Foam Glass
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Foam glass is a
porous Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
glass Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenching) of ...
foam Foams are materials formed by trapping pockets of gas in a liquid or solid. A bath sponge and the head on a glass of beer are examples of foams. In most foams, the volume of gas is large, with thin films of liquid or solid separating the reg ...
material Material is a substance or mixture of substances that constitutes an object. Materials can be pure or impure, living or non-living matter. Materials can be classified on the basis of their physical and chemical properties, or on their geologi ...
. Its advantages as a
building material Building material is material used for construction. Many naturally occurring substances, such as clay, rock (geology), rocks, sand, wood, and even twigs and leaves, have been used to construct buildings. Apart from naturally occurring materia ...
include its light weight, high strength, and thermal and acoustic insulating properties. It is made by heating a mixture of crushed or granulated glass and a
blowing agent A blowing agent is a substance which is capable of producing a cellular structure via a foaming process in a variety of materials that undergo hardening or phase transition, such as polymers, plastics, and metals. They are typically applied when ...
(chemical
foaming agent A foaming agent is a material such as a surfactant or a blowing agent that facilitates the formation of foam. A surfactant, when present in small amounts, reduces surface tension of a liquid (reduces the work needed to create the foam) or increase ...
) such as carbon or
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
. Near the melting point of the glass, the blowing agent releases a gas, producing a foaming effect in the glass. After cooling the mixture hardens into a rigid material with gas-filled closed-cell pores comprising a large portion of its volume. As to chemical foaming agents, there are several additives that facilitate the release of the gaseous phase upon heat treatment. In general, these additives are categorized into two categories: a) redox and neutralization agents, and b) decomposing agents. Redox and neutralization agents include nonoxide materials, e.g. carbides or nitrides. Decomposing agents include sulfates, e.g. CaSO4•nH2O, organic compounds, and carbonates, e.g. CaCO3. These materials release gas following decomposition and/or burning.


History

In the 1930s,
Saint-Gobain Compagnie de Saint-Gobain S.A. () is a French multinational corporation, founded in 1665 in Paris and headquartered on the outskirts of Paris, at La Défense and in Courbevoie. Originally a mirror manufacturer, it now also produces a variety of ...
of France first developed foam glass with calcium carbonate as a foaming agent. In 1935, it applied for a patent. An early report of foam glass as a construction material was made by the Soviet scientist, Professor I.I.Kitaygorodskiy at the All-Union Conference on Standardization and Manufacture of New Construction Materials in Moscow in 1932. Subsequently, in 1939, the Soviet Union reports experimentally produced foam glass at the intermediate pilot plant of the Mendeleev Institute of Chemical Technology. A glass powder screened through a 0.09 mm mesh was mixed with limestone and later on with anthracite and coal as gasifier. The product that is known today as Foamglas cellular glass insulation, was developed by Pittsburgh Corning and was later acquired by
Owens Corning Owens Corning is an American company that develops and produces insulation, roofing, and fiberglass composites and related materials and products. It is the world's largest manufacturer of fiberglass composites. It was formed in 1935 as a partn ...
. It is made of
cullet Glass recycling is the processing of waste glass into usable products. Glass that is crushed or imploded and ready to be remelted is called cullet. There are two types of cullet: internal and external. Internal cullet is composed of defective p ...
, foaming agent, modified additive and foaming accelerator. After fine pulverization and uniform mixing, it is melted at high temperature, foamed and annealed. An inorganic non-metallic glass material, it consists of a large number of uniform bubble structures with a diameter of 1 to 2 mm. Sound-absorbing Foamglas insulation is more than 50% open cell bubbles, and heat-insulating Foamglas is more than 75% closed-cell air bubbles, which can be adjusted according to the requirements of use through changes in production technical parameters. Similar products by other manufacturers are sold as 'cellular glass' or 'foam glass'.


Properties

Because this material is moisture-proof, fireproof, and anti-corrosive, and the glass material has the advantages of long-term use performance, it is favored for uses in harsh environments such as in heat insulation, deep cooling, underground, open-air, flammable, damp, and under chemical attack. It is widely used in wall insulation, petroleum, chemical industry, machine room noise reduction, highway sound absorption barrier, electric power, military products, etc. and is called green environmental protection
insulation material Building insulation materials are the building materials which form the thermal envelope of a building or otherwise reduce heat transfer. Insulation may be categorized by its composition (natural or synthetic materials), form (batts, blankets, lo ...
by users. Depending on the properties of the foam glass, it can be used as insulation material in various sectors of construction engineering, as well as in shipbuilding, chemical, cryogenic, and high-temperature technologies. White and stained glass are also used as sound absorbing and decorative materials. Waste in production – foamed glass powder and scrap can also be used as fillers for decorative light concrete and other applications. Depending on the application, foam glass products produced by the corresponding processes can be divided into four categories, namely insulating foam glass, sound-absorbing decorative foam glass, facing foam glass, and granular foam glass. Foam glass is a kind of lightweight, high-strength building material and decorative material with excellent performance (insulation) and sound absorption that is both moisture-proof and fireproof. The temperature range is from -196 degrees to 450 degrees Celsius. Although other new insulation materials emerge in an endless stream, foam glass occupies an increasingly important position in the fields of low thermal insulation, moisture-proof engineering, and sound absorption due to its permanence, safety, and high reliability. Its production is the recycling of waste solid materials, which is an example of protecting the environment and obtaining substantial economic benefits. Recently, it is available in monolitic dimensions of 2.8 x 1.2m. Lava foam glass: natural lava such as
obsidian Obsidian () is a naturally occurring volcanic glass formed when lava extrusive rock, extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock. Obsidian is produced from felsic lava, rich in the lighter elements s ...
and industrial waste slag is used as the base material, and a certain amount of glass powder can also be added to reduce the foaming temperature and foam glass made of or the like as a foaming agent. Generally used as insulation materials and wall materials for construction and industrial equipment.


Application

Foam glass is fireproof, waterproof, non-toxic, corrosion-resistant, anti-mite, non-aging, non-radioactive, and insulating. Anti-magnetic wave, anti-static, high mechanical strength, with good adhesion to various types of mud. It is a stable building exterior wall and roof insulation, sound insulation, and waterproof material. According to reports, foam glass can be used in places that require sound insulation and heat insulation, leak prevention and flood control. It has functions for home cleaning and health care. The use of foam glass to protect the heating duct reduces heat loss by approximately 25% compared to conventional protective materials. Foam glass, also known as
porous glass Porous glass is glass that includes pores, usually in the nanometre- or micrometre-range, commonly prepared by one of the following processes: through metastable phase separation in borosilicate glasses (such as in their system SiO2-B2O3-Na2O), fo ...
, is filled with numerous open or closed small pores. The area of the pores is 80%~90% of the total volume, and the pore size is 0.5~5mm, and some are as small as a few microns. 1. The matrix of the foam glass is glass, so it does not absorb water. The internal bubbles are also closed, so there is no capillary phenomenon and no penetration, so foam glass is currently the most ideal thermal insulation material. 2. The mechanical strength is high, and the intensity change is proportional to the apparent density. It has excellent pressure resistance and can withstand the erosion and load of the external environment more than other materials. The combination of excellent compression resistance and moisture barrier properties makes foam glass an ideal thermal insulation material for underground pipelines and tank foundations. 3. Foam glass has good thermal and moisture permeability, so thermal conductivity is stable for a long time, and it does not change due to environmental influences, and the thermal insulation performance is good. 4. Foam glass is a matrix wet glass, so it will not burn spontaneously and will not be burned. It is an excellent fireproof material. Foam glass has an operating temperature range of -200 to 430 °C, a small expansion coefficient (8 × 10 °C) and is reversible, so the material properties are unchanged for a long time, are not easy to embrittle, and have good stability. 5. Foam glass has good sound insulation performance and strong absorption of sound waves. The average penetration loss is 28.3 dB in 60~400 Hz. 6. The dyeing property of foam glass is good, so it can be used as insulation decoration materials. Foam glass insulation aggregate is used in the same way as coated clay aggregate but is capable of being used as a load-bearing
hardcore Hardcore, hard core or hard-core may refer to: Arts and media Film * ''Hardcore'' (1977 film), a British comedy film * ''Hardcore'' (1979 film), an American crime drama film starring George C Scott * ''Hardcore'' (2001 film), a British documen ...
. It also offers better insulation (lambda/k value = 0.08 – approximately 20% lower
thermal conductivity The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
than lightweight expanded clay aggregate). It therefore needs less depth for similar thermal performance.


See also

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Nanofoam Nanofoams are a class of nanostructured, porous materials (foams) containing a significant population of pores with diameters less than 100 nm. Aerogels are one example of nanofoam. Metal Overview Metallic nanofoams are a subcategorization ...
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Metal foam Regular foamed aluminium A metal foam is a cellular structure consisting of a solid metal (frequently aluminium) with gas-filled pores comprising a large portion of the volume. The pores can be sealed (closed-cell foam) or interconnected (open-c ...
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Ceramic foam Ceramic foam is a tough foam made from ceramics. Manufacturing techniques include impregnating open-cell polymer foams internally with ceramic slurry and then firing in a kiln, leaving only ceramic material. The foams may consist of several ceramic ...
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Porous medium A porous medium or a porous material is a material containing pores (voids). The skeletal portion of the material is often called the "matrix" or "frame". The pores are typically filled with a fluid (liquid or gas). The skeletal material is usua ...
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Reticulated foam Reticulated foam is a very porous, low density solid foam. 'Reticulated' means like a net. Reticulated foams are extremely open foams i.e. there are few, if any, intact bubbles or cell windows. In contrast, the foam formed by soap bubbles is compo ...
*
Foam Glass Gravel Foam glass gravel is a building material made from recycled glass. Characteristics Foam glass gravel is light and dimensionally stable, with a lambda rating of 0.08 W/mK and a specific weight of 150 kg per cubic metre. Being made from g ...


References


External links

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Foam glass
-Britannica online * {{cite journal, author=GE Wei-qing, author2=YANG Jing, title=The Study of the Present Situation of Foam Glass and Development Trend in China , journal=Journal of Tangshan College, date=2008, volume=21, issue=2, pages=66–67, 86 , issn=1672-349X, url=http://en.cnki.com.cn/Article_en/CJFDTOTAL-TSGD200802026.htm Building materials Building insulation materials