![Getchellite-Orpiment-41642](https://upload.wikimedia.org/wikipedia/commons/3/31/Getchellite-Orpiment-41642.jpg)
Getchellite is a rare
sulfide
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...
of
arsenic
Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but ...
and
antimony
Antimony is a chemical element with the symbol Sb (from la, stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient time ...
, AsSbS
3, that was discovered by B. G. Weissberg of the New Zealand Department of Scientific and Industrial Research in 1963, and approved as a new species by the
International Mineralogical Association
Founded in 1958, the International Mineralogical Association (IMA) is an international group of 40 national societies. The goal is to promote the science of mineralogy and to standardize the nomenclature of the 5000 plus known mineral species. Th ...
in 1965. Many metal sulfides are grey to black, but a few are brightly colored.
Orpiment
Orpiment is a deep-colored, orange-yellow arsenic sulfide mineral with formula . It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and is formed both by sublimation and as a byproduct of the decay of another a ...
is yellow to brownish gold,
cinnabar
Cinnabar (), or cinnabarite (), from the grc, κιννάβαρι (), is the bright scarlet to brick-red form of Mercury sulfide, mercury(II) sulfide (HgS). It is the most common source ore for refining mercury (element), elemental mercury and ...
is deep red and getchellite is a bright orange red.
Thermal properties
Getchellite turns darker red when heated, becoming black by the time it reaches its melting point. Close to this temperature it sublimes (changes directly from a solid to a vapor) and recrystallizes on cooler surfaces as minute acicular black crystals.
Melting point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends ...
: 340 °C to 355 °C.
Boiling point
The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor.
The boiling point of a liquid varies depending upon the surrounding envir ...
: near 470 °C.
[Weissberg, B G, American Mineralogist (1965) Volume 50 pages 1817 to 1826]
Structure
Each of the
semimetal
A semimetal is a material with a very small overlap between the bottom of the conduction band and the top of the valence band.
According to electronic band theory, solids can be classified as insulators, semiconductors, semimetals, or metals. ...
atoms, arsenic and antimony, is bonded to three
sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
atoms to form a trigonal pyramid characteristic of elements in group V of the
periodic table
The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of ch ...
. These pyramids form 8-membered rings which in turn combine to form sheets parallel to (001), with each sulfur atom bonded to two semimetal atoms.
The occupancy of the metal sites is disordered, and within the sheets the 8-membered rings are orientated normal to the plane of the sheet. The sheet structure is responsible for the
cleavage and twin planes of getchellite
Unit cell a = 11.949 Å; b = 9.028 Å; c = 10.130 Å; β= 116.15°; V = 980.9 Å
3; Z = 8.
[ Space group P21/a.
]
Powder diffraction
Discovery
In August 1962 Weissberg visited the Getchell mine at Adam Peak, about 32 km northeast of Golconda
Fort (Telugu: గోల్కొండ, romanized: ''Gōlkōnḍa'') is a historic fortress and ruined city located in Hyderabad, Telangana, India. It was originally called Mankal. The fort was originally built by Kakatiya ruler Pratāparu ...
, in Humboldt County, Nevada
Humboldt County is a county in the U.S. state of Nevada. As of the 2020 Census, the population was 17,285. It is a largely rural county that is sparsely populated with the only major city being Winnemucca which has a population of 8,431. Humbo ...
, US. The purpose of his visit was to collect samples for a study of the relationship between various fairly common sulfides, not to look for new minerals. Getchellite was in some of the samples, but it was not discovered until the rocks were re-examined, a year later. The new mineral was named after the Getchell Mine
The Getchell Mine is an underground gold mine in the Potosi Mining District of Humboldt County, Nevada, on the east flank of the Osgood Mountains, 35 miles northeast of Winnemucca. Prospectors Edward Knight and Emmet Chase discovered gold in 19 ...
, which in turn became the type locality.[ Samples from the mine are preserved as type material (a reference material for the mineral), at the Smithsonian National Museum of Natural History, Washington, D.C., US.]
Environment
At the type locality getchellite is found in an epithermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
(formed at low temperature) arsenical gold deposit in a narrow, steeply dipping fault zone
In geology, a fault is a planar fracture or discontinuity in a volume of rock across which there has been significant displacement as a result of rock-mass movements. Large faults within Earth's crust result from the action of plate tectonic ...
cutting across interbedded shale
Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
s, argillite
:''"Argillite" may also refer to Argillite, Kentucky.''
Argillite () is a fine-grained sedimentary rock composed predominantly of indurated clay particles. Argillaceous rocks are basically lithified muds and oozes. They contain variable amounts ...
s (lithified muds and oozes) and limestones
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms when th ...
, near an intrusion of granodiorite
Granodiorite () is a coarse-grained (phaneritic) intrusive igneous rock similar to granite, but containing more plagioclase feldspar than orthoclase feldspar.
The term banatite is sometimes used informally for various rocks ranging from gra ...
.
Associated minerals are orpiment
Orpiment is a deep-colored, orange-yellow arsenic sulfide mineral with formula . It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and is formed both by sublimation and as a byproduct of the decay of another a ...
, realgar
Realgar ( ), also known as "ruby sulphur" or "ruby of arsenic", is an arsenic sulfide mineral with the chemical formula α-. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in assoc ...
, stibnite
Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2 S3. This soft grey material crystallizes in an orthorhombic space group. It is the most important source for the metalloid antimony. The name is derived from the ...
, cinnabar
Cinnabar (), or cinnabarite (), from the grc, κιννάβαρι (), is the bright scarlet to brick-red form of Mercury sulfide, mercury(II) sulfide (HgS). It is the most common source ore for refining mercury (element), elemental mercury and ...
and quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
,[ as well as ]galkhaite
Galkhaite is a rare and chemically complex sulfosalt mineral from a group of natural thioarsenites. Its formula is , making the mineral the only known natural Cs-Hg and Cs-As phase. It occurs in Carlin-type hydrothermal deposits.
References
, laffittite, chabournéite, christite, lorandite, marcasite
The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...
, barite
Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...
, fluorite
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.
The Mohs sca ...
and calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
.[
]
Distribution
Getchellite is found at the type locality in Nevada
Nevada ( ; ) is a U.S. state, state in the Western United States, Western region of the United States. It is bordered by Oregon to the northwest, Idaho to the northeast, California to the west, Arizona to the southeast, and Utah to the east. N ...
, United States
The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...
, and also in Azerbaijan
Azerbaijan (, ; az, Azərbaycan ), officially the Republic of Azerbaijan, , also sometimes officially called the Azerbaijan Republic is a transcontinental country located at the boundary of Eastern Europe and Western Asia. It is a part of th ...
, China
China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's most populous country, with a population exceeding 1.4 billion, slightly ahead of India. China spans the equivalent of five time zones and ...
, Iran
Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkmeni ...
, Japan
Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north ...
, Kyrgyzstan
Kyrgyzstan,, pronounced or the Kyrgyz Republic, is a landlocked country in Central Asia. Kyrgyzstan is bordered by Kazakhstan to the north, Uzbekistan to the west, Tajikistan to the south, and the People's Republic of China to the east. ...
and Russia
Russia (, , ), or the Russian Federation, is a List of transcontinental countries, transcontinental country spanning Eastern Europe and North Asia, Northern Asia. It is the List of countries and dependencies by area, largest country in the ...
.[
]
Synthesis
Getchellite has been synthesized from As3SbS6 glass in sodium sulfide solutions at 2600 C. and 1,000 bars pressure.[
]
References
{{commons
Sulfide minerals
Monoclinic minerals
Minerals in space group 14