Goslarite
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Goslarite is a
hydrated Drinking is the act of ingesting water or other liquids into the body through the mouth, proboscis, or elsewhere. Humans drink by swallowing, completed by peristalsis in the esophagus. The physiological processes of drinking vary widely among o ...
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
sulfate mineral The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary mine ...
() which was first found in the Rammelsberg mine,
Goslar Goslar (; Eastphalian: ''Goslär'') is a historic town in Lower Saxony, Germany. It is the administrative centre of the district of Goslar and located on the northwestern slopes of the Harz mountain range. The Old Town of Goslar and the Mines ...
,
Harz The Harz () is a highland area in northern Germany. It has the highest elevations for that region, and its rugged terrain extends across parts of Lower Saxony, Saxony-Anhalt, and Thuringia. The name ''Harz'' derives from the Middle High German ...
,
Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
. It was described in 1847. Goslarite belongs to the
epsomite Epsomite, Epsom salt, or magnesium sulfate heptahydrate, is a hydrous magnesium sulfate mineral with formula MgSO4·7H2O. Epsomite crystallizes in the orthorhombic system as rarely found acicular or fibrous crystals, the normal form is as massi ...
group which also includes epsomite () and morenosite (). Goslarite is an unstable mineral at the surface and will dehydrate to other minerals like bianchite (), boyleite () and
gunningite Gunningite is one of the minerals in the Kieserite group, with the chemical formula . Its name honours Henry Cecil Gunning (1901–1991) of the Geological Survey of Canada and a professor at the University of British Columbia. Occurrence Gunning ...
().


Physical properties

The composition of goslarite was determined by the US National Bureau of Standards (now the
National Institute of Standards and Technology The National Institute of Standards and Technology (NIST) is an agency of the United States Department of Commerce whose mission is to promote American innovation and industrial competitiveness. NIST's activities are organized into physical sci ...
) in 1959 as follows: SO3 27.84 wt%, ZnO 28.30 wt% and 43.86 wt%. Goslarite's cleavage is perfect in , as for epsomite and morenosite. The color of goslarite ranges from brownish to pinkish, blue, brown, colorless, green and green blue. The luster ranges from vitreous to nacreous and silky (if fibrous). Goslarite is soluble in water, has an astringent taste, and is strongly
diamagnetic Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracted ...
.


Geologic occurrence

Goslarite is formed from the
oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
of
sphalerite Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimen ...
((Zn, Fe)S). It was first found in Rammelsberg mine, Goslar, Harz, Germany. It often occurs as an
efflorescence In chemistry, efflorescence (which means "to flower out" in French) is the migration of a salt to the surface of a porous material, where it forms a coating. The essential process involves the dissolving of an internally held salt in water, or ...
on timbers and walls of mine passages. Goslarite is widespread as a post mining efflorescence in mines that contain sphalerite or any zinc minerals.


Economical uses

In the pharmaceutical industry it is used as a direct
emetic Vomiting (also known as emesis and throwing up) is the involuntary, forceful expulsion of the contents of one's stomach through the mouth and sometimes the nose. Vomiting can be the result of ailments like food poisoning, gastroenteri ...
,
antiseptic An antiseptic (from Greek ἀντί ''anti'', "against" and σηπτικός ''sēptikos'', "putrefactive") is an antimicrobial substance or compound that is applied to living tissue/skin to reduce the possibility of infection, sepsis, or putre ...
and disinfectant.


References

{{Reflist, 35em


External links


Mineral Picture
Zinc minerals Sulfate minerals Orthorhombic minerals Minerals in space group 19 Minerals described in 1847