Engineered cementitious composite
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Engineered Cementitious Composite (ECC), also called Strain Hardening Cement-based Composites (SHCC) or more popularly as bendable concrete, is an easily molded mortar-based composite reinforced with specially selected short random fibers, usually
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
fibers. Unlike regular
concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wi ...
, ECC has a tensile strain capacity in the range of 3–7%, compared to 0.01% for ordinary portland cement (OPC) paste, mortar or concrete. ECC therefore acts more like a ductile
metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
material rather than a brittle
glass Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenching) of ...
material (as does OPC concrete), leading to a wide variety of applications.


Development

ECC, unlike common fiber reinforced concrete, is a family of micromechanically designed materials. As long as a cementitious material is designed/developed based on micromechanics and fracture mechanics theory to feature large tensile ductility, it can be called an ECC. Therefore, ECC is not a fixed material design, but a broad range of topics under different stages of research, development, and implementations. The ECC material family is expanding. The development of an individual mix design of ECC requires special efforts by systematically engineering of the material at nano-, micro-, macro- and composite scales. ECC looks similar to ordinary Portland cement-based concrete, except that it can deform (or bend) under strain. A number of research groups are developing ECC science, including those at the
University of Michigan , mottoeng = "Arts, Knowledge, Truth" , former_names = Catholepistemiad, or University of Michigania (1817–1821) , budget = $10.3 billion (2021) , endowment = $17 billion (2021)As o ...
,
University of California, Irvine The University of California, Irvine (UCI or UC Irvine) is a public land-grant research university in Irvine, California. One of the ten campuses of the University of California system, UCI offers 87 undergraduate degrees and 129 graduate and pr ...
, Delft University of Technology, the University of Tokyo, the
Czech Technical University Czech Technical University in Prague (CTU, cs, České vysoké učení technické v Praze, ČVUT) is one of the largest universities in the Czech Republic with 8 faculties, and is one of the oldest institutes of technology in Central Europe. It ...
,
University of British Columbia The University of British Columbia (UBC) is a public university, public research university with campuses near Vancouver and in Kelowna, British Columbia. Established in 1908, it is British Columbia's oldest university. The university ranks a ...
, and
Stanford University Stanford University, officially Leland Stanford Junior University, is a private research university in Stanford, California. The campus occupies , among the largest in the United States, and enrolls over 17,000 students. Stanford is consider ...
. Traditional concrete's lack of durability and failure under strain, both stemming from brittle behavior, have been a pushing factor in the development of ECC.


Properties

ECC has a variety of unique properties, including tensile properties superior to other fiber-reinforced composites, ease of processing on par with conventional cement, the use of only a small volume fraction of fibers (~ 2%), tight crack width, and a lack of anisotropically weak planes. These properties are due largely to the interaction between the fibers and cementing matrix, which can be custom-tailored through micromechanics design. Essentially, the fibers create many microcracks with a very specific width, rather than a few very large cracks (as in conventional concrete.) This allows ECC to deform without catastrophic failure. This microcracking behavior leads to superior
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
resistance (the cracks are so small and numerous that it is difficult for aggressive media to penetrate and attack the reinforcing steel) as well as to self-healing. In the presence of water (during a rainstorm, for instance) unreacted cement particles recently exposed due to cracking hydrate and form a number of products ( calcium silicate hydrates (C-S-H),
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
, etc.) that expand and fill in the crack. These products appear as a white ‘scar’ material filling in the crack. This self-healing behavior not only seals the crack to prevent transport of fluids, but mechanical properties are regained. This self-healing has been observed in a variety of conventional cement and concretes; however, above a certain crack width self healing becomes less effective. It is the tightly controlled crack widths seen in ECC that ensure all cracks thoroughly heal when exposed to the natural environment. When combined with a more conductive material, all cement materials can increase and be used for damage-sensing. This is essentially based on the fact that conductivity will change as damage occurs; the addition of conductive material is meant to raise the conductivity to a level where such changes will be easily identified. Though not a material property of ECC itself, semi-conductive ECC for damage-sensing are being developed.


Types

There are a number of different varieties of ECC, including: *Lightweight (i.e. low density) ECC have been developed through the addition of air voids, glass bubbles, polymer spheres, and/or lightweight aggregate. Compared to other lightweight concretes, lightweight ECC has superior ductility. Applications include floating homes, barges, and canoes. *‘Self compacting concrete’ refers to a
concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wi ...
that can flow under its own weight. For instance, a self-compacting material would be able to fill a mold containing elaborate pre-positioned steel reinforcement without the need of vibration or shaking to ensure even distribution. Self-compacting ECC was developed through the use of chemical admixtures to decrease viscosity and through controlling particle interactions with mix proportioning. *Sprayable ECC, which can be pneumatically sprayed from a hose, have been developed by using various superplasticizing agents and viscosity-reducing admixtures. Compared to other sprayable fiber-reinforced composites, sprayable ECC has enhanced pumpability in addition to its unique mechanical properties. Sprayable ECC has been used for retrofitting/repair work and tunnel/sewer linings. *An extrudable ECC for use in the extrusion of pipes was first developed in 1998. Extruded ECC pipes have both higher load capacity and higher deformability than any other extruded fiber-reinforced composite pipes.


Field applications

ECC have found use in a number of large-scale applications in Japan, Korea, Switzerland, Australia and the U.S. These include: * The Mitaka Dam near
Hiroshima is the capital of Hiroshima Prefecture in Japan. , the city had an estimated population of 1,199,391. The gross domestic product (GDP) in Greater Hiroshima, Hiroshima Urban Employment Area, was US$61.3 billion as of 2010. Kazumi Matsui h ...
was repaired using ECC in 2003. The surface of the then 60-year-old dam was severely damaged, showing evidence of cracks, spalling, and some water leakage. A 20 mm-thick layer of ECC was applied by spraying over the 600 m2 surface. * Also in 2003, an earth retaining wall in Gifu, Japan, was repaired using ECC. Ordinary
portland cement Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th c ...
could not be used due to the severity of the cracking in the original structure, which would have caused reflective cracking. ECC was intended to minimize this danger; after one year only microcracks of tolerable width were observed. * The 95 m (312 ft.) Glorio Roppongi high-rise apartment building in
Tokyo Tokyo (; ja, 東京, , ), officially the Tokyo Metropolis ( ja, 東京都, label=none, ), is the capital and largest city of Japan. Formerly known as Edo, its metropolitan area () is the most populous in the world, with an estimated 37.468 ...
contains a total of 54 ECC coupling beams (two per story) intended to mitigate earthquake damage. The properties of ECC (high damage tolerance, high energy absorption, and ability to deform under shear) give it superior properties in seismic resistance applications when compared to ordinary
portland cement Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th c ...
. Similar structures include the 41-story Nabeaure Yokohama Tower (four coupling beams per floor.) * The long Mihara Bridge in
Hokkaido is Japan's second largest island and comprises the largest and northernmost prefecture, making up its own region. The Tsugaru Strait separates Hokkaidō from Honshu; the two islands are connected by the undersea railway Seikan Tunnel. The la ...
, Japan was opened to traffic in 2005. The steel-reinforced road bed contains nearly 800 m3 of ECC material. The tensile ductility and tight crack control behavior of ECC led to a 40% reduction in material used during construction. * Similarly, a 225-mm thick ECC bridge deck on interstate 94 in
Michigan Michigan () is a state in the Great Lakes region of the upper Midwestern United States. With a population of nearly 10.12 million and an area of nearly , Michigan is the 10th-largest state by population, the 11th-largest by area, and the ...
was completed in 2005. 30 m3 of material was used, delivered on-site in standard mixing trucks. Due to the unique mechanical properties of ECC, this deck also used less material than a proposed deck made of ordinary portland cement. Both the
University of Michigan , mottoeng = "Arts, Knowledge, Truth" , former_names = Catholepistemiad, or University of Michigania (1817–1821) , budget = $10.3 billion (2021) , endowment = $17 billion (2021)As o ...
and the Michigan Department of Transportation are monitoring the bridge in an attempt to verify the theoretical superior durability of ECC; after four years of monitoring, performance remained undiminished. * The first self-consolidating and high-early-strength ECC patch repair was placed on Ellsworth Road Bridge over US-23 in November 2006.Li, M., Multi-Scale Design for Durable Repair of Concrete Structures, Ph.D. Dissertation, University of Michigan, 2009. The high-early-strength ECC can achieve a compressive strength of 23.59 ± 1.40 MPa (3422.16 ± 203.33 psi) in four hours and 55.59 ± 2.17 MPa (8062.90 ± 315.03 psi) in 28 days, allowing for fast repair and re-opening the session to traffic. The high-early-strength ECC repair has shown superior long-term durability in field conditions compared to typical concrete repair materials.


Comparison to other composite materials

Note: FRC=Fiber-Reinforced Cement. HPFRCC=High-Performance Fiber Reinforced Cementitious Composites


See also

*
High performance fiber reinforced cementitious composites High-performance fiber-reinforced cementitious composites (HPFRCCs) are a group of fiber-reinforced cement-based composites that possess the unique ability to flex and self-strengthen before fracturing. This particular class of concrete was develop ...


References


External links


Victor Li's ECC research group at the University of Michigan
* {{DEFAULTSORT:Engineered Cementitious Composite Concrete Composite materials Building materials Heterogeneous chemical mixtures Fibre-reinforced cementitious materials