Formation Factor
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In
petrophysics Petrophysics (from the Greek πέτρα, ''petra'', "rock" and φύσις, ''physis'', "nature") is the study of physical and chemical rock properties and their interactions with fluids. A major application of petrophysics is in studying reservo ...
, Archie's law relates the ''in-situ''
electrical conductivity Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allow ...
(C) of a porous rock to its
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
(\phi\,\!) and fluid saturation (S_w) of the pores: :C_t = \frac C_w \phi^m S_w^n Here, \phi\,\! denotes the porosity, C_t the electrical conductivity of the fluid saturated rock, C_w represents the electrical conductivity of the aqueous solution (fluid or liquid phase), S_w is the
water saturation Water content or moisture content is the quantity of water contained in a material, such as soil (called soil moisture), rock, ceramics, crops, or wood. Water content is used in a wide range of scientific and technical areas, and is expressed as ...
, or more generally the fluid saturation, of the pores, m is the cementation exponent of the rock (usually in the range 1.8–2.0 for sandstones), n is the saturation exponent (usually close to 2) and a is the
tortuosity Tortuosity is widely used as a critical parameter to predict transport properties of porous media, such as rocks and soils. But unlike other standard microstructural properties, the concept of tortuosity is vague with multiple definitions and vari ...
factor. Reformulated for the
electrical resistivity Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allows ...
(R), the inverse of the electrical conductivity (R = \frac), the equation reads :R_t = a R_w \phi^ S_w^ with R_t for the total fluid saturated rock resistivity, and R_w for the resistivity of the fluid itself (w meaning water or an aqueous solution containing dissolved salts with ions bearing electricity in solution). The factor :F = \frac = \frac is also called the formation factor, where R_t (index t standing for total) is the resistivity of the rock saturated with the fluid and R_w is the resistivity of the fluid (index w standing for water) inside the porosity of the rock. The porosity being saturated with the fluid (often water, w), S_w^ = 1. In case the fluid filling the porosity is a mixture of water and hydrocarbon (petroleum, oil, gas), a resistivity index (I) can be defined: :I = \frac = S_w^ Where R_o is the resistivity of the rock saturated in water only. It is a purely
empirical law Scientific laws or laws of science are statements, based on reproducibility, repeated experiments or observations, that describe or prediction, predict a range of natural phenomena. The term ''law'' has diverse usage in many cases (approximate, a ...
attempting to describe
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
flow (mostly
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
and
chloride The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts ...
) in clean, consolidated sands, with varying intergranular porosity. Electrical conduction is only performed by
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
s dissolved in
aqueous solution An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be re ...
. So, electrical conduction is considered to be absent in the rock grains of the solid phase or in organic fluids other than water (oil, hydrocarbon, gas). Archie's law is named after Gus Archie (1907–1978) who developed this empirical quantitative relationship between porosity, electrical conductivity, and fluid saturation of rocks. Archie's law laid the foundation for modern
well log Well logging, also known as borehole logging is the practice of making a detailed record (a ''well log'') of the geologic formations penetrated by a borehole. The log may be based either on visual inspection of samples brought to the surface (' ...
interpretation as it relates borehole electrical conductivity measurements to
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...
saturations (which, for fluid saturated rock, equals 1 - S_w).


Parameters


Cementation exponent, ''m''

The cementation exponent models how much the pore network increases the resistivity, as the rock itself is assumed to be non-conductive. If the pore network were to be modelled as a set of parallel capillary tubes, a cross-section area average of the rock's resistivity would yield porosity dependence equivalent to a cementation exponent of 1. However, the
tortuosity Tortuosity is widely used as a critical parameter to predict transport properties of porous media, such as rocks and soils. But unlike other standard microstructural properties, the concept of tortuosity is vague with multiple definitions and vari ...
of the rock increases this to a higher number than 1. This relates the cementation exponent to the permeability of the rock, increasing permeability decreases the cementation exponent. The exponent m has been observed near 1.3 for unconsolidated sands, and is believed to increase with cementation. Common values for this cementation exponent for consolidated sandstones are 1.8 < m < 2.0. In carbonate rocks, the cementation exponent shows higher variance due to strong diagenetic affinity and complex pore structures. Values between 1.7 and 4.1 have been observed. The cementation exponent is usually assumed not to be dependent on
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...
.


Saturation exponent, ''n''

The saturation exponent n usually is fixed to values close to 2. The
saturation Saturation, saturated, unsaturation or unsaturated may refer to: Chemistry * Saturation, a property of organic compounds referring to carbon-carbon bonds **Saturated and unsaturated compounds ** Degree of unsaturation **Saturated fat or fatty aci ...
exponent models the dependency on the presence of non-conductive fluid (hydrocarbons) in the pore-space, and is related to the
wettability Wetting is the ability of a liquid to maintain contact with a solid surface, resulting from intermolecular interactions when the two are brought together. This happens in presence of a gaseous phase or another liquid phase not miscible with ...
of the rock. Water-wet rocks will, for low water saturation values, maintain a continuous film along the pore walls making the rock conductive. Oil-wet rocks will have discontinuous droplets of water within the pore space, making the rock less conductive.


Tortuosity factor, ''a''

The constant a, called the ''tortuosity factor'', ''cementation intercept'', ''lithology factor'' or, ''
lithology The lithology of a rock unit is a description of its physical characteristics visible at outcrop, in hand or core samples, or with low magnification microscopy. Physical characteristics include colour, texture, grain size, and composition. Lit ...
coefficient'' is sometimes used. It is meant to correct for variation in compaction, pore structure and grain size. The parameter a is called the tortuosity factor and is related to the path length of the current flow. The value lies in the range 0.5 to 1.5, and it may be different in different reservoirs. However a typical value to start with for a sandstone reservoir might be 0.6, which then can be tuned during log data matching process with other sources of data such as core.


Measuring the exponents

In petrophysics, the only reliable source for the numerical value of both exponents is experiments on sand plugs from cored wells. The fluid electrical conductivity can be measured directly on produced fluid (groundwater) samples. Alternatively, the fluid electrical conductivity and the cementation exponent can also be inferred from downhole electrical conductivity measurements across fluid-saturated intervals. For fluid-saturated intervals (S_w=1) Archie's law can be written :\log = \log + m \log\,\! Hence, plotting the logarithm of the measured in-situ electrical conductivity against the logarithm of the measured in-situ porosity (Pickett plot), according to Archie's law a straight-line relationship is expected with slope equal to the cementation exponent m and intercept equal to the logarithm of the in-situ fluid electrical conductivity.


Sands with clay/shaly sands

Archie's law postulates that the rock
matrix Matrix most commonly refers to: * ''The Matrix'' (franchise), an American media franchise ** ''The Matrix'', a 1999 science-fiction action film ** "The Matrix", a fictional setting, a virtual reality environment, within ''The Matrix'' (franchis ...
is non-conductive. For sandstone with
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
, this assumption is no longer true in general, due to the clay's structure and
cation exchange capacity Cation-exchange capacity (CEC) is a measure of how many cations can be retained on soil particle surfaces. Negative charges on the surfaces of soil particles bind positively-charged atoms or molecules (cations), but allow these to exchange with ot ...
. The Waxman–Smits equation is one model that tries to correct for this.


See also

*
Birch's law Birch's law, discovered by the geophysicist Francis Birch, establishes a linear relation between compressional wave velocity and density of rocks and minerals: : v_\mathrm = a( \bar M ) + b \rho where \, \bar M \, is the mean atomic mass in fo ...
*
Byerlee's law In rheology, Byerlee's law, also known as Byerlee's friction law concerns the shear stress (τ) required to slide one rock over another. The rocks have macroscopically flat surfaces, but the surfaces have small asperities that make them "rough." F ...


References

* * * * * * * {{DEFAULTSORT:Archie's Law Geophysics Equations Well logging