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{{refimprove, date=June 2008 A fluoroelastomer is a
fluorocarbon Fluorocarbons are chemical compounds with carbon-fluorine bonds. Compounds that contain many C-F bonds often has distinctive properties, e.g., enhanced stability, volatility, and hydrophobicity. Fluorocarbons and their derivatives are commerci ...
-based
synthetic rubber A synthetic rubber is an artificial elastomer. They are polymers synthesized from petroleum byproducts. About 32-million metric tons of rubbers are produced annually in the United States, and of that amount two thirds are synthetic. Synthetic rubbe ...
. Fluroelastomers generally have wide chemical resistance.


Composition

Several compositions of fluoroelastomers exist including
FKM FKM is a family of fluorocarbon-based fluoroelastomer materials defined by ASTM International standard D1418, and ISO 1629, ISO standard 1629. It is commonly called fluorine rubber or fluoro-rubber. FKM is an abreveation of Fluorine Kautschuk Mate ...
(by ASTM D1418 standard, equivalent to FPM by ISO/DIN 1629 standard); perfluoro-elastomers (
FFKM FFKMs (by ASTM 1418 standard) (equivalent to FFPMs by ISO/DIN 1629 standard) are perfluoroelastomeric compounds containing an even higher amount of fluorine than FKM fluoroelastomers. They have improved resistance to high temperatures and chemic ...
); and tetrafluoro ethylene/propylene rubbers ( FEPM).


Performance

The performance of fluoroelastomers in aggressive chemicals depends on the nature of the base polymer and the compounding ingredients used for moulding the final products (e.g. O-rings, shaft seals). This performance can vary significantly when end-users purchase polymer containing rubber goods from different sources. Fluoroelastomers are generally compatible with hydrocarbons, but incompatible with
ketone In organic chemistry, a ketone is a functional group with the structure R–C(=O)–R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group –C(=O)– (which contains a carbon-oxygen double bo ...
s such as
acetone Acetone (2-propanone or dimethyl ketone), is an organic compound with the formula . It is the simplest and smallest ketone (). It is a colorless, highly volatile and flammable liquid with a characteristic pungent odour. Acetone is miscib ...
and organic acids such as
acetic acid Acetic acid , systematically named ethanoic acid , is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main component ...
.


References

Fluoropolymers Elastomers


Weblinks


Properties of Elastomers - Chemical Resitancelist
(PDF; 0,6 MB)
Designing with Fluoroelastomers
(PDF; 0,8 MB)