Gold chalcogenides are compounds formed between
gold and one of the
chalcogens, elements from
group 16 of the
periodic table
The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of ch ...
:
oxygen,
sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
,
selenium, or
tellurium.
*
Gold(III) oxide
Gold(III) oxide (Au2O3) is an inorganic compound of gold and oxygen with the formula Au2O3. It is a red-brown solid that decomposes at 298 °C.
According to X-ray crystallography, AuO features square planar gold centers with both 2- and 3- ...
, Au
2O
3. Decomposes into gold and oxygen above 160 °C, and dissolves in concentrated alkalis to form solutions which probably contain the
4">u(OH)4sup>− ion
*
Gold(I) sulfide, Au
2S. Formed by passing
hydrogen sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The unde ...
through solutions of gold(I) compounds.
*
Gold(III) sulfide, Au
2S
3, unstable in the presence of water.
*Gold tellurides: Au
2Te
3, Au
3Te
5, and AuTe
2 (approximate formulæ) are known as
non-stoichiometric compounds. They show
metallic conductivity. One telluride of gold is a
superconductor at very low temperatures: Au
3Te
5 (1.62 K).
Natural gold tellurides, like
calaverite and
krennerite (AuTe
2),
petzite ( Ag
3AuTe
2), and
sylvanite
Sylvanite or silver gold telluride, chemical formula , is the most common telluride of gold.
Properties
The gold:silver ratio varies from 3:1 to 1:1. It is a metallic mineral with a color that ranges from a steely gray to almost white. It is c ...
(AgAuTe
4), are minor ores of gold (and tellurium). See
telluride minerals for more information on individual naturally occurring tellurides.
References
*
Gold compounds
Non-stoichiometric compounds
Sulfides
Tellurides
{{inorganic-compound-stub
Transition metal oxides