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Gradient-index (GRIN) optics is the branch of
optics Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultraviole ...
covering optical effects produced by a
gradient In vector calculus, the gradient of a scalar-valued differentiable function of several variables is the vector field (or vector-valued function) \nabla f whose value at a point p is the "direction and rate of fastest increase". If the gradi ...
of the
refractive index In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, or ...
of a material. Such gradual variation can be used to produce lenses with flat surfaces, or lenses that do not have the aberrations typical of traditional spherical lenses. Gradient-index lenses may have a refraction gradient that is spherical, axial, or radial.


In nature

The lens of the
eye Eyes are organs of the visual system. They provide living organisms with vision, the ability to receive and process visual detail, as well as enabling several photo response functions that are independent of vision. Eyes detect light and conv ...
is the most obvious example of gradient-index optics in nature. In the
human eye The human eye is a sensory organ, part of the sensory nervous system, that reacts to visible light and allows humans to use visual information for various purposes including seeing things, keeping balance, and maintaining circadian rhythm. ...
, the
refractive index In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, or ...
of the lens varies from approximately 1.406 in the central layers down to 1.386 in less dense layers of the lens. This allows the eye to image with good resolution and low aberration at both short and long distances. Another example of gradient index optics in nature is the common
mirage A mirage is a naturally-occurring optical phenomenon in which light rays bend via refraction to produce a displaced image of distant objects or the sky. The word comes to English via the French ''(se) mirer'', from the Latin ''mirari'', meanin ...
of a pool of water appearing on a road on a hot day. The pool is actually an image of the sky, apparently located on the road since light rays are being refracted (bent) from their normal straight path. This is due to the variation of refractive index between the hot, less dense air at the surface of the road, and the denser cool air above it. The variation in temperature (and thus density) of the air causes a gradient in its refractive index, causing it to increase with height.Tsiboulia, A B (2003). "Gradient Index (GRIN) Lenses". In Ronald G. Driggers. ''Encyclopedia of Optical Engineering'', Volume 1. New York, NY: Marcel Dekker. 675-683. . This index gradient causes refraction of light rays (at a shallow angle to the road) from the sky, bending them into the eye of the viewer, with their apparent location being the road's surface. The Earth's atmosphere acts as a GRIN lens, allowing observers to see the sun for a few minutes after it is actually below the horizon, and observers can also view stars that are below the horizon. This effect also allows for observation of electromagnetic signals from satellites after they have descended below the horizon, as in radio occultation measurements.


Applications

The ability of GRIN lenses to have flat surfaces simplifies the mounting of the lens, which makes them useful where many very small lenses need to be mounted together, such as in
photocopier A photocopier (also called copier or copy machine, and formerly Xerox machine, the generic trademark) is a machine that makes copies of documents and other visual images onto paper or plastic film quickly and cheaply. Most modern photocopiers u ...
s and scanners. The flat surface also allows a GRIN lens to be easily optically aligned to a
fiber Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate ...
, to produce collimated output, making it applicable for
endoscopy An endoscopy is a procedure used in medicine to look inside the body. The endoscopy procedure uses an endoscope to examine the interior of a hollow organ or cavity of the body. Unlike many other medical imaging techniques, endoscopes are insert ...
as well as for ''in vivo''
calcium imaging Calcium imaging is a microscopy technique to optically measure the calcium (Ca2+) status of an isolated cell, tissue or medium. Calcium imaging takes advantage of calcium indicators, fluorescent molecules that respond to the binding of Ca2+ ions b ...
and optogenetic stimulation in brain. In imaging applications, GRIN lenses are mainly used to reduce aberrations. The design of such lenses involves detailed calculations of aberrations as well as efficient manufacture of the lenses. A number of different materials have been used for GRIN lenses including optical glasses, plastics,
germanium Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors s ...
,
zinc selenide Zinc selenide (ZnSe) is a light-yellow, solid compound comprising zinc (Zn) and selenium (Se). It is an intrinsic semiconductor with a band gap of about 2.70  eV at . ZnSe rarely occurs in nature, and is found in the mineral that was named af ...
, and
sodium chloride Sodium chloride , commonly known as salt (although sea salt also contains other chemical salts), is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. With molar masses of 22.99 and 35.45 g ...
. Certain optical fibres ( graded-index fibres) are made with a radially-varying refractive index profile; this design strongly reduces the
modal dispersion Modal dispersion is a distortion mechanism occurring in multimode fibers and other waveguides, in which the signal is spread in time because the propagation velocity of the optical signal is not the same for all modes. Other names for this phenom ...
of a multi-mode optical fiber. The radial variation in refractive index allows for a sinusoidal height distribution of rays within the fibre, preventing the rays from leaving the core. This differs from traditional optical fibres, which rely on
total internal reflection Total internal reflection (TIR) is the optical phenomenon in which waves arriving at the interface (boundary) from one medium to another (e.g., from water to air) are not refracted into the second ("external") medium, but completely reflected b ...
, in that all modes of the GRIN fibres propagate at the same speed, allowing for a higher temporal bandwidth for the fibre. Antireflection coatings are typically effective for narrow ranges of frequency or angle of incidence. Graded-index materials are less constrained. A axial gradient lens has been used to concentrate sunlight onto solar cells, capturing as much as 90% of incident light when the sun is not at an optimal angle.


Manufacture

GRIN lenses are made by several techniques: *
Neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons beh ...
irradiation –
Boron Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has th ...
-rich glass is bombarded with neutrons to cause a change in the boron concentration, and thus the refractive index of the lens. * Chemical vapour deposition – Involving the deposition of different glass with varying refractive indexes, onto a surface to produce a cumulative refractive change. * Partial polymerisation – An organic
monomer In chemistry, a monomer ( ; ''mono-'', "one" + '' -mer'', "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or three-dimensional network in a process called polymerization. Classification Mo ...
is partially polymerized using
ultraviolet light Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30  PHz) to 400 nm (750  THz), shorter than that of visible light, but longer than X-rays. UV radiation i ...
at varying intensities to give a refractive gradient. * Ion exchange – Glass is immersed into a liquid melt with
lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid el ...
ions. As a result of
diffusion Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical p ...
,
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
ions in the glass are partially exchanged with lithium ones, with a larger amount of exchange occurring at the edge. Thus the sample obtains a gradient material structure and a corresponding gradient of the refractive index. * Ion stuffing –
Phase Phase or phases may refer to: Science *State of matter, or phase, one of the distinct forms in which matter can exist *Phase (matter), a region of space throughout which all physical properties are essentially uniform * Phase space, a mathematic ...
separation of a specific glass causes pores to form, which can later be filled using a variety of
salt Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quantitie ...
s or concentration of salts to give a varying gradient. *
Direct laser writing Multiphoton lithography (also known as direct laser lithography or direct laser writing) of polymer templates has been known for years by the photonic crystal community. Similar to standard photolithography techniques, structuring is accomplished ...
– While point-by-point exposing the pre-designed structure an exposure dose is varied (scanning speed, laser power, etc.). This corresponds to spatially tunable monomer-to-polymer degree-of-conversion resulting to a different refractive index. The method is applicable to free-form micro-optical elements and multi-component optics.


History

In 1854, J C Maxwell suggested a lens whose refractive index distribution would allow for every region of space to be sharply imaged. Known as the ''Maxwell fisheye lens'', it involves a spherical index function and would be expected to be spherical in shape as well. This lens, however, is impractical to make and has little usefulness since only points on the surface and within the lens are sharply imaged and extended objects suffer from extreme aberrations. In 1905, R. W. Wood used a dipping technique creating a gelatin cylinder with a refractive index gradient that varied symmetrically with the radial distance from the axis. Disk-shaped slices of the cylinder were later shown to have plane faces with radial index distribution. He showed that even though the faces of the lens were flat, they acted like converging and diverging lens depending on whether the index was a decreasing or increasing relative to the radial distance. In 1964, a posthumous book of R. K. Luneburg was published in which he described a lens that focuses incident parallel rays of light onto a point on the opposite surface of the lens. This also limited the applications of the lens because it was difficult to use it to focus visible light; however, it had some usefulness in
microwave Microwave is a form of electromagnetic radiation with wavelengths ranging from about one meter to one millimeter corresponding to frequencies between 300 MHz and 300 GHz respectively. Different sources define different frequency ran ...
applications. Some years later several new techniques have been developed to fabricate lenses of the Wood type. Since then at least the thinner GRIN lenses can possess surprisingly good imaging properties considering their very simple mechanical construction, while thicker GRIN lenses found application e.g. in Selfoc rods.


Theory

An inhomogeneous gradient-index lens possesses a refractive index whose change follows the function n=f(x,y,z) of the coordinates of the region of interest in the medium. According to Fermat's principle, the light path integral (''L''), taken along a ray of light joining any two points of a
medium Medium may refer to: Science and technology Aviation *Medium bomber, a class of war plane * Tecma Medium, a French hang glider design Communication * Media (communication), tools used to store and deliver information or data * Medium of ...
, is
stationary In addition to its common meaning, stationary may have the following specialized scientific meanings: Mathematics * Stationary point * Stationary process * Stationary state Meteorology * A stationary front is a weather front that is not moving ...
relative to its value for any nearby curve joining the two points. The light path integral is given by the equation :L=\int_^n\,ds, where ''n'' is the refractive index and ''S'' is the arc length of the curve. If Cartesian coordinates are used, this equation is modified to incorporate the change in arc length for a spherical gradient, to each physical dimension: :L=\int_^n(x,y,z)\sqrt\, ds where prime corresponds to d/d''s.'' The light path integral is able to characterize the path of light through the lens in a qualitative manner, such that the lens may be easily reproduced in the future. The refractive index gradient of GRIN lenses can be mathematically modelled according to the method of production used. For example, GRIN lenses made from a radial gradient index material, such as SELFOC Microlens, have a refractive index that varies according to: :n_=n_\left ( 1-\frac \right ), where ''n''''r'' is the refractive index at a distance, ''r'', from the
optical axis An optical axis is a line along which there is some degree of rotational symmetry in an optical system such as a camera lens, microscope or telescopic sight. The optical axis is an imaginary line that defines the path along which light propagat ...
; ''n''o is the design index on the optical axis, and ''A'' is a positive constant.


See also

* Graded-index fiber


References

{{Glass science Optics Fiber optics Glass engineering and science