakespeare, Jacob Cats and many other European poets of the 13th to 17th centuries, gum arabic represented the "noble Orient". In the Sahel, it is a symbol of the purity of youth.


See also

*
Mastic (plant resin) Mastic ( el, Μαστίχα) is a resin obtained from the mastic tree (''Pistacia lentiscus''). It is also known as tears of Chios, being traditionally produced on the island Chios, and, like other natural resins, is produced in "tears" or dropl ...


References


External links


Kew Species Profile: ''Acacia senegal'' (gum arabic)Story on gum arabic, its production, and use in industry
from NPR {{Non-timber forest products Agricultural products of Africa Food ingredients Crops Natural gums Agriculture in Sudan Agriculture in Niger Agriculture in Chad Agriculture in Mauritania Agriculture in Senegal Agriculture in Nigeria Excipients Food stabilizers E-number additives