Geoffrey Wilkinson (actor)
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Sir Geoffrey Wilkinson FRS (14 July 1921 – 26 September 1996) was a
Nobel laureate The Nobel Prizes ( sv, Nobelpriset, no, Nobelprisen) are awarded annually by the Royal Swedish Academy of Sciences, the Swedish Academy, the Karolinska Institutet, and the Norwegian Nobel Committee to individuals and organizations who make out ...
English chemist who pioneered
inorganic chemistry Inorganic chemistry deals with synthesis and behavior of inorganic and organometallic compounds. This field covers chemical compounds that are not carbon-based, which are the subjects of organic chemistry. The distinction between the two disci ...
and homogeneous transition metal catalysis.


Education and early life

Wilkinson was born at Springside, Todmorden, in the West Riding of Yorkshire. His father, Henry Wilkinson, was a master house painter and decorator; his mother, Ruth, worked in a local cotton mill. One of his uncles, an organist and
choirmaster A choir ( ; also known as a chorale or chorus) is a musical ensemble of singers. Choral music, in turn, is the music written specifically for such an ensemble to perform. Choirs may perform music from the classical music repertoire, which sp ...
, had married into a family that owned a small chemical company making Epsom and
Glauber Glauber is a scientific discovery method written in the context of computational philosophy of science. It is related to machine learning in artificial intelligence. Glauber was written, among other programs, by Pat Langley, Herbert A. Simon ...
's salts for the pharmaceutical industry; this is where he first developed an interest in chemistry. He was educated at the local council primary school and, after winning a County Scholarship in 1932, went to Todmorden Grammar School. His physics teacher there, Luke Sutcliffe, had also taught Sir John Cockcroft, who received a Nobel Prize for "splitting the atom". In 1939 he obtained a Royal Scholarship for study at Imperial College London, from where he graduated in 1941, with his PhD awarded in 1946 entitled "Some physico-chemical observations of hydrolysis in the homogeneous vapour phase".


Career and research

In 1942 Professor
Friedrich Paneth Friedrich Adolf Paneth (31 August 1887 – 17 September 1958) was an Austrian-born British chemist. Fleeing the Nazis, he escaped to Britain. He became a naturalized British citizen in 1939. After the war, Paneth returned to Germany to bec ...
was recruiting young chemists for the
nuclear energy Nuclear energy may refer to: *Nuclear power, the use of sustained nuclear fission or nuclear fusion to generate heat and electricity * Nuclear binding energy, the energy needed to fuse or split a nucleus of an atom *Nuclear potential energy ...
project. Wilkinson joined and was sent out to Canada, where he stayed in Montreal and later Chalk River Laboratories until he could leave in 1946. For the next four years he worked with Professor
Glenn T. Seaborg Glenn Theodore Seaborg (; April 19, 1912February 25, 1999) was an American chemist whose involvement in the synthesis, discovery and investigation of ten transuranium elements earned him a share of the 1951 Nobel Prize in Chemistry. His work in ...
at University of California, Berkeley, mostly on nuclear taxonomy. He then became a research associate at the Massachusetts Institute of Technology and began to return to his first interest as a student – transition metal complexes of ligands such as carbon monoxide and
olefin In organic chemistry, an alkene is a hydrocarbon containing a carbon–carbon double bond. Alkene is often used as synonym of olefin, that is, any hydrocarbon containing one or more double bonds.H. Stephen Stoker (2015): General, Organic, an ...
s. He was at Harvard University from September 1951 until he returned to England in December 1955, with a sabbatical break of nine months in Copenhagen. At Harvard, he still did some nuclear work on excitation functions for
proton A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
s in cobalt, but had already begun to work on olefin complexes. In June 1955 he was appointed to the chair of Inorganic Chemistry at Imperial College London, and from then on worked almost entirely on the complexes of transition metals. Wilkinson is well known for his popularisation of the use of Wilkinson's catalyst RhCl(PPh3)3 in catalytic hydrogenation, and for the discovery of the structure of
ferrocene Ferrocene is an organometallic compound with the formula . The molecule is a complex consisting of two cyclopentadienyl rings bound to a central iron atom. It is an orange solid with a camphor-like odor, that sublimes above room temperature, a ...
. Wilkinson's catalyst is used industrially in the hydrogenation of alkenes to alkanes. He supervised PhD students and postdoctoral researchers including
John A. Osborn John A. Osborn (1939–2000) was an inorganic chemist who made many contributions to organometallic chemistry. Obsorn received his PhD under the mentorship of Geoffrey Wilkinson. During that degree Osborn contributed to the development of Wilk ...
,
Alan Davison Alan Davison FRS (24 March 1936 — 14 November 2015) was a British inorganic chemist known for his work on transition metals, and a professor at Massachusetts Institute of Technology. Education He earned a B.Sc. from Swansea University in 195 ...
and Malcolm Green.


Awards and honours

Wilkinson received many awards, including the Nobel Prize for Chemistry in 1973 for his work on " organometallic compounds" (with Ernst Otto Fischer). He is also well known for writing, with his former doctoral student F. Albert Cotton, "Advanced Inorganic Chemistry", often referred to simply as "Cotton and Wilkinson", one of the standard inorganic chemistry textbooks. He was elected a Fellow of the Royal Society (FRS) in 1965. In 1980 he was awarded an honorary doctorate of science from the University of Bath. Imperial College London named a new hall of residence after him, which opened in October 2009. Wilkinson Hall is named in his honour.Wilkinson Hall at Imperial College London
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Personal life

Wilkinson was married to Lise Schou, a Danish plant physiologist whom he had met at Berkeley. They had two daughters, Anne and Pernille.


References


External links

* {{DEFAULTSORT:Wilkinson, Geoffrey 1921 births 1996 deaths Alumni of Imperial College London Academics of Imperial College London English chemists British Nobel laureates Inorganic chemists Knights Bachelor Nobel laureates in Chemistry People from Todmorden Royal Medal winners Fellows of the Royal Society Foreign associates of the National Academy of Sciences English Nobel laureates