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mathematics Mathematics is a field of study that discovers and organizes methods, Mathematical theory, theories and theorems that are developed and Mathematical proof, proved for the needs of empirical sciences and mathematics itself. There are many ar ...
, Frobenius' theorem gives
necessary and sufficient condition In logic and mathematics, necessity and sufficiency are terms used to describe a conditional or implicational relationship between two statements. For example, in the conditional statement: "If then ", is necessary for , because the truth of ...
s for finding a maximal set of independent solutions of an overdetermined system of first-order homogeneous linear
partial differential equation In mathematics, a partial differential equation (PDE) is an equation which involves a multivariable function and one or more of its partial derivatives. The function is often thought of as an "unknown" that solves the equation, similar to ho ...
s. In modern
geometric Geometry (; ) is a branch of mathematics concerned with properties of space such as the distance, shape, size, and relative position of figures. Geometry is, along with arithmetic, one of the oldest branches of mathematics. A mathematician w ...
terms, given a family of
vector field In vector calculus and physics, a vector field is an assignment of a vector to each point in a space, most commonly Euclidean space \mathbb^n. A vector field on a plane can be visualized as a collection of arrows with given magnitudes and dire ...
s, the theorem gives necessary and sufficient
integrability condition In mathematics, certain systems of partial differential equations are usefully formulated, from the point of view of their underlying geometric and algebraic structure, in terms of a system of differential forms. The idea is to take advantage of th ...
s for the existence of a
foliation In mathematics (differential geometry), a foliation is an equivalence relation on an topological manifold, ''n''-manifold, the equivalence classes being connected, injective function, injectively immersed submanifolds, all of the same dimension ...
by maximal integral manifolds whose tangent bundles are spanned by the given vector fields. The theorem generalizes the
existence theorem In mathematics, an existence theorem is a theorem which asserts the existence of a certain object. It might be a statement which begins with the phrase " there exist(s)", or it might be a universal statement whose last quantifier is existential ...
for ordinary differential equations, which guarantees that a single vector field always gives rise to
integral curve In mathematics, an integral curve is a parametric curve that represents a specific solution to an ordinary differential equation or system of equations. Name Integral curves are known by various other names, depending on the nature and interpre ...
s; Frobenius gives compatibility conditions under which the integral curves of ''r'' vector fields mesh into coordinate grids on ''r''-dimensional integral manifolds. The theorem is foundational in
differential topology In mathematics, differential topology is the field dealing with the topological properties and smooth properties of smooth manifolds. In this sense differential topology is distinct from the closely related field of differential geometry, which ...
and calculus on manifolds.
Contact geometry In mathematics, contact geometry is the study of a geometric structure on smooth manifolds given by a hyperplane distribution in the tangent bundle satisfying a condition called 'complete non-integrability'. Equivalently, such a distribution ...
studies 1-forms that maximally violates the assumptions of Frobenius' theorem. An example is shown on the right.


Introduction


One-form version

Suppose we are to find the trajectory of a particle in a subset of 3D space, but we do not know its trajectory formula. Instead, we know only that its trajectory satisfies adx + bdy + cdz = 0, where a, b, c are smooth functions of (x,y,z). Thus, our only certainty is that if at some moment in time the particle is at location (x_0, y_0, z_0), then its velocity at that moment is restricted within the plane with equation a(x_0, y_0, z_0) -x_0+ b(x_0, y_0, z_0) -y_0+ c(x_0, y_0, z_0) -z_0= 0 In other words, we can draw a "local plane" at each point in 3D space, and we know that the particle's trajectory must be tangent to the local plane at all times. If we have two equations\begin adx + bdy + cdz = 0 \\ a'dx + b'dy + c'dz = 0 \endthen we can draw two local planes at each point, and their intersection is generically a line, allowing us to uniquely solve for the curve starting at any point. In other words, with two 1-forms, we can foliate the domain into curves. If we have only one equation adx + bdy + cdz = 0, then we might be able to foliate \R^3 into surfaces, in which case, we can be sure that a curve starting at a certain surface must be restricted to wander within that surface. If not, then a curve starting at any point might end up at any other point in \R^3. One can imagine starting with a cloud of little planes, and
quilting Quilting is the process of joining a minimum of three layers of textile, fabric together either through stitching manually using a Sewing needle, needle and yarn, thread, or mechanically with a sewing machine or specialised longarm quilting ...
them together to form a full surface. The main danger is that, if we quilt the little planes two at a time, we might go on a cycle and return to where we began, but shifted by a small amount. If this happens, then we would not get a 2-dimensional surface, but a 3-dimensional blob. An example is shown in the diagram on the right. If the one-form is integrable, then loops exactly close upon themselves, and each surface would be 2-dimensional. Frobenius' theorem states that this happens precisely when \omega \wedge d\omega = 0 over all of the domain, where \omega := adx + bdy + cdz. The notation is defined in the article on one-forms. During his development of axiomatic thermodynamics, Carathéodory proved that if \omega is an integrable one-form on an open subset of \R^n, then \omega = f dg for some scalar functions f, g on the subset. This is usually called Carathéodory's theorem in axiomatic thermodynamics. One can prove this intuitively by first constructing the little planes according to \omega, quilting them together into a foliation, then assigning each surface in the foliation with a scalar label. Now for each point p, define g(p) to be the scalar label of the surface containing point p. Now, dg is a one-form that has exactly the same planes as \omega. However, it has "even thickness" everywhere, while \omega might have "uneven thickness". This can be fixed by a scalar scaling by f, giving \omega = f dg. This is illustrated on the right.


Multiple one-forms

In its most elementary form, the theorem addresses the problem of finding a maximal set of independent solutions of a regular system of first-order linear homogeneous
partial differential equation In mathematics, a partial differential equation (PDE) is an equation which involves a multivariable function and one or more of its partial derivatives. The function is often thought of as an "unknown" that solves the equation, similar to ho ...
s. Let : \left \ be a collection of functions, with , and such that the matrix has
rank A rank is a position in a hierarchy. It can be formally recognized—for example, cardinal, chief executive officer, general, professor—or unofficial. People Formal ranks * Academic rank * Corporate title * Diplomatic rank * Hierarchy ...
''r'' when evaluated at any point of . Consider the following system of partial differential equations for a function : :(1) \quad \begin L_1u\ \stackrel\ \sum_i f_1^i(x)\frac = \vec f_1 \cdot \nabla u = 0\\ L_2u\ \stackrel\ \sum_i f_2^i(x)\frac = \vec f_2 \cdot \nabla u = 0\\ \qquad \cdots \\ L_ru\ \stackrel\ \sum_i f_r^i(x)\frac = \vec f_r \cdot \nabla u = 0 \end One seeks conditions on the existence of a collection of solutions such that the gradients are
linearly independent In the theory of vector spaces, a set of vectors is said to be if there exists no nontrivial linear combination of the vectors that equals the zero vector. If such a linear combination exists, then the vectors are said to be . These concep ...
. The Frobenius theorem asserts that this problem admits a solution locally if, and only if, the operators satisfy a certain
integrability condition In mathematics, certain systems of partial differential equations are usefully formulated, from the point of view of their underlying geometric and algebraic structure, in terms of a system of differential forms. The idea is to take advantage of th ...
known as ''involutivity''. Specifically, they must satisfy relations of the form :L_iL_ju(x)-L_jL_iu(x)=\sum_k c_^k(x)L_ku(x) for , and all functions ''u'', and for some coefficients ''c''''k''''ij''(''x'') that are allowed to depend on ''x''. In other words, the
commutator In mathematics, the commutator gives an indication of the extent to which a certain binary operation fails to be commutative. There are different definitions used in group theory and ring theory. Group theory The commutator of two elements, ...
s must lie in the
linear span In mathematics, the linear span (also called the linear hull or just span) of a set S of elements of a vector space V is the smallest linear subspace of V that contains S. It is the set of all finite linear combinations of the elements of , and ...
of the at every point. The involutivity condition is a generalization of the commutativity of partial derivatives. In fact, the strategy of proof of the Frobenius theorem is to form linear combinations among the operators so that the resulting operators do commute, and then to show that there is a
coordinate system In geometry, a coordinate system is a system that uses one or more numbers, or coordinates, to uniquely determine and standardize the position of the points or other geometric elements on a manifold such as Euclidean space. The coordinates are ...
for which these are precisely the partial derivatives with respect to .


From analysis to geometry

Even though the system is overdetermined there are typically infinitely many solutions. For example, the system of differential equations :\begin \frac + \frac =0\\ \frac+ \frac=0 \end clearly permits multiple solutions. Nevertheless, these solutions still have enough structure that they may be completely described. The first observation is that, even if ''f''1 and ''f''2 are two different solutions, the
level surface In mathematics, a level set of a real-valued function of real variables is a set where the function takes on a given constant value , that is: : L_c(f) = \left\~. When the number of independent variables is two, a level set is call ...
s of ''f''1 and ''f''2 must overlap. In fact, the level surfaces for this system are all planes in of the form , for a constant. The second observation is that, once the level surfaces are known, all solutions can then be given in terms of an arbitrary function. Since the value of a solution ''f'' on a level surface is constant by definition, define a function ''C''(''t'') by: :f(x,y,z)=C(t) \text x - y + z = t. Conversely, if a function is given, then each function ''f'' given by this expression is a solution of the original equation. Thus, because of the existence of a family of level surfaces, solutions of the original equation are in a one-to-one correspondence with arbitrary functions of one variable. Frobenius' theorem allows one to establish a similar such correspondence for the more general case of solutions of (1). Suppose that are solutions of the problem (1) satisfying the independence condition on the gradients. Consider the
level set In mathematics, a level set of a real-valued function of real variables is a set where the function takes on a given constant value , that is: : L_c(f) = \left\~. When the number of independent variables is two, a level set is call ...
s of as functions with values in . If is another such collection of solutions, one can show (using some
linear algebra Linear algebra is the branch of mathematics concerning linear equations such as :a_1x_1+\cdots +a_nx_n=b, linear maps such as :(x_1, \ldots, x_n) \mapsto a_1x_1+\cdots +a_nx_n, and their representations in vector spaces and through matrix (mathemat ...
and the
mean value theorem In mathematics, the mean value theorem (or Lagrange's mean value theorem) states, roughly, that for a given planar arc (geometry), arc between two endpoints, there is at least one point at which the tangent to the arc is parallel to the secant lin ...
) that this has the same family of level sets but with a possibly different choice of constants for each set. Thus, even though the independent solutions of (1) are not unique, the equation (1) nonetheless determines a unique family of level sets. Just as in the case of the example, general solutions ''u'' of (1) are in a one-to-one correspondence with (continuously differentiable) functions on the family of level sets. The level sets corresponding to the maximal independent solution sets of (1) are called the ''integral manifolds'' because functions on the collection of all integral manifolds correspond in some sense to
constants of integration In calculus, the constant of integration, often denoted by C (or c), is a constant term added to an antiderivative of a function f(x) to indicate that the indefinite integral of f(x) (i.e., the Set (mathematics), set of all antiderivatives of f(x) ...
. Once one of these constants of integration is known, then the corresponding solution is also known.


Frobenius' theorem in modern language

The Frobenius theorem can be restated more economically in modern language. Frobenius' original version of the theorem was stated in terms of Pfaffian systems, which today can be translated into the language of
differential form In mathematics, differential forms provide a unified approach to define integrands over curves, surfaces, solids, and higher-dimensional manifolds. The modern notion of differential forms was pioneered by Élie Cartan. It has many applications ...
s. An alternative formulation, which is somewhat more intuitive, uses
vector field In vector calculus and physics, a vector field is an assignment of a vector to each point in a space, most commonly Euclidean space \mathbb^n. A vector field on a plane can be visualized as a collection of arrows with given magnitudes and dire ...
s.


Formulation using vector fields

In the vector field formulation, the theorem states that a subbundle of the
tangent bundle A tangent bundle is the collection of all of the tangent spaces for all points on a manifold, structured in a way that it forms a new manifold itself. Formally, in differential geometry, the tangent bundle of a differentiable manifold M is ...
of a
manifold In mathematics, a manifold is a topological space that locally resembles Euclidean space near each point. More precisely, an n-dimensional manifold, or ''n-manifold'' for short, is a topological space with the property that each point has a N ...
is integrable (or involutive) if and only if it arises from a regular foliation. In this context, the Frobenius theorem relates integrability to foliation; to state the theorem, both concepts must be clearly defined. One begins by noting that an arbitrary smooth
vector field In vector calculus and physics, a vector field is an assignment of a vector to each point in a space, most commonly Euclidean space \mathbb^n. A vector field on a plane can be visualized as a collection of arrows with given magnitudes and dire ...
X on a manifold M defines a family of
curve In mathematics, a curve (also called a curved line in older texts) is an object similar to a line, but that does not have to be straight. Intuitively, a curve may be thought of as the trace left by a moving point. This is the definition that ...
s, its integral curves u:I\to M (for intervals I). These are the solutions of \dot u(t) = X_, which is a system of first-order
ordinary differential equation In mathematics, an ordinary differential equation (ODE) is a differential equation (DE) dependent on only a single independent variable (mathematics), variable. As with any other DE, its unknown(s) consists of one (or more) Function (mathematic ...
s, whose solvability is guaranteed by the
Picard–Lindelöf theorem In mathematics, specifically the study of differential equations, the Picard–Lindelöf theorem gives a set of conditions under which an initial value problem has a unique solution. It is also known as Picard's existence theorem, the Cauchy– ...
. If the vector field X is nowhere zero then it defines a one-dimensional subbundle of the tangent bundle of M, and the integral curves form a regular foliation of M. Thus, one-dimensional subbundles are always integrable. If the subbundle has dimension greater than one, a condition needs to be imposed. One says that a subbundle E\subset TM of the
tangent bundle A tangent bundle is the collection of all of the tangent spaces for all points on a manifold, structured in a way that it forms a new manifold itself. Formally, in differential geometry, the tangent bundle of a differentiable manifold M is ...
TM is integrable (or involutive), if, for any two vector fields X and Y taking values in E, the
Lie bracket In mathematics, a Lie algebra (pronounced ) is a vector space \mathfrak g together with an operation called the Lie bracket, an alternating bilinear map \mathfrak g \times \mathfrak g \rightarrow \mathfrak g, that satisfies the Jacobi identit ...
,Y/math> takes values in E as well. This notion of integrability need only be defined locally; that is, the existence of the vector fields X and Y and their integrability need only be defined on subsets of M. Several definitions of
foliation In mathematics (differential geometry), a foliation is an equivalence relation on an topological manifold, ''n''-manifold, the equivalence classes being connected, injective function, injectively immersed submanifolds, all of the same dimension ...
exist. Here we use the following: Definition. A ''p''-dimensional, class ''Cr'' foliation of an ''n''-dimensional manifold ''M'' is a decomposition of ''M'' into a union of disjoint connected submanifolds α∈''A'', called the ''leaves'' of the foliation, with the following property: Every point in ''M'' has a neighborhood ''U'' and a system of local, class ''Cr'' coordinates ''x''=(''x''1, ⋅⋅⋅, ''xn'') : ''U''→R''n'' such that for each leaf ''L''α, the components of ''U'' ∩ ''L''α are described by the equations ''x''''p''+1=constant, ⋅⋅⋅, ''xn''=constant. A foliation is denoted by \mathcal=α∈''A''. Trivially, any
foliation In mathematics (differential geometry), a foliation is an equivalence relation on an topological manifold, ''n''-manifold, the equivalence classes being connected, injective function, injectively immersed submanifolds, all of the same dimension ...
of M defines an integrable subbundle, since if p\in M and N\subset M is the leaf of the foliation passing through p then E_p = T_pN is integrable. Frobenius' theorem states that the converse is also true: Given the above definitions, Frobenius' theorem states that a subbundle E is integrable if and only if the subbundle E arises from a regular foliation of M.


Differential forms formulation

Let ''U'' be an open set in a manifold , be the space of smooth, differentiable
1-form In differential geometry, a one-form (or covector field) on a differentiable manifold is a differential form of degree one, that is, a smooth section of the cotangent bundle. Equivalently, a one-form on a manifold M is a smooth mapping of the t ...
s on ''U'', and ''F'' be a
submodule In mathematics, a module is a generalization of the notion of vector space in which the field of scalars is replaced by a (not necessarily commutative) ring. The concept of a ''module'' also generalizes the notion of an abelian group, since t ...
of of
rank A rank is a position in a hierarchy. It can be formally recognized—for example, cardinal, chief executive officer, general, professor—or unofficial. People Formal ranks * Academic rank * Corporate title * Diplomatic rank * Hierarchy ...
''r'', the rank being constant in value over ''U''. The Frobenius theorem states that ''F'' is integrable if and only if for every in the stalk ''Fp'' is generated by ''r''
exact differential form In mathematics, especially vector calculus and differential topology, a closed form is a differential form ''α'' whose exterior derivative is zero (); and an exact form is a differential form, ''α'', that is the exterior derivative of another dif ...
s. Geometrically, the theorem states that an integrable module of -forms of rank ''r'' is the same thing as a codimension-r
foliation In mathematics (differential geometry), a foliation is an equivalence relation on an topological manifold, ''n''-manifold, the equivalence classes being connected, injective function, injectively immersed submanifolds, all of the same dimension ...
. The correspondence to the definition in terms of vector fields given in the introduction follows from the close relationship between
differential form In mathematics, differential forms provide a unified approach to define integrands over curves, surfaces, solids, and higher-dimensional manifolds. The modern notion of differential forms was pioneered by Élie Cartan. It has many applications ...
s and
Lie derivative In differential geometry, the Lie derivative ( ), named after Sophus Lie by Władysław Ślebodziński, evaluates the change of a tensor field (including scalar functions, vector fields and one-forms), along the flow defined by another vector fi ...
s. Frobenius' theorem is one of the basic tools for the study of
vector field In vector calculus and physics, a vector field is an assignment of a vector to each point in a space, most commonly Euclidean space \mathbb^n. A vector field on a plane can be visualized as a collection of arrows with given magnitudes and dire ...
s and foliations. There are thus two forms of the theorem: one which operates with
distribution Distribution may refer to: Mathematics *Distribution (mathematics), generalized functions used to formulate solutions of partial differential equations *Probability distribution, the probability of a particular value or value range of a varia ...
s, that is smooth subbundles ''D'' of the tangent bundle ''TM''; and the other which operates with subbundles of the graded ring of all forms on ''M''. These two forms are related by duality. If ''D'' is a smooth tangent distribution on , then the annihilator of ''D'', ''I''(''D'') consists of all forms \alpha\in\Omega^k (M) (for any k\in \) such that :\alpha(v_1,\dots,v_k) = 0 for all v_1,\dots,v_k\in D. The set ''I''(''D'') forms a subring and, in fact, an ideal in . Furthermore, using the definition of the
exterior derivative On a differentiable manifold, the exterior derivative extends the concept of the differential of a function to differential forms of higher degree. The exterior derivative was first described in its current form by Élie Cartan in 1899. The re ...
, it can be shown that ''I''(''D'') is closed under exterior differentiation (it is a differential ideal) if and only if ''D'' is involutive. Consequently, the Frobenius theorem takes on the equivalent form that is closed under exterior differentiation if and only if ''D'' is integrable.


Generalizations

The theorem may be generalized in a variety of ways.


Infinite dimensions

One infinite-dimensional generalization is as follows. Let and be
Banach space In mathematics, more specifically in functional analysis, a Banach space (, ) is a complete normed vector space. Thus, a Banach space is a vector space with a metric that allows the computation of vector length and distance between vectors and ...
s, and a pair of
open set In mathematics, an open set is a generalization of an Interval (mathematics)#Definitions_and_terminology, open interval in the real line. In a metric space (a Set (mathematics), set with a metric (mathematics), distance defined between every two ...
s. Let :F:A\times B \to L(X,Y) be a continuously differentiable function of the
Cartesian product In mathematics, specifically set theory, the Cartesian product of two sets and , denoted , is the set of all ordered pairs where is an element of and is an element of . In terms of set-builder notation, that is A\times B = \. A table c ...
(which inherits a
differentiable structure In mathematics, an ''n''- dimensional differential structure (or differentiable structure) on a set ''M'' makes ''M'' into an ''n''-dimensional differential manifold, which is a topological manifold with some additional structure that allows for d ...
from its inclusion into ''X'' ×''Y'' ) into the space of continuous linear transformations of into ''Y''. A differentiable mapping ''u'' : ''A'' → ''B'' is a solution of the differential equation :(1) \quad y' = F(x,y) if :\forall x \in A: \quad u'(x) = F(x, u(x)). The equation (1) is completely integrable if for each (x_0, y_0)\in A\times B, there is a neighborhood ''U'' of ''x''0 such that (1) has a unique solution defined on ''U'' such that ''u''(''x''0)=''y''0. The conditions of the Frobenius theorem depend on whether the underlying field is or . If it is R, then assume ''F'' is continuously differentiable. If it is , then assume ''F'' is twice continuously differentiable. Then (1) is completely integrable at each point of if and only if :D_1F(x,y)\cdot(s_1,s_2) + D_2F(x,y)\cdot(F(x,y)\cdot s_1,s_2) = D_1F(x,y) \cdot (s_2,s_1) + D_2F(x,y)\cdot(F(x,y)\cdot s_2,s_1) for all . Here (resp. ) denotes the partial derivative with respect to the first (resp. second) variable; the
dot product In mathematics, the dot product or scalar productThe term ''scalar product'' means literally "product with a Scalar (mathematics), scalar as a result". It is also used for other symmetric bilinear forms, for example in a pseudo-Euclidean space. N ...
denotes the action of the linear operator , as well as the actions of the operators and .


Banach manifolds

The infinite-dimensional version of the Frobenius theorem also holds on
Banach manifold In mathematics, a Banach manifold is a manifold modeled on Banach spaces. Thus it is a topological space in which each point has a neighbourhood homeomorphic to an open set in a Banach space (a more involved and formal definition is given below). B ...
s. The statement is essentially the same as the finite-dimensional version. Let be a Banach manifold of class at least ''C''2. Let be a subbundle of the tangent bundle of . The bundle is involutive if, for each point and pair of sections and ''Y'' of defined in a neighborhood of ''p'', the Lie bracket of and ''Y'' evaluated at ''p'', lies in : : ,Yp \in E_p On the other hand, is integrable if, for each , there is an immersed submanifold whose image contains ''p'', such that the differential of is an isomorphism of ''TN'' with . The Frobenius theorem states that a subbundle is integrable if and only if it is involutive.


Holomorphic forms

The statement of the theorem remains true for holomorphic 1-forms on
complex manifold In differential geometry and complex geometry, a complex manifold is a manifold with a ''complex structure'', that is an atlas (topology), atlas of chart (topology), charts to the open unit disc in the complex coordinate space \mathbb^n, such th ...
s — manifolds over with biholomorphic transition functions. Specifically, if \omega^1,\dots,\omega^r are ''r'' linearly independent holomorphic 1-forms on an open set in such that :d\omega^j = \sum_^r \psi_i^j \wedge \omega^i for some system of holomorphic 1-forms , then there exist holomorphic functions ''f''ij and such that, on a possibly smaller domain, :\omega^j = \sum_^r f_i^jdg^i. This result holds locally in the same sense as the other versions of the Frobenius theorem. In particular, the fact that it has been stated for domains in is not restrictive.


Higher degree forms

The statement does not generalize to higher degree forms, although there is a number of partial results such as Darboux's theorem and the Cartan-Kähler theorem.


History

Despite being named for
Ferdinand Georg Frobenius Ferdinand Georg Frobenius (26 October 1849 – 3 August 1917) was a German mathematician, best known for his contributions to the theory of elliptic functions, differential equations, number theory, and to group theory. He is known for the famou ...
, the theorem was first proven by
Alfred Clebsch Rudolf Friedrich Alfred Clebsch (19 January 1833 – 7 November 1872) was a German mathematician who made important contributions to algebraic geometry and invariant theory. He attended the University of Königsberg and was habilitated at Humboldt ...
and Feodor Deahna. Deahna was the first to establish the sufficient conditions for the theorem, and Clebsch developed the necessary conditions. Frobenius is responsible for applying the theorem to Pfaffian systems, thus paving the way for its usage in differential topology.


Applications

* In
classical mechanics Classical mechanics is a Theoretical physics, physical theory describing the motion of objects such as projectiles, parts of Machine (mechanical), machinery, spacecraft, planets, stars, and galaxies. The development of classical mechanics inv ...
, the integrability of a system's constraint equations determines whether the system is holonomic or nonholonomic. * In
microeconomic theory Microeconomics is a branch of economics that studies the behavior of individuals and Theory of the firm, firms in making decisions regarding the allocation of scarcity, scarce resources and the interactions among these individuals and firms. M ...
, Frobenius' theorem can be used to prove the existence of a solution to the problem of integrability of demand functions.


Carathéodory's axiomatic thermodynamics

In
classical thermodynamics Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of th ...
, Frobenius' theorem can be used to construct entropy and temperature in Carathéodory's formalism. Specifically, Carathéodory considered a thermodynamic system (concretely one can imagine a piston of gas) that can interact with the outside world by either heat conduction (such as setting the piston on fire) or mechanical work (pushing on the piston). He then defined "adiabatic process" as any process that the system may undergo without heat conduction, and defined a relation of "
adiabatic accessibility In thermodynamics, adiabatic accessibility determines if one equilibrium state of a system can transition to another solely through an adiabatic process, meaning no heat is exchanged with the environment. The concept was coined by Constantin Carat ...
" thus: if the system can go from state A to state B after an adiabatic process, then B is adiabatically accessible from A. Write it as A \succeq B. Now assume that * For any pair of states A, B, at least one of A \succeq B and B \succeq A holds. * For any state A, and any neighborhood of A, there exists a state B in the neighborhood, such that B is adiabatically inaccessible from A. Then, we can foliate the state space into subsets of states that are mutually adiabatically accessible. With mild assumptions on the smoothness of \succeq, each subset is a manifold of codimension 1. Call these manifolds "adiabatic surfaces". By the
first law of thermodynamics The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes. For a thermodynamic process affecting a thermodynamic system without transfer of matter, the law distinguishes two ...
, there exists a scalar function U ("internal energy") on the state space, such thatdU = \delta W + \delta Q = \sum_i X_i dx_i + \delta Qwhere X_1 dx_1, ..., X_n dx_n are the possible ways to perform mechanical work on the system. For example, if the system is a tank of ideal gas, then \delta W = -p dV. Now, define the one-form on the state space\omega := dU - \sum_i X_i dx_iNow, since the adiabatic surfaces are tangent to \omega at every point in state space, \omega is integrable, so by Carathéodory's theorem, there exists two scalar functions T, S on state space, such that \omega = TdS. These are the temperature and entropy functions, up to a multiplicative constant. By plugging in the ideal gas laws, and noting that
Joule expansion The Joule expansion (a subset of free expansion) is an irreversible process in thermodynamics in which a volume of gas is kept in one side of a thermally isolated container (via a small partition), with the other side of the container being eva ...
is an (irreversible) adiabatic process, we can fix the sign of dS, and find that A \succeq B means S(A) \leq S(B). That is, entropy is preserved in reversible adiabatic processes, and increases during irreversible adiabatic processes.


See also

*
Integrability conditions for differential systems In mathematics, certain systems of partial differential equations are usefully formulated, from the point of view of their underlying geometric and algebraic structure, in terms of a system of differential forms. The idea is to take advantage of th ...
* Domain-straightening theorem * Newlander-Nirenberg Theorem


Notes


References

* * * * * {{refend Theorems in differential geometry Theorems in differential topology Differential systems Foliations