Faraday efficiency (also called ''faradaic efficiency'', ''faradaic yield'', ''coulombic efficiency'' or ''current efficiency'') describes the efficiency with which

charge Charge or charged may refer to: Arts, entertainment, and media Films * '' Charge, Zero Emissions/Maximum Speed'', a 2011 documentary Music * ''Charge'' (David Ford album) * ''Charge'' (Machel Montano album) * ''Charge!!'', an album by The Aqu ...

(

electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have n ...

s) is transferred in a system facilitating an

electrochemical reaction Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outco ...

. The word "Faraday" in this term has two interrelated aspects. First, the historic unit for

is the

faraday Michael Faraday (; 22 September 1791 – 25 August 1867) was an English scientist who contributed to the study of electromagnetism and electrochemistry. His main discoveries include the principles underlying electromagnetic induction, ...

, but has since been replaced by the

coulomb The coulomb (symbol: C) is the unit of electric charge in the International System of Units (SI). In the present version of the SI it is equal to the electric charge delivered by a 1 ampere constant current in 1 second and to elementary char ...

. Secondly, the related

Faraday's constant In physical chemistry, the Faraday constant, denoted by the symbol and sometimes stylized as ℱ, is the electric charge per mole of elementary charges. It is named after the English scientist Michael Faraday. Since the 2019 redefinition of ...

correlates charge with moles of matter and electrons (

amount of substance In chemistry, the amount of substance ''n'' in a given sample of matter is defined as the quantity or number of discrete atomic-scale particles in it divided by the Avogadro constant ''N''A. The particles or entities may be molecules, atoms, io ...

). This phenomenon was originally understood through

Michael Faraday Michael Faraday (; 22 September 1791 – 25 August 1867) was an English scientist who contributed to the study of electromagnetism and electrochemistry. His main discoveries include the principles underlying electromagnetic inducti ...

's work and expressed in his

laws of electrolysis Faraday's laws of electrolysis are quantitative relationships based on the electrochemical research published by Michael Faraday in 1833. First law Michael Faraday reported that the mass (m) of elements deposited at an electrode is directly prop ...

Sources of faradaic loss

Faradaic losses are experienced by both electrolytic and galvanic cells when electrons or ions participate in unwanted side reactions. These losses appear as heat and/or chemical byproducts. An example can be found in the oxidation of water to

oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...

at the positive electrode in electrolysis. Some electrons are diverted to the production of

hydrogen peroxide Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3 ...

. The fraction of electrons so diverted represent a faradaic loss and vary in different apparatuses. Even when the proper electrolysis products are produced, losses can still occur if the products are permitted to recombine. During

water electrolysis Electrolysis of water, also known as electrochemical water splitting, is the process of using electricity to decompose water into oxygen and hydrogen gas by electrolysis. Hydrogen gas released in this way can be used as hydrogen fuel, or remi ...

, the desired products ( H₂ and O₂), could recombine to form

water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...

. This could realistically happen in the presence of catalytic materials such as

platinum Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Pla ...

palladium Palladium is a chemical element with the symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1803 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas, which was itself ...

commonly used as electrodes. Failure to account for this

Faraday-efficiency effect The Faraday-efficiency effect refers to the potential for misinterpretation of data from experiments in electrochemistry through failure to take into account a Faraday efficiency of less than 100 percent. Assumption about efficiency Until recent d ...

has been identified as the cause of the misidentification of positive results in

cold fusion Cold fusion is a hypothesized type of nuclear reaction that would occur at, or near, room temperature. It would contrast starkly with the "hot" fusion that is known to take place naturally within stars and artificially in hydrogen bombs and p ...

experiments.

Proton exchange membrane fuel cell A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...

s provide another example of faradaic losses when some of the electrons separated from hydrogen at the

anode An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic is ...

leak through the membrane and reach the

cathode A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. A conventional current describes the direction in whi ...

directly instead of passing through the load and performing useful

work Work may refer to: * Work (human activity), intentional activity people perform to support themselves, others, or the community ** Manual labour, physical work done by humans ** House work, housework, or homemaking ** Working animal, an animal t ...

. Ideally the electrolyte membrane would be a perfect insulator and prevent this from happening. An especially familiar example of faradaic loss is the

self-discharge Self-discharge is a phenomenon in batteries Battery most often refers to: * Electric battery, a device that provides electrical power * Battery (crime), a crime involving unlawful physical contact Battery may also refer to: Energy source *Au ...

that limits battery shelf-life.

Methods of measuring faradaic loss

Faradaic efficiency of a cell design is usually measured through bulk electrolysis where a known quantity of reagent is

stoichiometric Stoichiometry refers to the relationship between the quantities of reactants and products before, during, and following chemical reactions. Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equ ...

ally converted to product, as measured by the current passed. This result is then compared to the observed quantity of product measured through another analytical method.

Faradaic loss vs. voltage and energy efficiency

Faradaic loss is only one form of energy loss in an electrochemical system. Another is

overpotential In electrochemistry, overpotential is the potential difference (voltage) between a half-reaction's thermodynamically determined reduction potential and the potential at which the redox event is experimentally observed. The term is directly rela ...

, the difference between the theoretical and actual electrode voltages needed to drive the reaction at the desired rate. Even a rechargeable battery with 100% faradaic efficiency requires charging at a higher voltage than it produces during discharge, so its overall energy efficiency is the product of voltage efficiency and faradaic efficiency. Voltage efficiencies below 100% reflect the thermodynamic irreversibility of every real-world chemical reaction.

References

{{DEFAULTSORT:Faraday Efficiency Electrochemistry ru:Выход по току