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Flint, occasionally flintstone, is a
sedimentary Sedimentary rocks are types of rock (geology), rock that are formed by the accumulation or deposition of mineral or organic matter, organic particles at Earth#Surface, Earth's surface, followed by cementation (geology), cementation. Sedimentati ...
cryptocrystalline Cryptocrystalline is a rock microstructure, rock texture made up of such minute crystals that its crystalline nature is only vaguely revealed even microscopically in thin section by transmitted polarized light. Among the sedimentary rocks, chert a ...
form of the
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
, categorized as the variety of
chert Chert () is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a prec ...
that occurs in
chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Chalk ...
or
marl Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae. Marl makes up the lower part o ...
y
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
. Flint was widely used historically to make
stone tool A stone tool is, in the most general sense, any tool made either partially or entirely out of stone. Although stone tool-dependent societies and cultures still exist today, most stone tools are associated with prehistoric (particularly Stone Ag ...
s and start fires. It occurs chiefly as nodules and masses in sedimentary rocks, such as
chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Chalk ...
s and
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
s.''The Flints from Portsdown Hill''
Inside the nodule, flint is usually dark grey, black, green, white or brown in colour, and often has a glassy or waxy appearance. A thin layer on the outside of the nodules is usually different in colour, typically white and rough in texture. The nodules can often be found along
stream A stream is a continuous body of water, body of surface water Current (stream), flowing within the stream bed, bed and bank (geography), banks of a channel (geography), channel. Depending on its location or certain characteristics, a stream ...
s and
beach A beach is a landform alongside a body of water which consists of loose particles. The particles composing a beach are typically made from rock, such as sand, gravel, shingle, pebbles, etc., or biological sources, such as mollusc shel ...
es. Flint breaks and chips into sharp-edged pieces, making it useful for knife blades and other cutting tools. The use of flint to make
stone tools A stone tool is, in the most general sense, any tool made either partially or entirely out of stone. Although stone tool-dependent societies and cultures still exist today, most stone tools are associated with prehistoric (particularly Stone Ag ...
dates back hundreds of thousands of years, and flint's extreme durability has made it possible to accurately date its use over this time. Flint is one of the primary materials used to define the
Stone Age The Stone Age was a broad prehistoric period during which stone was widely used to make tools with an edge, a point, or a percussion surface. The period lasted for roughly 3.4 million years, and ended between 4,000 BC and 2,000 BC, with t ...
. During the Stone Age, access to flint was so important for survival that people would travel or trade to obtain flint. Flint Ridge in
Ohio Ohio () is a state in the Midwestern region of the United States. Of the fifty U.S. states, it is the 34th-largest by area, and with a population of nearly 11.8 million, is the seventh-most populous and tenth-most densely populated. The sta ...
was an important source of flint and Native Americans extracted the flint from hundreds of quarries along the ridge. This "Ohio Flint" was traded across the eastern United States and has been found as far west as the
Rocky Mountains The Rocky Mountains, also known as the Rockies, are a major mountain range and the largest mountain system in North America. The Rocky Mountains stretch in straight-line distance from the northernmost part of western Canada, to New Mexico in ...
and south around the
Gulf of Mexico The Gulf of Mexico ( es, Golfo de México) is an oceanic basin, ocean basin and a marginal sea of the Atlantic Ocean, largely surrounded by the North American continent. It is bounded on the northeast, north and northwest by the Gulf Coast of ...
. When struck against steel, flint will produce enough sparks to ignite a fire with the correct
tinder Tinder is easily combustible material used to start a fire. Tinder is a finely divided, open material which will begin to glow under a shower of sparks. Air is gently wafted over the glowing tinder until it bursts into flame. The flaming tinder i ...
, or
gunpowder Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). ...
used in weapons, namely the
flintlock Flintlock is a general term for any firearm that uses a flint-striking lock (firearm), ignition mechanism, the first of which appeared in Western Europe in the early 16th century. The term may also apply to a particular form of the mechanism its ...
firing mechanism A trigger is a mechanism that actuates the function of a ranged weapon such as a firearm, airgun, crossbow, or speargun. The word may also be used to describe a switch that initiates the operation of other non-shooting devices such as a trap, ...
. Although it has been superseded in these uses by different processes (the
percussion cap The percussion cap or percussion primer, introduced in the early 1820s, is a type of single-use percussion ignition device for muzzle loader firearm locks enabling them to fire reliably in any weather condition. This crucial invention gave rise t ...
), or materials (
ferrocerium Ferrocerium (also known in Europe as Auermetall) is a synthetic pyrophoric alloy of mischmetal (cerium, lanthanum, neodymium, other trace lanthanides and some iron – about 95% lanthanides and 5% iron) hardened by blending in oxides of ...
), "flint" has lent its name as generic term for a fire starter.


Origin

The exact mode of formation of flint is not yet clear, but it is thought that it occurs as a result of chemical changes in compressed sedimentary rock formations during the process of
diagenesis Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
. One
hypothesis A hypothesis (plural hypotheses) is a proposed explanation for a phenomenon. For a hypothesis to be a scientific hypothesis, the scientific method requires that one can test it. Scientists generally base scientific hypotheses on previous obse ...
is that a gelatinous material fills cavities in the sediment, such as holes bored by
crustaceans Crustaceans (Crustacea, ) form a large, diverse arthropod taxon which includes such animals as decapods, seed shrimp, branchiopods, fish lice, krill, remipedes, isopods, barnacles, copepods, amphipods and mantis shrimp. The crustacean group ...
or
molluscs Mollusca is the second-largest phylum of invertebrate animals after the Arthropoda, the members of which are known as molluscs or mollusks (). Around 85,000 extant taxon, extant species of molluscs are recognized. The number of fossil sp ...
and that this becomes
silicified In geology, petrifaction or petrification () is the process by which organic material becomes a fossil through the replacement of the original material and the filling of the original pore spaces with minerals. Petrified wood typifies this proce ...
. This hypothesis would certainly explain the complex shapes of flint nodules that are found. The source of dissolved silica in the porous media could be the
spicules of silicious sponges Spicules are structural elements found in most sponges. The meshing of many spicules serves as the sponge's skeleton and thus it provides structural support and potentially defense against predators. Sponge spicules are made of calcium carbon ...
(
demosponge Demosponges (Demospongiae) are the most diverse class in the phylum Porifera. They include 76.2% of all species of sponges with nearly 8,800 species worldwide (World Porifera Database). They are sponges with a soft body that covers a har ...
s). Certain types of flint, such as that from the south coast of England and its counterpart on the French side of the
Channel Channel, channels, channeling, etc., may refer to: Geography * Channel (geography), in physical geography, a landform consisting of the outline (banks) of the path of a narrow body of water. Australia * Channel Country, region of outback Austral ...
, contain trapped fossilised marine flora. Pieces of coral and vegetation have been found preserved inside the flint similar to insects and plant parts within
amber Amber is fossilized tree resin that has been appreciated for its color and natural beauty since Neolithic times. Much valued from antiquity to the present as a gemstone, amber is made into a variety of decorative objects."Amber" (2004). In Ma ...
. Thin slices of the stone often reveal this effect. Flint sometimes occurs in large
flint fields Flint fields (german: Feuersteinfelder) are large natural deposits of flint. They are found in numerous Jurassic and Cretaceous beds across the whole of Europe.
in
Jurassic The Jurassic ( ) is a Geological period, geologic period and System (stratigraphy), stratigraphic system that spanned from the end of the Triassic Period million years ago (Mya) to the beginning of the Cretaceous Period, approximately Mya. The J ...
or
Cretaceous The Cretaceous ( ) is a geological period that lasted from about 145 to 66 million years ago (Mya). It is the third and final period of the Mesozoic Era, as well as the longest. At around 79 million years, it is the longest geological period of th ...
beds, for example, in Europe. Puzzling giant flint formations known as
paramoudra Paramoudras, paramoudra flints, pot stones or potstones are flint nodules found mainly in parts of north-west Europe: Norfolk (United Kingdom), Ireland, Denmark, Spain and Germany. In Norfolk they are known as pot stones and can be found on th ...
and flint circles are found around Europe but especially in Norfolk, England on the beaches at Beeston Bump and
West Runton West Runton is a village in North Norfolk, England, on the North Sea coast. Toponymy The villages name means either, Runa's farm/settlement' or 'Runi's farm/settlement'. Overview West Runton and East Runton together form the parish of Runton ...
. The "Ohio flint" is the official gemstone of Ohio state. It is formed from limey debris that was deposited at the bottom of inland
Paleozoic The Paleozoic (or Palaeozoic) Era is the earliest of three geologic eras of the Phanerozoic Eon. The name ''Paleozoic'' ( ;) was coined by the British geologist Adam Sedgwick in 1838 by combining the Greek words ''palaiós'' (, "old") and ' ...
seas hundreds of millions of years ago that hardened into
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
and later became infused with
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
. The flint from Flint Ridge is found in many hues like red, green, pink, blue, white and gray, with the color variations caused by minute impurities of iron compounds. Flint can be coloured: sandy brown, medium to dark gray, black, reddish brown or an off-white grey.


Uses


Tools or cutting edges

Flint was used in the manufacture of tools during the
Stone Age The Stone Age was a broad prehistoric period during which stone was widely used to make tools with an edge, a point, or a percussion surface. The period lasted for roughly 3.4 million years, and ended between 4,000 BC and 2,000 BC, with t ...
as it splits into thin, sharp splinters called flakes or blades (depending on the shape) when struck by another hard object (such as a
hammerstone In archaeology, a hammerstone is a hard cobble used to strike off lithic flakes from a lump of tool stone during the process of lithic reduction. The hammerstone is a rather universal stone tool which appeared early in most regions of the wo ...
made of another material). This process is referred to as knapping. Flint mining is attested since the
Paleolithic The Paleolithic or Palaeolithic (), also called the Old Stone Age (from Greek: παλαιός ''palaios'', "old" and λίθος ''lithos'', "stone"), is a period in human prehistory that is distinguished by the original development of stone too ...
, but became more common since the Neolithic (Michelsberg culture, Funnelbeaker culture). In Europe, some of the best toolmaking flint has come from Belgium (Obourg, flint mines of Spiennes), the coastal chalks of the English Channel, the Paris Basin, Thy in Jutland (flint mine at Hov), the Sennonian deposits of Rügen, Grimes Graves in England, the Upper Cretaceous chalk formation of Dobruja and the lower Danube (Balkan flint), the Cenomanian chalky marl formation of the Moldavian Plateau (Miorcani flint) and the
Jurassic The Jurassic ( ) is a Geological period, geologic period and System (stratigraphy), stratigraphic system that spanned from the end of the Triassic Period million years ago (Mya) to the beginning of the Cretaceous Period, approximately Mya. The J ...
deposits of the Kraków area and Krzemionki in Poland, as well as of the Lägern ( silex) in the
Jura Mountains The Jura Mountains ( , , , ; french: Massif du Jura; german: Juragebirge; it, Massiccio del Giura, rm, Montagnas da Jura) are a sub-alpine mountain range a short distance north of the Western Alps and mainly demarcate a long part of the Frenc ...
of Switzerland. In 1938, a project of the Ohio Historical Society, under the leadership of H. Holmes Ellis began to study the knapping methods and techniques of Native Americans. Like past studies, this work involved experimenting with actual knapping techniques by creation of stone tools through the use of techniques like direct freehand percussion, freehand pressure and pressure using a rest. Other scholars who have conducted similar experiments and studies include William Henry Holmes,
Alonzo W. Pond Alonzo W. Pond (1894–25 December 1986) was an American archaeologist. Born in Janesville, Wisconsin, he was assistant curator of the Logan Museum of Anthropology in Beloit, Wisconsin in 1924. Between 1925 and 1930 he conducted excavations of preh ...
, Francis H. S. Knowles and Don Crabtree. To combat fragmentation, flint/chert may be heat-treated, being slowly brought up to a temperature of for 24 hours, then slowly cooled to room temperature. This makes the material more homogeneous and thus more knappable and produces tools with a cleaner, sharper cutting edge. Heat treating was known to Stone Age artisans.


To ignite fire or gunpowder

When struck against steel, a flint edge produces sparks. The hard flint edge shaves off a particle of the steel that exposes iron, which reacts with oxygen from the atmosphere and can ignite the proper
tinder Tinder is easily combustible material used to start a fire. Tinder is a finely divided, open material which will begin to glow under a shower of sparks. Air is gently wafted over the glowing tinder until it bursts into flame. The flaming tinder i ...
. Prior to the wide availability of steel, rocks of pyrite (FeS2) would be used along with the flint, in a similar (but more time-consuming) way. These methods remain popular in woodcraft, bushcraft, and amongst people practising traditional fire-starting skills.


Flintlocks

A later, major use of flint and steel was in the flintlock mechanism, used primarily in
flintlock Flintlock is a general term for any firearm that uses a flint-striking lock (firearm), ignition mechanism, the first of which appeared in Western Europe in the early 16th century. The term may also apply to a particular form of the mechanism its ...
firearms, but also used on dedicated fire-starting tools. A piece of flint held in the jaws of a spring-loaded hammer, when released by a trigger, strikes a hinged piece of steel (" frizzen") at an angle, creating a shower of sparks and exposing a charge of priming powder. The sparks ignite the priming powder and that flame, in turn, ignites the main charge, propelling the ball, bullet, or shot through the barrel. While the military use of the flintlock declined after the adoption of the
percussion cap The percussion cap or percussion primer, introduced in the early 1820s, is a type of single-use percussion ignition device for muzzle loader firearm locks enabling them to fire reliably in any weather condition. This crucial invention gave rise t ...
from the 1840s onward, flintlock rifles and shotguns remain in use amongst recreational shooters.


Comparison with ferrocerium

Flint and steel used to strike sparks were superseded in the 20th century by
ferrocerium Ferrocerium (also known in Europe as Auermetall) is a synthetic pyrophoric alloy of mischmetal (cerium, lanthanum, neodymium, other trace lanthanides and some iron – about 95% lanthanides and 5% iron) hardened by blending in oxides of ...
(sometimes referred to as "flint", although not true flint, " mischmetal", "hot spark", "metal match", or "fire steel"). This man-made material, when scraped with any hard, sharp edge, produces sparks that are much hotter than obtained with natural flint and steel, allowing use of a wider range of tinders. Because it can produce sparks when wet and can start fires when used correctly, ferrocerium is commonly included in survival kits. Ferrocerium is used in many cigarette lighters, where it is referred to as "a flint".


Fragmentation

Flint's utility as a fire starter is hampered by its property of uneven expansion under heating, causing it to fracture, sometimes violently, during heating. This tendency is enhanced by the impurities found in most samples of flint that may expand to a greater or lesser degree than the surrounding stone, and is similar to the tendency of glass to shatter when exposed to heat, and can become a drawback when flint is used as a building material.


As a building material

Flint, knapped or unknapped, has been used from antiquity (for example at the Late Roman fort of Burgh Castle in Norfolk) up to the present day as a material for building stone walls, using lime mortar, and often combined with other available stone or brick rubble. It was most common in those parts of southern England where no good building stone was available locally, and where brick-making was not widespread until the later Middle Ages. It is especially associated with
East Anglia East Anglia is an area in the East of England, often defined as including the counties of Norfolk, Suffolk and Cambridgeshire. The name derives from the Anglo-Saxon kingdom of the East Angles, a people whose name originated in Anglia, in ...
, but also used in chalky areas stretching through Hampshire, Sussex,
Surrey Surrey () is a ceremonial and non-metropolitan county in South East England, bordering Greater London to the south west. Surrey has a large rural area, and several significant urban areas which form part of the Greater London Built-up Area. ...
and Kent to Somerset. Flint was used in the construction of many churches, houses, and other buildings, for example, the large stronghold of Framlingham Castle. Many different decorative effects have been achieved by using different types of knapping or arrangement and combinations with stone ( flushwork), especially in the 15th and early 16th centuries. Because knapping flints to a relatively flush surface and size is a highly skilled process with a high level of wastage, flint finishes typically indicate high status buildings. During World War I, in the chalky-soil country of France, the British filled sandbags with flint and used these sandbags as breastworks. File:flint church in england arp.jpg, A flint church – the Parish Church of Saint Thomas, in
Cricket Saint Thomas Cricket St Thomas is a parish in Somerset, England, situated in a valley between Chard and Crewkerne within the South Somerset administrative district. The A30 road passes nearby. The parish has a population of 50. It is noted for the historic ...
, Somerset, England. The height of the very neatly knapped flints varies between . File:Gariannonum Burgh Castle south wall well preserved close up.jpg, Close-up of the wall of the Roman shore fort at Burgh Castle, Norfolk, showing alternating courses of flint and
brick A brick is a type of block used to build walls, pavements and other elements in masonry construction. Properly, the term ''brick'' denotes a block composed of dried clay, but is now also used informally to denote other chemically cured cons ...
File:Surroundings of Canterbury Cathedral 02.JPG, A typical medieval wall (with modern memorial) at
Canterbury Cathedral Canterbury Cathedral in Canterbury, Kent, is one of the oldest and most famous Christian structures in England. It forms part of a World Heritage Site. It is the cathedral of the Archbishop of Canterbury, currently Justin Welby, leader of the ...
– knapped and unknapped ("cobble") flints are mixed with pieces of brick and other stones File:2004 thetford 03.JPG, Ruins of Thetford Priory show flints and mortar through the whole depth of the wall


Ceramics

Flint pebbles are used as the media in ball mills to grind glazes and other raw materials for the ceramics industry. The pebbles are hand-selected based on colour; those having a tint of red, indicating high iron content, are discarded. The remaining blue-grey stones have a low content of
chromophoric A chromophore is the part of a molecule responsible for its color. The color that is seen by our eyes is the one not absorbed by the reflecting object within a certain wavelength spectrum of visible light. The chromophore is a region in the molec ...
oxides and so are less deleterious to the colour of the ceramic composition after firing. Until recently flint was also an important raw material in clay-based ceramic bodies produced in the UK. In preparation for use flint pebbles, frequently sourced from the coasts of South-East England or Western France, were calcined to around . This heating process both removed organic impurities and induced certain physical reactions, including converting some of the silica to cristobalite. After calcination the flint pebbles were milled to a fine particle size. However, the use of flint has now been superseded by
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
. Because of the historical use of flint, the word “flint” is used by some potters (especially in the U.S.) to refer generically to siliceous materials used in ceramics that are not flint.


Jewelry

Flint bracelets were known in Ancient Egypt, and several examples have been found.


See also

Mineralogy * * * * * * not to be confused with concretion * * * * Archaeology * * , archaeological artefacts of the Clovis culture in New Mexico, USA * , a prehistoric flint mine in Norfolk, England * , a Native American flint quarry in Hopewell Township, Licking County, Ohio, US *


References


External links


Flint Architecture of East Anglia
Book by Stephen Hart
Flintsource.net European Artefacts – detailed site



Paramoudras and flint circles photograph collection




Introduction to the historical use of flint in construction and the repair and conservation of historic flint buildings {{Authority control Sedimentary rocks Chert Lithics Firelighting Firelighting using percussion Building stone