Electron Positron Accumulator
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The electron ( or ) is a subatomic particle with a negative one
elementary electric charge The elementary charge, usually denoted by is the electric charge carried by a single proton or, equivalently, the magnitude of the negative electric charge carried by a single electron, which has charge −1 . This elementary charge is a fund ...
. Electrons belong to the first
generation A generation refers to all of the people born and living at about the same time, regarded collectively. It can also be described as, "the average period, generally considered to be about 20–⁠30 years, during which children are born and gr ...
of the lepton particle family, and are generally thought to be
elementary particle In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions ( quarks, leptons, a ...
s because they have no known components or substructure. The electron's
mass Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a physical body, until the discovery of the atom and particle physics. It was found that different atoms and different eleme ...
is approximately 1/1836 that of the proton.
Quantum mechanical Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, qua ...
properties of the electron include an intrinsic
angular momentum In physics, angular momentum (rarely, moment of momentum or rotational momentum) is the rotational analog of linear momentum. It is an important physical quantity because it is a conserved quantity—the total angular momentum of a closed syst ...
( spin) of a half-integer value, expressed in units of the
reduced Planck constant The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivalen ...
, . Being fermions, no two electrons can occupy the same
quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution i ...
, in accordance with the
Pauli exclusion principle In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formulat ...
. Like all elementary particles, electrons exhibit properties of both particles and waves: They can collide with other particles and can be
diffracted Diffraction is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a s ...
like light. The wave properties of electrons are easier to observe with experiments than those of other particles like
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons beh ...
s and protons because electrons have a lower mass and hence a longer
de Broglie wavelength Matter waves are a central part of the theory of quantum mechanics, being an example of wave–particle duality. All matter exhibits wave-like behavior. For example, a beam of electrons can be diffracted just like a beam of light or a water wave ...
for a given energy. Electrons play an essential role in numerous physical phenomena, such as
electricity Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as describ ...
, magnetism, chemistry and
thermal conductivity The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
, and they also participate in gravitational,
electromagnetic In physics, electromagnetism is an interaction that occurs between particles with electric charge. It is the second-strongest of the four fundamental interactions, after the strong force, and it is the dominant force in the interactions o ...
and weak
interactions Interaction is action that occurs between two or more objects, with broad use in philosophy and the sciences. It may refer to: Science * Interaction hypothesis, a theory of second language acquisition * Interaction (statistics) * Interactions o ...
. Since an electron has charge, it has a surrounding electric field, and if that electron is moving relative to an observer, said observer will observe it to generate a magnetic field. Electromagnetic fields produced from other sources will affect the motion of an electron according to the Lorentz force law. Electrons radiate or absorb energy in the form of
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they a ...
s when they are accelerated. Laboratory instruments are capable of trapping individual electrons as well as electron plasma by the use of electromagnetic fields. Special
telescope A telescope is a device used to observe distant objects by their emission, absorption, or reflection of electromagnetic radiation. Originally meaning only an optical instrument using lenses, curved mirrors, or a combination of both to observ ...
s can detect electron plasma in outer space. Electrons are involved in many applications such as
tribology Tribology is the science and engineering of interacting surfaces in relative motion. It includes the study and application of the principles of friction, lubrication and wear. Tribology is highly interdisciplinary, drawing on many academic f ...
or frictional charging, electrolysis, electrochemistry, battery technologies,
electronics The field of electronics is a branch of physics and electrical engineering that deals with the emission, behaviour and effects of electrons using electronic devices. Electronics uses active devices to control electron flow by amplification ...
,
welding Welding is a fabrication process that joins materials, usually metals or thermoplastics, by using high heat to melt the parts together and allowing them to cool, causing fusion. Welding is distinct from lower temperature techniques such as bra ...
, cathode-ray tubes, photoelectricity, photovoltaic solar panels,
electron microscope An electron microscope is a microscope that uses a beam of accelerated electrons as a source of illumination. As the wavelength of an electron can be up to 100,000 times shorter than that of visible light photons, electron microscopes have a hi ...
s,
radiation therapy Radiation therapy or radiotherapy, often abbreviated RT, RTx, or XRT, is a therapy using ionizing radiation, generally provided as part of cancer treatment to control or kill malignant cells and normally delivered by a linear accelerator. Radi ...
,
lasers A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The fir ...
,
gaseous ionization detectors Gaseous ionization detectors are radiation detection instruments used in particle physics to detect the presence of ionizing particles, and in radiation protection applications to measure ionizing radiation. They use the ionising effect of radia ...
and
particle accelerator A particle accelerator is a machine that uses electromagnetic fields to propel charged particles to very high speeds and energies, and to contain them in well-defined beams. Large accelerators are used for fundamental research in particle ...
s. Interactions involving electrons with other subatomic particles are of interest in fields such as chemistry and
nuclear physics Nuclear physics is the field of physics that studies atomic nuclei and their constituents and interactions, in addition to the study of other forms of nuclear matter. Nuclear physics should not be confused with atomic physics, which studies the ...
. The Coulomb force interaction between the positive protons within atomic nuclei and the negative electrons without, allows the composition of the two known as
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, ...
s. Ionization or differences in the proportions of negative electrons versus positive nuclei changes the
binding energy In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a system of particles into individual parts. In the former meaning the term is predominantly use ...
of an atomic system. The exchange or sharing of the electrons between two or more atoms is the main cause of
chemical bond A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules and crystals. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of ...
ing. In 1838, British natural philosopher
Richard Laming Richard Laming (c. 1798–3 May 1879) was a British surgeon, natural philosopher, inventor, chemist and industrialist. There is some uncertainty about his origins. It is believed that he was born in Margate, England on 17 August 1799, the son o ...
first hypothesized the concept of an indivisible quantity of electric charge to explain the
chemical properties A chemical property is any of a material's properties that becomes evident during, or after, a chemical reaction; that is, any quality that can be established only by changing a substance's chemical identity.William L. Masterton, Cecile N. Hurley, ...
of atoms. Irish physicist George Johnstone Stoney named this charge 'electron' in 1891, and
J. J. Thomson Sir Joseph John Thomson (18 December 1856 – 30 August 1940) was a British physicist and Nobel Laureate in Physics, credited with the discovery of the electron, the first subatomic particle to be discovered. In 1897, Thomson showed that ...
and his team of British physicists identified it as a particle in 1897 during the cathode-ray tube experiment. Electrons can also participate in
nuclear reaction In nuclear physics and nuclear chemistry, a nuclear reaction is a process in which two nuclei, or a nucleus and an external subatomic particle, collide to produce one or more new nuclides. Thus, a nuclear reaction must cause a transformatio ...
s, such as nucleosynthesis in stars, where they are known as beta particles. Electrons can be created through
beta decay In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For ...
of
radioactive isotopes A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...
and in high-energy collisions, for instance when
cosmic ray Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own ...
s enter the atmosphere. The
antiparticle In particle physics, every type of particle is associated with an antiparticle with the same mass but with opposite physical charges (such as electric charge). For example, the antiparticle of the electron is the positron (also known as an antie ...
of the electron is called the positron; it is identical to the electron except that it carries electrical
charge Charge or charged may refer to: Arts, entertainment, and media Films * '' Charge, Zero Emissions/Maximum Speed'', a 2011 documentary Music * ''Charge'' (David Ford album) * ''Charge'' (Machel Montano album) * ''Charge!!'', an album by The Aqu ...
of the opposite sign. When an electron collides with a positron, both particles can be
annihilated The eighth season of the television series, '' Law & Order: Special Victims Unit'' premiered September 19, 2006 and ended May 22, 2007 on NBC. The series remained in its 10pm/9c Tuesday timeslot. With the introduction of a new partner for Detecti ...
, producing
gamma ray A gamma ray, also known as gamma radiation (symbol γ or \gamma), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically ...
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they a ...
s.


History


Discovery of effect of electric force

The
ancient Greeks Ancient Greece ( el, Ἑλλάς, Hellás) was a northeastern Mediterranean civilization, existing from the Greek Dark Ages of the 12th–9th centuries BC to the end of classical antiquity ( AD 600), that comprised a loose collection of cult ...
noticed that
amber Amber is fossilized tree resin that has been appreciated for its color and natural beauty since Neolithic times. Much valued from antiquity to the present as a gemstone, amber is made into a variety of decorative objects."Amber" (2004). In ...
attracted small objects when rubbed with fur. Along with
lightning Lightning is a naturally occurring electrostatic discharge during which two electrically charged regions, both in the atmosphere or with one on the ground, temporarily neutralize themselves, causing the instantaneous release of an avera ...
, this phenomenon is one of humanity's earliest recorded experiences with
electricity Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as describ ...
. In his 1600 treatise , the English scientist William Gilbert coined the
New Latin New Latin (also called Neo-Latin or Modern Latin) is the revival of Literary Latin used in original, scholarly, and scientific works since about 1500. Modern scholarly and technical nomenclature, such as in zoological and botanical taxonomy ...
term , to refer to those substances with property similar to that of amber which attract small objects after being rubbed. Both ''electric'' and ''electricity'' are derived from the Latin ' (also the root of the alloy of the same name), which came from the Greek word for amber, (').


Discovery of two kinds of charges

In the early 1700s, French chemist Charles François du Fay found that if a charged gold-leaf is repulsed by glass rubbed with silk, then the same charged gold-leaf is attracted by amber rubbed with wool. From this and other results of similar types of experiments, du Fay concluded that electricity consists of two electrical fluids, ''vitreous'' fluid from glass rubbed with silk and ''resinous'' fluid from amber rubbed with wool. These two fluids can neutralize each other when combined. American scientist Ebenezer Kinnersley later also independently reached the same conclusion. A decade later
Benjamin Franklin Benjamin Franklin ( April 17, 1790) was an American polymath who was active as a writer, scientist, inventor, statesman, diplomat, printer, publisher, and political philosopher. Encyclopædia Britannica, Wood, 2021 Among the leading inte ...
proposed that electricity was not from different types of electrical fluid, but a single electrical fluid showing an excess (+) or deficit (−). He gave them the modern
charge Charge or charged may refer to: Arts, entertainment, and media Films * '' Charge, Zero Emissions/Maximum Speed'', a 2011 documentary Music * ''Charge'' (David Ford album) * ''Charge'' (Machel Montano album) * ''Charge!!'', an album by The Aqu ...
nomenclature of positive and negative respectively. Franklin thought of the charge carrier as being positive, but he did not correctly identify which situation was a surplus of the charge carrier, and which situation was a deficit. Between 1838 and 1851, British natural philosopher
Richard Laming Richard Laming (c. 1798–3 May 1879) was a British surgeon, natural philosopher, inventor, chemist and industrialist. There is some uncertainty about his origins. It is believed that he was born in Margate, England on 17 August 1799, the son o ...
developed the idea that an atom is composed of a core of matter surrounded by subatomic particles that had unit
electric charge Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respe ...
s. Beginning in 1846, German physicist
Wilhelm Eduard Weber Wilhelm Eduard Weber (; ; 24 October 1804 – 23 June 1891) was a German physicist and, together with Carl Friedrich Gauss, inventor of the first electromagnetic telegraph. Biography of Wilhelm Early years Weber was born in Schlossstrasse i ...
theorized that electricity was composed of positively and negatively charged fluids, and their interaction was governed by the inverse square law. After studying the phenomenon of electrolysis in 1874, Irish physicist George Johnstone Stoney suggested that there existed a "single definite quantity of electricity", the charge of a monovalent
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
. He was able to estimate the value of this elementary charge ''e'' by means of
Faraday's laws of electrolysis Faraday's laws of electrolysis are quantitative relationships based on the electrochemical research published by Michael Faraday in 1833. First law Michael Faraday reported that the mass (m) of elements deposited at an electrode is directly pro ...
. However, Stoney believed these charges were permanently attached to atoms and could not be removed. In 1881, German physicist
Hermann von Helmholtz Hermann Ludwig Ferdinand von Helmholtz (31 August 1821 – 8 September 1894) was a German physicist and physician who made significant contributions in several scientific fields, particularly hydrodynamic stability. The Helmholtz Associatio ...
argued that both positive and negative charges were divided into elementary parts, each of which "behaves like atoms of electricity". Stoney initially coined the term ''electrolion'' in 1881. Ten years later, he switched to ''electron'' to describe these elementary charges, writing in 1894: "... an estimate was made of the actual amount of this most remarkable fundamental unit of electricity, for which I have since ventured to suggest the name ''electron''". A 1906 proposal to change to ''electrion'' failed because Hendrik Lorentz preferred to keep ''electron''. The word ''electron'' is a combination of the words ''electric'' and ''ion''. The suffix -''on'' which is now used to designate other subatomic particles, such as a proton or neutron, is in turn derived from electron.


Discovery of free electrons outside matter

While studying electrical conductivity in rarefied gases in 1859, the German physicist
Julius Plücker Julius Plücker (16 June 1801 – 22 May 1868) was a German mathematician and physicist. He made fundamental contributions to the field of analytical geometry and was a pioneer in the investigations of cathode rays that led eventually to the dis ...
observed the radiation emitted from the cathode caused phosphorescent light to appear on the tube wall near the cathode; and the region of the phosphorescent light could be moved by application of a magnetic field. In 1869, Plücker's student Johann Wilhelm Hittorf found that a solid body placed in between the cathode and the phosphorescence would cast a shadow upon the phosphorescent region of the tube. Hittorf inferred that there are straight rays emitted from the cathode and that the phosphorescence was caused by the rays striking the tube walls. In 1876, the German physicist Eugen Goldstein showed that the rays were emitted perpendicular to the cathode surface, which distinguished between the rays that were emitted from the cathode and the incandescent light. Goldstein dubbed the rays
cathode ray Cathode rays or electron beam (e-beam) are streams of electrons observed in discharge tubes. If an evacuated glass tube is equipped with two electrodes and a voltage is applied, glass behind the positive electrode is observed to glow, due to el ...
s. Decades of experimental and theoretical research involving cathode rays were important in
J. J. Thomson Sir Joseph John Thomson (18 December 1856 – 30 August 1940) was a British physicist and Nobel Laureate in Physics, credited with the discovery of the electron, the first subatomic particle to be discovered. In 1897, Thomson showed that ...
's eventual discovery of electrons. During the 1870s, the English chemist and physicist Sir
William Crookes Sir William Crookes (; 17 June 1832 – 4 April 1919) was a British chemist and physicist who attended the Royal College of Chemistry, now part of Imperial College London, and worked on spectroscopy. He was a pioneer of vacuum tubes, inventing t ...
developed the first cathode-ray tube to have a high vacuum inside. He then showed in 1874 that the cathode rays can turn a small paddle wheel when placed in their path. Therefore, he concluded that the rays carried momentum. Furthermore, by applying a magnetic field, he was able to deflect the rays, thereby demonstrating that the beam behaved as though it were negatively charged. In 1879, he proposed that these properties could be explained by regarding cathode rays as composed of negatively charged gaseous
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioche ...
s in a fourth state of matter in which the mean free path of the particles is so long that collisions may be ignored. The German-born British physicist
Arthur Schuster Sir Franz Arthur Friedrich Schuster (12 September 1851 – 14 October 1934) was a German-born British physicist known for his work in spectroscopy, electrochemistry, optics, X-radiography and the application of harmonic analysis to physics. ...
expanded upon Crookes's experiments by placing metal plates parallel to the cathode rays and applying an
electric potential The electric potential (also called the ''electric field potential'', potential drop, the electrostatic potential) is defined as the amount of work energy needed to move a unit of electric charge from a reference point to the specific point in ...
between the plates. The field deflected the rays toward the positively charged plate, providing further evidence that the rays carried negative charge. By measuring the amount of deflection for a given level of
current Currents, Current or The Current may refer to: Science and technology * Current (fluid), the flow of a liquid or a gas ** Air current, a flow of air ** Ocean current, a current in the ocean *** Rip current, a kind of water current ** Current (stre ...
, in 1890 Schuster was able to estimate the
charge-to-mass ratio The mass-to-charge ratio (''m''/''Q'') is a physical quantity relating the ''mass'' (quantity of matter) and the ''electric charge'' of a given particle, expressed in units of kilograms per coulomb (kg/C). It is most widely used in the electrod ...
of the ray components. However, this produced a value that was more than a thousand times greater than what was expected, so little credence was given to his calculations at the time. This is because it was assumed that the charge carriers were much heavier
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
or
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
atoms. Schuster's estimates would subsequently turn out to be largely correct. In 1892 Hendrik Lorentz suggested that the mass of these particles (electrons) could be a consequence of their electric charge. While studying naturally fluorescing minerals in 1896, the French physicist
Henri Becquerel Antoine Henri Becquerel (; 15 December 1852 – 25 August 1908) was a French engineer, physicist, Nobel laureate, and the first person to discover evidence of radioactivity. For work in this field he, along with Marie Skłodowska-Curie and Pie ...
discovered that they emitted radiation without any exposure to an external energy source. These
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
materials became the subject of much interest by scientists, including the New Zealand physicist
Ernest Rutherford Ernest Rutherford, 1st Baron Rutherford of Nelson, (30 August 1871 – 19 October 1937) was a New Zealand physicist who came to be known as the father of nuclear physics. ''Encyclopædia Britannica'' considers him to be the greatest ...
who discovered they emitted particles. He designated these particles alpha and beta, on the basis of their ability to penetrate matter. In 1900, Becquerel showed that the beta rays emitted by
radium Radium is a chemical element with the symbol Ra and atomic number 88. It is the sixth element in group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, but it readily reacts with nitrogen (rathe ...
could be deflected by an electric field, and that their mass-to-charge ratio was the same as for cathode rays. This evidence strengthened the view that electrons existed as components of atoms. Buchwald and Warwick (2001:90–91). In 1897, the British physicist
J. J. Thomson Sir Joseph John Thomson (18 December 1856 – 30 August 1940) was a British physicist and Nobel Laureate in Physics, credited with the discovery of the electron, the first subatomic particle to be discovered. In 1897, Thomson showed that ...
, with his colleagues John S. Townsend and H. A. Wilson, performed experiments indicating that cathode rays really were unique particles, rather than waves, atoms or molecules as was believed earlier. Thomson made good estimates of both the charge ''e'' and the mass ''m'', finding that cathode ray particles, which he called "corpuscles", had perhaps one thousandth of the mass of the least massive ion known: hydrogen. He showed that their charge-to-mass ratio, ''e''/''m'', was independent of cathode material. He further showed that the negatively charged particles produced by radioactive materials, by heated materials and by illuminated materials were universal. The name electron was adopted for these particles by the scientific community, mainly due to the advocation by G. F. FitzGerald, J. Larmor, and H. A. Lorentz. In the same year
Emil Wiechert Emil Johann Wiechert (26 December 1861 – 19 March 1928) was a German physicist and geophysicist who made many contributions to both fields, including presenting the first verifiable model of a layered structure of the Earth and being among the ...
and Walter Kaufmann also calculated the e/m ratio but they failed short of interpreting their results while J. J. Thomson would subsequently in 1899 give estimates for the electron charge and mass as well: e~ esu and m~ g The electron's charge was more carefully measured by the American physicists Robert Millikan and
Harvey Fletcher Harvey Fletcher (September 11, 1884 – July 23, 1981) was an American physicist. Known as the "father of stereophonic sound", he is credited with the invention of the 2-A audiometer and an early electronic hearing aid. He was an investigator i ...
in their
oil-drop experiment The oil drop experiment was performed by Robert A. Millikan and Harvey Fletcher in 1909 to measure the elementary electric charge (the charge of the electron). The experiment took place in the Ryerson Physical Laboratory at the University of Chi ...
of 1909, the results of which were published in 1911. This experiment used an electric field to prevent a charged droplet of oil from falling as a result of gravity. This device could measure the electric charge from as few as 1–150 ions with an error margin of less than 0.3%. Comparable experiments had been done earlier by Thomson's team, using clouds of charged water droplets generated by electrolysis, and in 1911 by Abram Ioffe, who independently obtained the same result as Millikan using charged microparticles of metals, then published his results in 1913. However, oil drops were more stable than water drops because of their slower evaporation rate, and thus more suited to precise experimentation over longer periods of time. Around the beginning of the twentieth century, it was found that under certain conditions a fast-moving charged particle caused a condensation of supersaturated water vapor along its path. In 1911, Charles Wilson used this principle to devise his
cloud chamber A cloud chamber, also known as a Wilson cloud chamber, is a particle detector used for visualizing the passage of ionizing radiation. A cloud chamber consists of a sealed environment containing a supersaturated vapour of water or alcohol. An ...
so he could photograph the tracks of charged particles, such as fast-moving electrons.


Atomic theory

By 1914, experiments by physicists
Ernest Rutherford Ernest Rutherford, 1st Baron Rutherford of Nelson, (30 August 1871 – 19 October 1937) was a New Zealand physicist who came to be known as the father of nuclear physics. ''Encyclopædia Britannica'' considers him to be the greatest ...
,
Henry Moseley Henry Gwyn Jeffreys Moseley (; 23 November 1887 – 10 August 1915) was an English physicist, whose contribution to the science of physics was the justification from physical laws of the previous empirical and chemical concept of the atomic num ...
,
James Franck James Franck (; 26 August 1882 – 21 May 1964) was a German physicist who won the 1925 Nobel Prize for Physics with Gustav Hertz "for their discovery of the laws governing the impact of an electron upon an atom". He completed his doctorate i ...
and
Gustav Hertz Gustav Ludwig Hertz (; 22 July 1887 – 30 October 1975) was a German experimental physicist and Nobel Prize winner for his work on inelastic electron collisions in gases, and a nephew of Heinrich Rudolf Hertz. Biography Hertz was born in Hamb ...
had largely established the structure of an atom as a dense nucleus of positive charge surrounded by lower-mass electrons. In 1913, Danish physicist
Niels Bohr Niels Henrik David Bohr (; 7 October 1885 – 18 November 1962) was a Danish physicist who made foundational contributions to understanding atomic structure and quantum theory, for which he received the Nobel Prize in Physics in 1922 ...
postulated that electrons resided in quantized energy states, with their energies determined by the angular momentum of the electron's orbit about the nucleus. The electrons could move between those states, or orbits, by the emission or absorption of photons of specific frequencies. By means of these quantized orbits, he accurately explained the
spectral line A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to iden ...
s of the hydrogen atom. However, Bohr's model failed to account for the relative intensities of the spectral lines and it was unsuccessful in explaining the spectra of more complex atoms. Chemical bonds between atoms were explained by
Gilbert Newton Lewis Gilbert Newton Lewis (October 23 or October 25, 1875 – March 23, 1946) was an American physical chemist and a Dean of the College of Chemistry at University of California, Berkeley. Lewis was best known for his discovery of the covalent bond a ...
, who in 1916 proposed that a covalent bond between two atoms is maintained by a pair of electrons shared between them. Later, in 1927, Walter Heitler and
Fritz London Fritz Wolfgang London (March 7, 1900 – March 30, 1954) was a German physicist and professor at Duke University. His fundamental contributions to the theories of chemical bonding and of intermolecular forces ( London dispersion forces) are today ...
gave the full explanation of the electron-pair formation and chemical bonding in terms of
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistr ...
. In 1919, the American chemist Irving Langmuir elaborated on the Lewis's static model of the atom and suggested that all electrons were distributed in successive "concentric (nearly) spherical shells, all of equal thickness". In turn, he divided the shells into a number of cells each of which contained one pair of electrons. With this model Langmuir was able to qualitatively explain the
chemical properties A chemical property is any of a material's properties that becomes evident during, or after, a chemical reaction; that is, any quality that can be established only by changing a substance's chemical identity.William L. Masterton, Cecile N. Hurley, ...
of all elements in the periodic table, which were known to largely repeat themselves according to the
periodic law Periodic trends are specific patterns that are present in the periodic table that illustrate different aspects of a certain element. They were discovered by the Russian chemist Dmitri Mendeleev in the year 1863. Major periodic trends include atom ...
. In 1924, Austrian physicist
Wolfgang Pauli Wolfgang Ernst Pauli (; ; 25 April 1900 – 15 December 1958) was an Austrian theoretical physicist and one of the pioneers of quantum physics. In 1945, after having been nominated by Albert Einstein, Pauli received the Nobel Prize in Physics ...
observed that the shell-like structure of the atom could be explained by a set of four parameters that defined every quantum energy state, as long as each state was occupied by no more than a single electron. This prohibition against more than one electron occupying the same quantum energy state became known as the
Pauli exclusion principle In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formulat ...
. The physical mechanism to explain the fourth parameter, which had two distinct possible values, was provided by the Dutch physicists
Samuel Goudsmit Samuel Abraham Goudsmit (July 11, 1902 – December 4, 1978) was a Dutch-American physicist famous for jointly proposing the concept of electron spin with George Eugene Uhlenbeck in 1925. Life and career Goudsmit was born in The Hague, Nethe ...
and
George Uhlenbeck George Eugene Uhlenbeck (December 6, 1900 – October 31, 1988) was a Dutch-American theoretical physicist. Background and education George Uhlenbeck was the son of Eugenius and Anne Beeger Uhlenbeck. He attended the Hogere Burgerschool (High S ...
. In 1925, they suggested that an electron, in addition to the angular momentum of its orbit, possesses an intrinsic angular momentum and magnetic dipole moment. This is analogous to the rotation of the Earth on its axis as it orbits the Sun. The intrinsic angular momentum became known as spin, and explained the previously mysterious splitting of spectral lines observed with a high-resolution spectrograph; this phenomenon is known as fine structure splitting.


Quantum mechanics

In his 1924 dissertation ' (Research on Quantum Theory), French physicist
Louis de Broglie Louis Victor Pierre Raymond, 7th Duc de Broglie (, also , or ; 15 August 1892 – 19 March 1987) was a French physicist and aristocrat who made groundbreaking contributions to Old quantum theory, quantum theory. In his 1924 PhD thesis, he pos ...
hypothesized that all matter can be represented as a de Broglie wave in the manner of
light Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 te ...
. That is, under the appropriate conditions, electrons and other matter would show properties of either particles or waves. The corpuscular properties of a particle are demonstrated when it is shown to have a localized position in space along its trajectory at any given moment. The wave-like nature of light is displayed, for example, when a beam of light is passed through parallel slits thereby creating
interference Interference is the act of interfering, invading, or poaching. Interference may also refer to: Communications * Interference (communication), anything which alters, modifies, or disrupts a message * Adjacent-channel interference, caused by extr ...
patterns. In 1927, George Paget Thomson discovered the interference effect was produced when a beam of electrons was passed through thin metal foils and by American physicists
Clinton Davisson Clinton Joseph Davisson (October 22, 1881 – February 1, 1958) was an American physicist who won the 1937 Nobel Prize in Physics for his discovery of electron diffraction in the famous Davisson–Germer experiment. Davisson shared the Nobel Priz ...
and Lester Germer by the reflection of electrons from a crystal of
nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow ...
. De Broglie's prediction of a wave nature for electrons led
Erwin Schrödinger Erwin Rudolf Josef Alexander Schrödinger (, ; ; 12 August 1887 – 4 January 1961), sometimes written as or , was a Nobel Prize-winning Austrian physicist with Irish citizenship who developed a number of fundamental results in quantum theo ...
to postulate a wave equation for electrons moving under the influence of the nucleus in the atom. In 1926, this equation, the
Schrödinger equation The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of th ...
, successfully described how electron waves propagated. Rather than yielding a solution that determined the location of an electron over time, this wave equation also could be used to predict the probability of finding an electron near a position, especially a position near where the electron was bound in space, for which the electron wave equations did not change in time. This approach led to a second formulation of
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistr ...
(the first by Heisenberg in 1925), and solutions of Schrödinger's equation, like Heisenberg's, provided derivations of the energy states of an electron in a hydrogen atom that were equivalent to those that had been derived first by Bohr in 1913, and that were known to reproduce the hydrogen spectrum. Once spin and the interaction between multiple electrons were describable, quantum mechanics made it possible to predict the configuration of electrons in atoms with atomic numbers greater than hydrogen. In 1928, building on Wolfgang Pauli's work,
Paul Dirac Paul Adrien Maurice Dirac (; 8 August 1902 – 20 October 1984) was an English theoretical physicist who is regarded as one of the most significant physicists of the 20th century. He was the Lucasian Professor of Mathematics at the Univer ...
produced a model of the electron – the
Dirac equation In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it describes all spin- massive particles, called "Dirac par ...
, consistent with relativity theory, by applying relativistic and symmetry considerations to the
hamiltonian Hamiltonian may refer to: * Hamiltonian mechanics, a function that represents the total energy of a system * Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system ** Dyall Hamiltonian, a modified Hamiltonian ...
formulation of the quantum mechanics of the electro-magnetic field. In order to resolve some problems within his relativistic equation, Dirac developed in 1930 a model of the vacuum as an infinite sea of particles with negative energy, later dubbed the
Dirac sea The Dirac sea is a theoretical model of the vacuum as an infinite sea of particles with negative energy. It was first postulated by the British physicist Paul Dirac in 1930 to explain the anomalous negative-energy quantum states predicted by th ...
. This led him to predict the existence of a positron, the
antimatter In modern physics, antimatter is defined as matter composed of the antiparticles (or "partners") of the corresponding particles in "ordinary" matter. Antimatter occurs in natural processes like cosmic ray collisions and some types of radioac ...
counterpart of the electron. This particle was discovered in 1932 by Carl Anderson, who proposed calling standard electrons ''negatrons'' and using ''electron'' as a generic term to describe both the positively and negatively charged variants. In 1947,
Willis Lamb Willis Eugene Lamb Jr. (; July 12, 1913 – May 15, 2008) was an American physicist who won the Nobel Prize in Physics in 1955 "for his discoveries concerning the fine structure of the hydrogen spectrum." The Nobel Committee that year awarded hal ...
, working in collaboration with graduate student Robert Retherford, found that certain quantum states of the hydrogen atom, which should have the same energy, were shifted in relation to each other; the difference came to be called the
Lamb shift In physics, the Lamb shift, named after Willis Lamb, is a difference in energy between two energy levels 2''S''1/2 and 2''P''1/2 (in term symbol notation) of the hydrogen atom which was not predicted by the Dirac equation, according to which th ...
. About the same time,
Polykarp Kusch Polykarp Kusch (January 26, 1911 – March 20, 1993) was a German-born American physicist. In 1955, the Nobel Committee gave a divided Nobel Prize for Physics, with one half going to Kusch for his accurate determination that the magnetic momen ...
, working with Henry M. Foley, discovered the magnetic moment of the electron is slightly larger than predicted by Dirac's theory. This small difference was later called
anomalous magnetic dipole moment In quantum electrodynamics, the anomalous magnetic moment of a particle is a contribution of effects of quantum mechanics, expressed by Feynman diagrams with loops, to the magnetic moment of that particle. (The ''magnetic moment'', also called '' ...
of the electron. This difference was later explained by the theory of
quantum electrodynamics In particle physics, quantum electrodynamics (QED) is the relativistic quantum field theory of electrodynamics. In essence, it describes how light and matter interact and is the first theory where full agreement between quantum mechanics and spec ...
, developed by Sin-Itiro Tomonaga,
Julian Schwinger Julian Seymour Schwinger (; February 12, 1918 – July 16, 1994) was a Nobel Prize winning American theoretical physicist. He is best known for his work on quantum electrodynamics (QED), in particular for developing a relativistically invariant ...
and
Richard Feynman Richard Phillips Feynman (; May 11, 1918 – February 15, 1988) was an American theoretical physicist, known for his work in the path integral formulation of quantum mechanics, the theory of quantum electrodynamics, the physics of the superfl ...
in the late 1940s.


Particle accelerators

With the development of the
particle accelerator A particle accelerator is a machine that uses electromagnetic fields to propel charged particles to very high speeds and energies, and to contain them in well-defined beams. Large accelerators are used for fundamental research in particle ...
during the first half of the twentieth century, physicists began to delve deeper into the properties of subatomic particles. The first successful attempt to accelerate electrons using electromagnetic induction was made in 1942 by
Donald Kerst Donald William Kerst (November 1, 1911 – August 19, 1993) was an American physicist who worked on advanced particle accelerator concepts (accelerator physics) and plasma physics. He is most notable for his development of the betatron, a novel ...
. His initial
betatron A betatron is a type of cyclic particle accelerator. It is essentially a transformer with a torus-shaped vacuum tube as its secondary coil. An alternating current in the primary coils accelerates electrons in the vacuum around a circular path. Th ...
reached energies of 2.3 MeV, while subsequent betatrons achieved 300 MeV. In 1947, synchrotron radiation was discovered with a 70 MeV electron synchrotron at
General Electric General Electric Company (GE) is an American multinational conglomerate founded in 1892, and incorporated in New York state and headquartered in Boston. The company operated in sectors including healthcare, aviation, power, renewable en ...
. This radiation was caused by the acceleration of electrons through a magnetic field as they moved near the speed of light. With a beam energy of 1.5 GeV, the first high-energy particle
collider A collider is a type of particle accelerator which brings two opposing particle beams together such that the particles collide. Colliders may either be ring accelerators or linear accelerators. Colliders are used as a research tool in particl ...
was
ADONE ADONE (''big AdA'') was a high-energy (beam energy 1.5  GeV, center-of-mass energy 3 GeV) particle collider. It collided electrons with their antiparticles, positrons. It was 105 meters in circumference. It was operated from 1969 to 1993, by ...
, which began operations in 1968. This device accelerated electrons and positrons in opposite directions, effectively doubling the energy of their collision when compared to striking a static target with an electron. The
Large Electron–Positron Collider The Large Electron–Positron Collider (LEP) was one of the largest particle accelerators ever constructed. It was built at CERN, a multi-national centre for research in nuclear and particle physics near Geneva, Switzerland. LEP collided elect ...
(LEP) at CERN, which was operational from 1989 to 2000, achieved collision energies of 209 GeV and made important measurements for the Standard Model of particle physics.


Confinement of individual electrons

Individual electrons can now be easily confined in ultra small (, ) CMOS transistors operated at cryogenic temperature over a range of −269 °C (4  K) to about −258 °C (15  K). The electron wavefunction spreads in a semiconductor lattice and negligibly interacts with the valence band electrons, so it can be treated in the single particle formalism, by replacing its mass with the effective mass tensor.


Characteristics


Classification

In the Standard Model of particle physics, electrons belong to the group of subatomic particles called leptons, which are believed to be fundamental or
elementary particle In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions ( quarks, leptons, a ...
s. Electrons have the lowest mass of any charged lepton (or electrically charged particle of any type) and belong to the first-
generation A generation refers to all of the people born and living at about the same time, regarded collectively. It can also be described as, "the average period, generally considered to be about 20–⁠30 years, during which children are born and gr ...
of fundamental particles. The second and third generation contain charged leptons, the muon and the
tau Tau (uppercase Τ, lowercase τ, or \boldsymbol\tau; el, ταυ ) is the 19th letter of the Greek alphabet, representing the voiceless dental or alveolar plosive . In the system of Greek numerals, it has a value of 300. The name in English ...
, which are identical to the electron in charge, spin and
interactions Interaction is action that occurs between two or more objects, with broad use in philosophy and the sciences. It may refer to: Science * Interaction hypothesis, a theory of second language acquisition * Interaction (statistics) * Interactions o ...
, but are more massive. Leptons differ from the other basic constituent of matter, the quarks, by their lack of strong interaction. All members of the lepton group are fermions, because they all have half-odd integer spin; the electron has spin .


Fundamental properties

The invariant mass of an electron is approximately  kilograms, or  
atomic mass unit The dalton or unified atomic mass unit (symbols: Da or u) is a non-SI unit of mass widely used in physics and chemistry. It is defined as of the mass of an unbound neutral atom of carbon-12 in its nuclear and electronic ground state and at ...
s. Due to
mass–energy equivalence In physics, mass–energy equivalence is the relationship between mass and energy in a system's rest frame, where the two quantities differ only by a multiplicative constant and the units of measurement. The principle is described by the physici ...
, this corresponds to a rest energy of 0.511 MeV. The ratio between the mass of a proton and that of an electron is about 1836. Astronomical measurements show that the proton-to-electron mass ratio has held the same value, as is predicted by the Standard Model, for at least half the
age of the universe In physical cosmology, the age of the universe is the time elapsed since the Big Bang. Astronomers have derived two different measurements of the age of the universe: a measurement based on direct observations of an early state of the universe, ...
. Electrons have an
electric charge Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respe ...
of coulombs,The original source for CODATA is :Individual physical constants from the CODATA are available at: which is used as a standard unit of charge for subatomic particles, and is also called the elementary charge. Within the limits of experimental accuracy, the electron charge is identical to the charge of a proton, but with the opposite sign. As the symbol ''e'' is used for the elementary charge, the electron is commonly symbolized by , where the minus sign indicates the negative charge. The positron is symbolized by because it has the same properties as the electron but with a positive rather than negative charge. The electron has an intrinsic
angular momentum In physics, angular momentum (rarely, moment of momentum or rotational momentum) is the rotational analog of linear momentum. It is an important physical quantity because it is a conserved quantity—the total angular momentum of a closed syst ...
or spin of . This property is usually stated by referring to the electron as a spin- particle. For such particles the spin magnitude is ,This magnitude is obtained from the spin quantum number as :\begin S & = \sqrt \cdot \frac \\ & = \frac \hbar \\ \end for quantum number ''s'' = .
See: Gupta (2001).
while the result of the measurement of a projection of the spin on any axis can only be ±. In addition to spin, the electron has an intrinsic
magnetic moment In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electromagne ...
along its spin axis. It is approximately equal to one
Bohr magneton In atomic physics, the Bohr magneton (symbol ) is a physical constant and the natural unit for expressing the magnetic moment of an electron caused by its orbital or spin angular momentum. The Bohr magneton, in SI units is defined as \mu_\mat ...
, which is a physical constant equal to . The orientation of the spin with respect to the momentum of the electron defines the property of elementary particles known as helicity. The electron has no known substructure. Nevertheless, in condensed matter physics, spin–charge separation can occur in some materials. In such cases, electrons 'split' into three independent particles, the
spinon Spinons are one of three quasiparticles, along with holons and orbitons, that electrons in solids are able to split into during the process of spin–charge separation, when extremely tightly confined at temperatures close to absolute zero. The e ...
, the
orbiton Orbitons are one of three quasiparticles, along with holons and spinons, that electrons in solids are able to split into during the process of spin–charge separation, when extremely tightly confined at temperatures close to absolute zero. The e ...
and the holon (or chargon). The electron can always be theoretically considered as a bound state of the three, with the spinon carrying the spin of the electron, the orbiton carrying the orbital degree of freedom and the chargon carrying the charge, but in certain conditions they can behave as independent
quasiparticles In physics, quasiparticles and collective excitations are closely related emergent phenomena arising when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum. For exa ...
. The issue of the radius of the electron is a challenging problem of modern theoretical physics. The admission of the hypothesis of a finite radius of the electron is incompatible to the premises of the theory of relativity. On the other hand, a point-like electron (zero radius) generates serious mathematical difficulties due to the self-energy of the electron tending to infinity. Observation of a single electron in a Penning trap suggests the upper limit of the particle's radius to be 10−22 meters. The upper bound of the electron radius of 10−18 meters can be derived using the
uncertainty relation In quantum mechanics, the uncertainty principle (also known as Heisenberg's uncertainty principle) is any of a variety of mathematical inequalities asserting a fundamental limit to the accuracy with which the values for certain pairs of physic ...
in energy. There ''is'' also a physical constant called the "
classical electron radius The classical electron radius is a combination of fundamental physical quantities that define a length scale for problems involving an electron interacting with electromagnetic radiation. It links the classical electrostatic self-interaction energ ...
", with the much larger value of , greater than the radius of the proton. However, the terminology comes from a simplistic calculation that ignores the effects of
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistr ...
; in reality, the so-called classical electron radius has little to do with the true fundamental structure of the electron.The classical electron radius is derived as follows. Assume that the electron's charge is spread uniformly throughout a spherical volume. Since one part of the sphere would repel the other parts, the sphere contains electrostatic potential energy. This energy is assumed to equal the electron's
rest energy The invariant mass, rest mass, intrinsic mass, proper mass, or in the case of bound systems simply mass, is the portion of the total mass of an object or system of objects that is independent of the overall motion of the system. More precisely, ...
, defined by
special relativity In physics, the special theory of relativity, or special relativity for short, is a scientific theory regarding the relationship between space and time. In Albert Einstein's original treatment, the theory is based on two postulates: # The laws ...
(''E'' = ''mc''2).
From electrostatics theory, the potential energy of a sphere with radius ''r'' and charge ''e'' is given by: :E_ = \frac, where ''ε''0 is the vacuum permittivity. For an electron with rest mass ''m''0, the rest energy is equal to: :\textstyle E_ = m_0 c^2, where ''c'' is the speed of light in a vacuum. Setting them equal and solving for ''r'' gives the classical electron radius.
See: Haken, Wolf, & Brewer (2005).
There are
elementary particle In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions ( quarks, leptons, a ...
s that spontaneously decay into less massive particles. An example is the muon, with a
mean lifetime A quantity is subject to exponential decay if it decreases at a rate proportional to its current value. Symbolically, this process can be expressed by the following differential equation, where is the quantity and ( lambda) is a positive rate ...
of  seconds, which decays into an electron, a muon
neutrino A neutrino ( ; denoted by the Greek letter ) is a fermion (an elementary particle with spin of ) that interacts only via the weak interaction and gravity. The neutrino is so named because it is electrically neutral and because its rest mass ...
and an electron
antineutrino A neutrino ( ; denoted by the Greek letter ) is a fermion (an elementary particle with spin of ) that interacts only via the weak interaction and gravity. The neutrino is so named because it is electrically neutral and because its rest mass is ...
. The electron, on the other hand, is thought to be stable on theoretical grounds: the electron is the least massive particle with non-zero electric charge, so its decay would violate
charge conservation In physics, charge conservation is the principle that the total electric charge in an isolated system never changes. The net quantity of electric charge, the amount of positive charge minus the amount of negative charge in the universe, is alwa ...
. The experimental lower bound for the electron's mean lifetime is years, at a 90% confidence level.


Quantum properties

As with all particles, electrons can act as waves. This is called the
wave–particle duality Wave–particle duality is the concept in quantum mechanics that every particle or quantum entity may be described as either a particle or a wave. It expresses the inability of the classical concepts "particle" or "wave" to fully describe the b ...
and can be demonstrated using the double-slit experiment. The wave-like nature of the electron allows it to pass through two parallel slits simultaneously, rather than just one slit as would be the case for a classical particle. In quantum mechanics, the wave-like property of one particle can be described mathematically as a
complex Complex commonly refers to: * Complexity, the behaviour of a system whose components interact in multiple ways so possible interactions are difficult to describe ** Complex system, a system composed of many components which may interact with each ...
-valued function, the
wave function A wave function in quantum physics is a mathematical description of the quantum state of an isolated quantum system. The wave function is a complex-valued probability amplitude, and the probabilities for the possible results of measurements ...
, commonly denoted by the Greek letter psi (''ψ''). When the absolute value of this function is squared, it gives the probability that a particle will be observed near a location—a
probability density In probability theory, a probability density function (PDF), or density of a continuous random variable, is a function whose value at any given sample (or point) in the sample space (the set of possible values taken by the random variable) can ...
. Electrons are
identical particles In quantum mechanics, identical particles (also called indistinguishable or indiscernible particles) are particles that cannot be distinguished from one another, even in principle. Species of identical particles include, but are not limited to, ...
because they cannot be distinguished from each other by their intrinsic physical properties. In quantum mechanics, this means that a pair of interacting electrons must be able to swap positions without an observable change to the state of the system. The wave function of fermions, including electrons, is antisymmetric, meaning that it changes sign when two electrons are swapped; that is, , where the variables ''r''1 and ''r''2 correspond to the first and second electrons, respectively. Since the absolute value is not changed by a sign swap, this corresponds to equal probabilities.
Boson In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer spi ...
s, such as the photon, have symmetric wave functions instead. In the case of antisymmetry, solutions of the wave equation for interacting electrons result in a zero probability that each pair will occupy the same location or state. This is responsible for the
Pauli exclusion principle In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formulat ...
, which precludes any two electrons from occupying the same quantum state. This principle explains many of the properties of electrons. For example, it causes groups of bound electrons to occupy different orbitals in an atom, rather than all overlapping each other in the same orbit.


Virtual particles

In a simplified picture, which often tends to give the wrong idea but may serve to illustrate some aspects, every photon spends some time as a combination of a virtual electron plus its antiparticle, the virtual positron, which rapidly annihilate each other shortly thereafter. The combination of the energy variation needed to create these particles, and the time during which they exist, fall under the threshold of detectability expressed by the
Heisenberg uncertainty relation In quantum mechanics, the uncertainty principle (also known as Heisenberg's uncertainty principle) is any of a variety of mathematical inequalities asserting a fundamental limit to the accuracy with which the values for certain pairs of physi ...
, Δ''E'' · Δ''t'' ≥ ''ħ''. In effect, the energy needed to create these virtual particles, Δ''E'', can be "borrowed" from the
vacuum A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or " void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often di ...
for a period of time, Δ''t'', so that their product is no more than the
reduced Planck constant The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivalen ...
, . Thus, for a virtual electron, Δ''t'' is at most . While an electron–positron virtual pair is in existence, the Coulomb force from the ambient electric field surrounding an electron causes a created positron to be attracted to the original electron, while a created electron experiences a repulsion. This causes what is called
vacuum polarization In quantum field theory, and specifically quantum electrodynamics, vacuum polarization describes a process in which a background electromagnetic field produces virtual electron–positron pairs that change the distribution of charges and curr ...
. In effect, the vacuum behaves like a medium having a dielectric permittivity more than
unity Unity may refer to: Buildings * Unity Building, Oregon, Illinois, US; a historic building * Unity Building (Chicago), Illinois, US; a skyscraper * Unity Buildings, Liverpool, UK; two buildings in England * Unity Chapel, Wyoming, Wisconsin, US; ...
. Thus the effective charge of an electron is actually smaller than its true value, and the charge decreases with increasing distance from the electron. This polarization was confirmed experimentally in 1997 using the Japanese
TRISTAN Tristan (Latin/ Brythonic: ''Drustanus''; cy, Trystan), also known as Tristram or Tristain and similar names, is the hero of the legend of Tristan and Iseult. In the legend, he is tasked with escorting the Irish princess Iseult to we ...
particle accelerator. Virtual particles cause a comparable
shielding effect In chemistry, the shielding effect sometimes referred to as atomic shielding or electron shielding describes the attraction between an electron and the nucleus in any atom with more than one electron. The shielding effect can be defined as a re ...
for the mass of the electron. The interaction with virtual particles also explains the small (about 0.1%) deviation of the intrinsic magnetic moment of the electron from the Bohr magneton (the
anomalous magnetic moment In quantum electrodynamics, the anomalous magnetic moment of a particle is a contribution of effects of quantum mechanics, expressed by Feynman diagrams with loops, to the magnetic moment of that particle. (The ''magnetic moment'', also called '' ...
). The extraordinarily precise agreement of this predicted difference with the experimentally determined value is viewed as one of the great achievements of
quantum electrodynamics In particle physics, quantum electrodynamics (QED) is the relativistic quantum field theory of electrodynamics. In essence, it describes how light and matter interact and is the first theory where full agreement between quantum mechanics and spec ...
. The apparent paradox in classical physics of a point particle electron having intrinsic angular momentum and magnetic moment can be explained by the formation of virtual photons in the electric field generated by the electron. These photons can heuristically be thought of as causing the electron to shift about in a jittery fashion (known as zitterbewegung), which results in a net circular motion with
precession Precession is a change in the orientation of the rotational axis of a rotating body. In an appropriate reference frame it can be defined as a change in the first Euler angle, whereas the third Euler angle defines the rotation itself. In oth ...
. This motion produces both the spin and the magnetic moment of the electron. In atoms, this creation of virtual photons explains the
Lamb shift In physics, the Lamb shift, named after Willis Lamb, is a difference in energy between two energy levels 2''S''1/2 and 2''P''1/2 (in term symbol notation) of the hydrogen atom which was not predicted by the Dirac equation, according to which th ...
observed in
spectral line A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to iden ...
s. The Compton Wavelength shows that near elementary particles such as the electron, the uncertainty of the energy allows for the creation of virtual particles near the electron. This wavelength explains the "static" of virtual particles around elementary particles at a close distance.


Interaction

An electron generates an electric field that exerts an attractive force on a particle with a positive charge, such as the proton, and a repulsive force on a particle with a negative charge. The strength of this force in nonrelativistic approximation is determined by Coulomb's inverse square law. When an electron is in motion, it generates a magnetic field. The Ampère–Maxwell law relates the magnetic field to the mass motion of electrons (the
current Currents, Current or The Current may refer to: Science and technology * Current (fluid), the flow of a liquid or a gas ** Air current, a flow of air ** Ocean current, a current in the ocean *** Rip current, a kind of water current ** Current (stre ...
) with respect to an observer. This property of induction supplies the magnetic field that drives an
electric motor An electric motor is an electrical machine that converts electrical energy into mechanical energy. Most electric motors operate through the interaction between the motor's magnetic field and electric current in a wire winding to generate for ...
. The electromagnetic field of an arbitrary moving charged particle is expressed by the Liénard–Wiechert potentials, which are valid even when the particle's speed is close to that of light ( relativistic). When an electron is moving through a magnetic field, it is subject to the Lorentz force that acts perpendicularly to the plane defined by the magnetic field and the electron velocity. This centripetal force causes the electron to follow a
helical Helical may refer to: * Helix, the mathematical concept for the shape * Helical engine, a proposed spacecraft propulsion drive * Helical spring, a coilspring * Helical plc, a British property company, once a maker of steel bar stock * Helicoil A t ...
trajectory through the field at a radius called the
gyroradius The gyroradius (also known as radius of gyration, Larmor radius or cyclotron radius) is the radius of the circular motion of a charged particle in the presence of a uniform magnetic field. In SI units, the non-relativistic gyroradius is given by :r_ ...
. The acceleration from this curving motion induces the electron to radiate energy in the form of synchrotron radiation. The energy emission in turn causes a recoil of the electron, known as the Abraham–Lorentz–Dirac Force, which creates a friction that slows the electron. This force is caused by a back-reaction of the electron's own field upon itself. Photons mediate electromagnetic interactions between particles in
quantum electrodynamics In particle physics, quantum electrodynamics (QED) is the relativistic quantum field theory of electrodynamics. In essence, it describes how light and matter interact and is the first theory where full agreement between quantum mechanics and spec ...
. An isolated electron at a constant velocity cannot emit or absorb a real photon; doing so would violate conservation of energy and momentum. Instead, virtual photons can transfer momentum between two charged particles. This exchange of virtual photons, for example, generates the Coulomb force. Energy emission can occur when a moving electron is deflected by a charged particle, such as a proton. The acceleration of the electron results in the emission of
Bremsstrahlung ''Bremsstrahlung'' (), from "to brake" and "radiation"; i.e., "braking radiation" or "deceleration radiation", is electromagnetic radiation produced by the deceleration of a charged particle when deflected by another charged particle, typicall ...
radiation. An inelastic collision between a photon (light) and a solitary (free) electron is called
Compton scattering Compton scattering, discovered by Arthur Holly Compton, is the scattering of a high frequency photon after an interaction with a charged particle, usually an electron. If it results in a decrease in energy (increase in wavelength) of the photon ...
. This collision results in a transfer of momentum and energy between the particles, which modifies the wavelength of the photon by an amount called the Compton shift. The maximum magnitude of this wavelength shift is ''h''/''m''e''c'', which is known as the
Compton wavelength The Compton wavelength is a quantum mechanical property of a particle. The Compton wavelength of a particle is equal to the wavelength of a photon whose energy is the same as the rest energy of that particle (see mass–energy equivalence). It was ...
. For an electron, it has a value of . When the wavelength of the light is long (for instance, the wavelength of the
visible light Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 te ...
is 0.4–0.7 μm) the wavelength shift becomes negligible. Such interaction between the light and free electrons is called
Thomson scattering Thomson scattering is the elastic scattering of electromagnetic radiation by a free charged particle, as described by classical electromagnetism. It is the low-energy limit of Compton scattering: the particle's kinetic energy and photon frequen ...
or linear Thomson scattering. The relative strength of the electromagnetic interaction between two charged particles, such as an electron and a proton, is given by the
fine-structure constant In physics, the fine-structure constant, also known as the Sommerfeld constant, commonly denoted by (the Greek letter ''alpha''), is a fundamental physical constant which quantifies the strength of the electromagnetic interaction between el ...
. This value is a dimensionless quantity formed by the ratio of two energies: the electrostatic energy of attraction (or repulsion) at a separation of one Compton wavelength, and the rest energy of the charge. It is given by ''α'' ≈ , which is approximately equal to . When electrons and positrons collide, they annihilate each other, giving rise to two or more gamma ray photons. If the electron and positron have negligible momentum, a positronium atom can form before annihilation results in two or three gamma ray photons totalling 1.022 MeV. On the other hand, a high-energy photon can transform into an electron and a positron by a process called
pair production Pair production is the creation of a subatomic particle and its antiparticle from a neutral boson. Examples include creating an electron and a positron, a muon and an antimuon, or a proton and an antiproton. Pair production often refers specifi ...
, but only in the presence of a nearby charged particle, such as a nucleus. In the theory of
electroweak interaction In particle physics, the electroweak interaction or electroweak force is the unified description of two of the four known fundamental interactions of nature: electromagnetism and the weak interaction. Although these two forces appear very differe ...
, the
left-handed In human biology, handedness is an individual's preferential use of one hand, known as the dominant hand, due to it being stronger, faster or more dextrous. The other hand, comparatively often the weaker, less dextrous or simply less subject ...
component of electron's wavefunction forms a
weak isospin In particle physics, weak isospin is a quantum number relating to the weak interaction, and parallels the idea of isospin under the strong interaction. Weak isospin is usually given the symbol or , with the third component written as or . It c ...
doublet with the
electron neutrino The electron neutrino () is an elementary particle which has zero electric charge and a spin of . Together with the electron, it forms the first generation of leptons, hence the name electron neutrino. It was first hypothesized by Wolfgang Pauli ...
. This means that during
weak interaction In nuclear physics and particle physics, the weak interaction, which is also often called the weak force or weak nuclear force, is one of the four known fundamental interactions, with the others being electromagnetism, the strong interaction ...
s, electron neutrinos behave like electrons. Either member of this doublet can undergo a charged current interaction by emitting or absorbing a and be converted into the other member. Charge is conserved during this reaction because the W boson also carries a charge, canceling out any net change during the transmutation. Charged current interactions are responsible for the phenomenon of
beta decay In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For ...
in a
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
atom. Both the electron and electron neutrino can undergo a
neutral current Weak neutral current interactions are one of the ways in which subatomic particles can interact by means of the weak force. These interactions are mediated by the Z boson. The discovery of weak neutral currents was a significant step towa ...
interaction via a exchange, and this is responsible for neutrino-electron
elastic scattering Elastic scattering is a form of particle scattering in scattering theory, nuclear physics and particle physics. In this process, the kinetic energy of a particle is conserved in the center-of-mass frame, but its direction of propagation is modif ...
.


Atoms and molecules

An electron can be ''bound'' to the nucleus of an atom by the attractive Coulomb force. A system of one or more electrons bound to a nucleus is called an atom. If the number of electrons is different from the nucleus's electrical charge, such an atom is called an
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
. The wave-like behavior of a bound electron is described by a function called an
atomic orbital In atomic theory and quantum mechanics, an atomic orbital is a function describing the location and wave-like behavior of an electron in an atom. This function can be used to calculate the probability of finding any electron of an atom in an ...
. Each orbital has its own set of quantum numbers such as energy, angular momentum and projection of angular momentum, and only a discrete set of these orbitals exist around the nucleus. According to the Pauli exclusion principle each orbital can be occupied by up to two electrons, which must differ in their spin quantum number. Electrons can transfer between different orbitals by the emission or absorption of photons with an energy that matches the difference in potential. Other methods of orbital transfer include collisions with particles, such as electrons, and the
Auger effect The Auger effect or Auger−Meitner effect is a physical phenomenon in which the filling of an inner-shell vacancy of an atom is accompanied by the emission of an electron from the same atom. When a core electron is removed, leaving a vacancy, ...
. To escape the atom, the energy of the electron must be increased above its
binding energy In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a system of particles into individual parts. In the former meaning the term is predominantly use ...
to the atom. This occurs, for example, with the
photoelectric effect The photoelectric effect is the emission of electrons when electromagnetic radiation, such as light, hits a material. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physics, and solid sta ...
, where an incident photon exceeding the atom's ionization energy is absorbed by the electron. The orbital angular momentum of electrons is quantized. Because the electron is charged, it produces an orbital magnetic moment that is proportional to the angular momentum. The net magnetic moment of an atom is equal to the vector sum of orbital and spin magnetic moments of all electrons and the nucleus. The magnetic moment of the nucleus is negligible compared with that of the electrons. The magnetic moments of the electrons that occupy the same orbital (so called, paired electrons) cancel each other out. The
chemical bond A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules and crystals. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of ...
between atoms occurs as a result of electromagnetic interactions, as described by the laws of quantum mechanics. The strongest bonds are formed by the
sharing Sharing is the joint use of a resource or space. It is also the process of dividing and distributing. In its narrow sense, it refers to joint or alternating use of inherently finite goods, such as a common pasture or a shared residence. Still ...
or
transfer Transfer may refer to: Arts and media * ''Transfer'' (2010 film), a German science-fiction movie directed by Damir Lukacevic and starring Zana Marjanović * ''Transfer'' (1966 film), a short film * ''Transfer'' (journal), in management studies ...
of electrons between atoms, allowing the formation of
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioche ...
s. Within a molecule, electrons move under the influence of several nuclei, and occupy
molecular orbital In chemistry, a molecular orbital is a mathematical function describing the location and wave-like behavior of an electron in a molecule. This function can be used to calculate chemical and physical properties such as the probability of findin ...
s; much as they can occupy atomic orbitals in isolated atoms. A fundamental factor in these molecular structures is the existence of electron pairs. These are electrons with opposed spins, allowing them to occupy the same molecular orbital without violating the Pauli exclusion principle (much like in atoms). Different molecular orbitals have different spatial distribution of the electron density. For instance, in bonded pairs (i.e. in the pairs that actually bind atoms together) electrons can be found with the maximal probability in a relatively small volume between the nuclei. By contrast, in non-bonded pairs electrons are distributed in a large volume around nuclei.


Conductivity

If a body has more or fewer electrons than are required to balance the positive charge of the nuclei, then that object has a net electric charge. When there is an excess of electrons, the object is said to be negatively charged. When there are fewer electrons than the number of protons in nuclei, the object is said to be positively charged. When the number of electrons and the number of protons are equal, their charges cancel each other and the object is said to be electrically neutral. A macroscopic body can develop an electric charge through rubbing, by the triboelectric effect. Independent electrons moving in vacuum are termed ''free'' electrons. Electrons in metals also behave as if they were free. In reality the particles that are commonly termed electrons in metals and other solids are quasi-electrons—
quasiparticle In physics, quasiparticles and collective excitations are closely related emergent phenomena arising when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum. For exa ...
s, which have the same electrical charge, spin, and magnetic moment as real electrons but might have a different mass. When free electrons—both in vacuum and metals—move, they produce a net flow of charge called an electric current, which generates a magnetic field. Likewise a current can be created by a changing magnetic field. These interactions are described mathematically by
Maxwell's equations Maxwell's equations, or Maxwell–Heaviside equations, are a set of coupled partial differential equations that, together with the Lorentz force law, form the foundation of classical electromagnetism, classical optics, and electric circuits. ...
. At a given temperature, each material has an electrical conductivity that determines the value of electric current when an
electric potential The electric potential (also called the ''electric field potential'', potential drop, the electrostatic potential) is defined as the amount of work energy needed to move a unit of electric charge from a reference point to the specific point in ...
is applied. Examples of good conductors include metals such as copper and gold, whereas glass and
Teflon Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chemo ...
are poor conductors. In any
dielectric In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the mate ...
material, the electrons remain bound to their respective atoms and the material behaves as an insulator. Most
semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. ...
s have a variable level of conductivity that lies between the extremes of conduction and insulation. On the other hand,
metals A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typical ...
have an
electronic band structure In solid-state physics, the electronic band structure (or simply band structure) of a solid describes the range of energy levels that electrons may have within it, as well as the ranges of energy that they may not have (called ''band gaps'' or ' ...
containing partially filled electronic bands. The presence of such bands allows electrons in metals to behave as if they were free or
delocalized electron In chemistry, delocalized electrons are electrons in a molecule, ion or solid metal that are not associated with a single atom or a covalent bond.IUPAC Gold Boo''delocalization''/ref> The term delocalization is general and can have slightly dif ...
s. These electrons are not associated with specific atoms, so when an electric field is applied, they are free to move like a gas (called
Fermi gas An ideal Fermi gas is a state of matter which is an ensemble of many non-interacting fermions. Fermions are particles that obey Fermi–Dirac statistics, like electrons, protons, and neutrons, and, in general, particles with half-integer sp ...
) through the material much like free electrons. Because of collisions between electrons and atoms, the drift velocity of electrons in a conductor is on the order of millimeters per second. However, the speed at which a change of current at one point in the material causes changes in currents in other parts of the material, the velocity of propagation, is typically about 75% of light speed. This occurs because electrical signals propagate as a wave, with the velocity dependent on the dielectric constant of the material. Metals make relatively good conductors of heat, primarily because the delocalized electrons are free to transport thermal energy between atoms. However, unlike electrical conductivity, the thermal conductivity of a metal is nearly independent of temperature. This is expressed mathematically by the
Wiedemann–Franz law In physics, the Wiedemann–Franz law states that the ratio of the electronic contribution of the thermal conductivity (''κ'') to the electrical conductivity (''σ'') of a metal is proportional to the temperature (''T''). : \frac \kapp ...
, which states that the ratio of
thermal conductivity The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
to the electrical conductivity is proportional to the temperature. The thermal disorder in the metallic lattice increases the electrical
resistivity Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allows ...
of the material, producing a temperature dependence for electric current. When cooled below a point called the critical temperature, materials can undergo a phase transition in which they lose all resistivity to electric current, in a process known as superconductivity. In
BCS theory BCS theory or Bardeen–Cooper–Schrieffer theory (named after John Bardeen, Leon Cooper, and John Robert Schrieffer) is the first microscopic theory of superconductivity since Heike Kamerlingh Onnes's 1911 discovery. The theory describes sup ...
, pairs of electrons called
Cooper pair In condensed matter physics, a Cooper pair or BCS pair (Bardeen–Cooper–Schrieffer pair) is a pair of electrons (or other fermions) bound together at low temperatures in a certain manner first described in 1956 by American physicist Leon Coope ...
s have their motion coupled to nearby matter via lattice vibrations called phonons, thereby avoiding the collisions with atoms that normally create electrical resistance. (Cooper pairs have a radius of roughly 100 nm, so they can overlap each other.) However, the mechanism by which higher temperature superconductors operate remains uncertain. Electrons inside conducting solids, which are quasi-particles themselves, when tightly confined at temperatures close to absolute zero, behave as though they had split into three other
quasiparticle In physics, quasiparticles and collective excitations are closely related emergent phenomena arising when a microscopically complicated system such as a solid behaves as if it contained different weakly interacting particles in vacuum. For exa ...
s:
spinon Spinons are one of three quasiparticles, along with holons and orbitons, that electrons in solids are able to split into during the process of spin–charge separation, when extremely tightly confined at temperatures close to absolute zero. The e ...
s,
orbiton Orbitons are one of three quasiparticles, along with holons and spinons, that electrons in solids are able to split into during the process of spin–charge separation, when extremely tightly confined at temperatures close to absolute zero. The e ...
s and holons. The former carries spin and magnetic moment, the next carries its orbital location while the latter electrical charge.


Motion and energy

According to Einstein's theory of
special relativity In physics, the special theory of relativity, or special relativity for short, is a scientific theory regarding the relationship between space and time. In Albert Einstein's original treatment, the theory is based on two postulates: # The laws ...
, as an electron's speed approaches the
speed of light The speed of light in vacuum, commonly denoted , is a universal physical constant that is important in many areas of physics. The speed of light is exactly equal to ). According to the special theory of relativity, is the upper limit ...
, from an observer's point of view its
relativistic mass The word "mass" has two meanings in special relativity: '' invariant mass'' (also called rest mass) is an invariant quantity which is the same for all observers in all reference frames, while the relativistic mass is dependent on the velocity o ...
increases, thereby making it more and more difficult to accelerate it from within the observer's frame of reference. The speed of an electron can approach, but never reach, the speed of light in a vacuum, ''c''. However, when relativistic electrons—that is, electrons moving at a speed close to ''c''—are injected into a dielectric medium such as water, where the local speed of light is significantly less than ''c'', the electrons temporarily travel faster than light in the medium. As they interact with the medium, they generate a faint light called Cherenkov radiation. The effects of special relativity are based on a quantity known as the
Lorentz factor The Lorentz factor or Lorentz term is a quantity expressing how much the measurements of time, length, and other physical properties change for an object while that object is moving. The expression appears in several equations in special relativit ...
, defined as \scriptstyle\gamma=1/ \sqrt where ''v'' is the speed of the particle. The kinetic energy ''K''e of an electron moving with velocity ''v'' is: :\displaystyle K_ = (\gamma - 1)m_ c^2, where ''m''e is the mass of electron. For example, the Stanford linear accelerator can
accelerate In mechanics, acceleration is the rate of change of the velocity of an object with respect to time. Accelerations are vector quantities (in that they have magnitude and direction). The orientation of an object's acceleration is given by t ...
an electron to roughly 51 GeV. Since an electron behaves as a wave, at a given velocity it has a characteristic
de Broglie wavelength Matter waves are a central part of the theory of quantum mechanics, being an example of wave–particle duality. All matter exhibits wave-like behavior. For example, a beam of electrons can be diffracted just like a beam of light or a water wave ...
. This is given by ''λ''e = ''h''/''p'' where ''h'' is the
Planck constant The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivale ...
and ''p'' is the momentum. For the 51 GeV electron above, the wavelength is about , small enough to explore structures well below the size of an atomic nucleus.


Formation

The Big Bang theory is the most widely accepted scientific theory to explain the early stages in the evolution of the Universe. For the first millisecond of the Big Bang, the temperatures were over 10 billion 
kelvin The kelvin, symbol K, is the primary unit of temperature in the International System of Units (SI), used alongside its prefixed forms and the degree Celsius. It is named after the Belfast-born and University of Glasgow-based engineer and phy ...
s and photons had mean energies over a million
electronvolt In physics, an electronvolt (symbol eV, also written electron-volt and electron volt) is the measure of an amount of kinetic energy gained by a single electron accelerating from rest through an electric potential difference of one volt in vacuum ...
s. These photons were sufficiently energetic that they could react with each other to form pairs of electrons and positrons. Likewise, positron-electron pairs annihilated each other and emitted energetic photons: : + ↔ + An equilibrium between electrons, positrons and photons was maintained during this phase of the evolution of the Universe. After 15 seconds had passed, however, the temperature of the universe dropped below the threshold where electron-positron formation could occur. Most of the surviving electrons and positrons annihilated each other, releasing gamma radiation that briefly reheated the universe. For reasons that remain uncertain, during the annihilation process there was an excess in the number of particles over antiparticles. Hence, about one electron for every billion electron-positron pairs survived. This excess matched the excess of protons over antiprotons, in a condition known as
baryon asymmetry In physical cosmology, the baryon asymmetry problem, also known as the matter asymmetry problem or the matter–antimatter asymmetry problem, is the observed imbalance in baryonic matter (the type of matter experienced in everyday life) and antib ...
, resulting in a net charge of zero for the universe. The surviving protons and neutrons began to participate in reactions with each other—in the process known as
nucleosynthesis Nucleosynthesis is the process that creates new atomic nuclei from pre-existing nucleons (protons and neutrons) and nuclei. According to current theories, the first nuclei were formed a few minutes after the Big Bang, through nuclear reactions in ...
, forming isotopes of hydrogen and
helium Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
, with trace amounts of
lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid ...
. This process peaked after about five minutes. Any leftover neutrons underwent negative
beta decay In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For ...
with a half-life of about a thousand seconds, releasing a proton and electron in the process, : → + + For about the next –, the excess electrons remained too energetic to bind with atomic nuclei. What followed is a period known as recombination, when neutral atoms were formed and the expanding universe became transparent to radiation. Roughly one million years after the big bang, the first generation of stars began to form. Within a star, stellar nucleosynthesis results in the production of positrons from the fusion of atomic nuclei. These antimatter particles immediately annihilate with electrons, releasing gamma rays. The net result is a steady reduction in the number of electrons, and a matching increase in the number of neutrons. However, the process of stellar evolution can result in the synthesis of radioactive isotopes. Selected isotopes can subsequently undergo negative beta decay, emitting an electron and antineutrino from the nucleus. An example is the
cobalt-60 Cobalt-60 (60Co) is a synthetic radioactive isotope of cobalt with a half-life of 5.2713 years. It is produced artificially in nuclear reactors. Deliberate industrial production depends on neutron activation of bulk samples of the monoisot ...
(60Co) isotope, which decays to form nickel-60 (). At the end of its lifetime, a star with more than about 20 solar masses can undergo gravitational collapse to form a black hole. According to classical physics, these massive stellar objects exert a gravitational attraction that is strong enough to prevent anything, even
electromagnetic radiation In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, infrared, (visible) li ...
, from escaping past the
Schwarzschild radius The Schwarzschild radius or the gravitational radius is a physical parameter in the Schwarzschild solution to Einstein's field equations that corresponds to the radius defining the event horizon of a Schwarzschild black hole. It is a characteris ...
. However, quantum mechanical effects are believed to potentially allow the emission of
Hawking radiation Hawking radiation is theoretical black body radiation that is theorized to be released outside a black hole's event horizon because of relativistic quantum effects. It is named after the physicist Stephen Hawking, who developed a theoretical a ...
at this distance. Electrons (and positrons) are thought to be created at the
event horizon In astrophysics, an event horizon is a boundary beyond which events cannot affect an observer. Wolfgang Rindler coined the term in the 1950s. In 1784, John Michell proposed that gravity can be strong enough in the vicinity of massive compact ob ...
of these stellar remnants. When a pair of virtual particles (such as an electron and positron) is created in the vicinity of the event horizon, random spatial positioning might result in one of them to appear on the exterior; this process is called quantum tunnelling. The
gravitational potential In classical mechanics, the gravitational potential at a location is equal to the work (energy transferred) per unit mass that would be needed to move an object to that location from a fixed reference location. It is analogous to the electric ...
of the black hole can then supply the energy that transforms this virtual particle into a real particle, allowing it to radiate away into space. In exchange, the other member of the pair is given negative energy, which results in a net loss of mass-energy by the black hole. The rate of Hawking radiation increases with decreasing mass, eventually causing the black hole to evaporate away until, finally, it explodes.
Cosmic ray Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own ...
s are particles traveling through space with high energies. Energy events as high as have been recorded. When these particles collide with nucleons in the
Earth's atmosphere The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing fo ...
, a shower of particles is generated, including
pion In particle physics, a pion (or a pi meson, denoted with the Greek letter pi: ) is any of three subatomic particles: , , and . Each pion consists of a quark and an antiquark and is therefore a meson. Pions are the lightest mesons and, more gene ...
s. More than half of the cosmic radiation observed from the Earth's surface consists of muons. The particle called a muon is a lepton produced in the upper atmosphere by the decay of a pion. : → + A muon, in turn, can decay to form an electron or positron. : → + +


Observation

Remote observation of electrons requires detection of their radiated energy. For example, in high-energy environments such as the
corona Corona (from the Latin for 'crown') most commonly refers to: * Stellar corona, the outer atmosphere of the Sun or another star * Corona (beer), a Mexican beer * Corona, informal term for the coronavirus SARS-CoV-2, which causes the COVID-19 di ...
of a star, free electrons form a plasma that radiates energy due to
Bremsstrahlung ''Bremsstrahlung'' (), from "to brake" and "radiation"; i.e., "braking radiation" or "deceleration radiation", is electromagnetic radiation produced by the deceleration of a charged particle when deflected by another charged particle, typicall ...
radiation. Electron gas can undergo plasma oscillation, which is waves caused by synchronized variations in electron density, and these produce energy emissions that can be detected by using radio telescopes. The
frequency Frequency is the number of occurrences of a repeating event per unit of time. It is also occasionally referred to as ''temporal frequency'' for clarity, and is distinct from ''angular frequency''. Frequency is measured in hertz (Hz) which is eq ...
of a
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they a ...
is proportional to its energy. As a bound electron transitions between different energy levels of an atom, it absorbs or emits photons at characteristic frequencies. For instance, when atoms are irradiated by a source with a broad spectrum, distinct dark lines appear in the spectrum of transmitted radiation in places where the corresponding frequency is absorbed by the atom's electrons. Each element or molecule displays a characteristic set of spectral lines, such as the
hydrogen spectral series The emission spectrum of atomic hydrogen has been divided into a number of spectral series, with wavelengths given by the Rydberg formula. These observed spectral lines are due to the electron making transitions between two energy levels in an ...
. When detected,
spectroscopic Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter wa ...
measurements of the strength and width of these lines allow the composition and physical properties of a substance to be determined. In laboratory conditions, the interactions of individual electrons can be observed by means of
particle detector In experimental and applied particle physics, nuclear physics, and nuclear engineering, a particle detector, also known as a radiation detector, is a device used to detect, track, and/or identify ionizing particles, such as those produced by nu ...
s, which allow measurement of specific properties such as energy, spin and charge. The development of the Paul trap and Penning trap allows charged particles to be contained within a small region for long durations. This enables precise measurements of the particle properties. For example, in one instance a Penning trap was used to contain a single electron for a period of 10 months. The magnetic moment of the electron was measured to a precision of eleven digits, which, in 1980, was a greater accuracy than for any other physical constant. The first video images of an electron's energy distribution were captured by a team at
Lund University , motto = Ad utrumque , mottoeng = Prepared for both , established = , type = Public research university , budget = SEK 9 billion attosecond pulses, which allowed an electron's motion to be observed for the first time. The distribution of the electrons in solid materials can be visualized by angle-resolved photoemission spectroscopy (ARPES). This technique employs the photoelectric effect to measure the
reciprocal space In physics, the reciprocal lattice represents the Fourier transform of another lattice (usually a Bravais lattice). In normal usage, the initial lattice (whose transform is represented by the reciprocal lattice) is usually a periodic spatial fu ...
—a mathematical representation of periodic structures that is used to infer the original structure. ARPES can be used to determine the direction, speed and scattering of electrons within the material.


Plasma applications


Particle beams

Electron beams Cathode rays or electron beam (e-beam) are streams of electrons observed in discharge tubes. If an evacuated glass tube is equipped with two electrodes and a voltage is applied, glass behind the positive electrode is observed to glow, due to el ...
are used in
welding Welding is a fabrication process that joins materials, usually metals or thermoplastics, by using high heat to melt the parts together and allowing them to cool, causing fusion. Welding is distinct from lower temperature techniques such as bra ...
. They allow energy densities up to across a narrow focus diameter of and usually require no filler material. This welding technique must be performed in a vacuum to prevent the electrons from interacting with the gas before reaching their target, and it can be used to join conductive materials that would otherwise be considered unsuitable for welding.
Electron-beam lithography Electron-beam lithography (often abbreviated as e-beam lithography, EBL) is the practice of scanning a focused beam of electrons to draw custom shapes on a surface covered with an electron-sensitive film called a resist (exposing). The electron b ...
(EBL) is a method of etching semiconductors at resolutions smaller than a micrometer. This technique is limited by high costs, slow performance, the need to operate the beam in the vacuum and the tendency of the electrons to scatter in solids. The last problem limits the resolution to about 10 nm. For this reason, EBL is primarily used for the production of small numbers of specialized integrated circuits.
Electron beam processing Electron-beam processing or electron irradiation (EBI) is a process that involves using electrons, usually of high energy, to treat an object for a variety of purposes. This may take place under elevated temperatures and nitrogen atmosphere. Poss ...
is used to irradiate materials in order to change their physical properties or sterilize medical and food products. Electron beams fluidise or quasi-melt glasses without significant increase of temperature on intensive irradiation: e.g. intensive electron radiation causes a many orders of magnitude decrease of viscosity and stepwise decrease of its activation energy.
Linear particle accelerator A linear particle accelerator (often shortened to linac) is a type of particle accelerator that accelerates charged subatomic particles or ions to a high speed by subjecting them to a series of oscillating electric potentials along a linear b ...
s generate electron beams for treatment of superficial tumors in
radiation therapy Radiation therapy or radiotherapy, often abbreviated RT, RTx, or XRT, is a therapy using ionizing radiation, generally provided as part of cancer treatment to control or kill malignant cells and normally delivered by a linear accelerator. Radi ...
. Electron therapy can treat such skin lesions as
basal-cell carcinoma Basal-cell carcinoma (BCC), also known as basal-cell cancer, is the most common type of skin cancer. It often appears as a painless raised area of skin, which may be shiny with small blood vessels running over it. It may also present as a raise ...
s because an electron beam only penetrates to a limited depth before being absorbed, typically up to 5 cm for electron energies in the range 5–20 MeV. An electron beam can be used to supplement the treatment of areas that have been irradiated by
X-ray An X-ray, or, much less commonly, X-radiation, is a penetrating form of high-energy electromagnetic radiation. Most X-rays have a wavelength ranging from 10  picometers to 10  nanometers, corresponding to frequencies in the range 30&nb ...
s.
Particle accelerator A particle accelerator is a machine that uses electromagnetic fields to propel charged particles to very high speeds and energies, and to contain them in well-defined beams. Large accelerators are used for fundamental research in particle ...
s use electric fields to propel electrons and their antiparticles to high energies. These particles emit synchrotron radiation as they pass through magnetic fields. The dependency of the intensity of this radiation upon spin polarizes the electron beam—a process known as the Sokolov–Ternov effect. Polarized electron beams can be useful for various experiments. Synchrotron radiation can also cool the electron beams to reduce the momentum spread of the particles. Electron and positron beams are collided upon the particles' accelerating to the required energies;
particle detector In experimental and applied particle physics, nuclear physics, and nuclear engineering, a particle detector, also known as a radiation detector, is a device used to detect, track, and/or identify ionizing particles, such as those produced by nu ...
s observe the resulting energy emissions, which
particle physics Particle physics or high energy physics is the study of fundamental particles and forces that constitute matter and radiation. The fundamental particles in the universe are classified in the Standard Model as fermions (matter particles) an ...
studies .


Imaging

Low-energy electron diffraction Low-energy electron diffraction (LEED) is a technique for the determination of the surface structure of single-crystalline materials by bombardment with a collimated beam of low-energy electrons (30–200 eV) and observation of diffracted el ...
(LEED) is a method of bombarding a crystalline material with a
collimated beam A collimated beam of light or other electromagnetic radiation has parallel rays, and therefore will spread minimally as it propagates. A perfectly collimated light beam, with no divergence, would not disperse with distance. However, diffraction p ...
of electrons and then observing the resulting diffraction patterns to determine the structure of the material. The required energy of the electrons is typically in the range 20–200 eV. The
reflection high-energy electron diffraction Reflection high-energy electron diffraction (RHEED) is a analytical technique, technique used to characterize the surface of crystalline materials. RHEED systems gather information only from the surface layer of the sample, which distinguishes RHEE ...
(RHEED) technique uses the reflection of a beam of electrons fired at various low angles to characterize the surface of crystalline materials. The beam energy is typically in the range 8–20 keV and the angle of incidence is 1–4°. The
electron microscope An electron microscope is a microscope that uses a beam of accelerated electrons as a source of illumination. As the wavelength of an electron can be up to 100,000 times shorter than that of visible light photons, electron microscopes have a hi ...
directs a focused beam of electrons at a specimen. Some electrons change their properties, such as movement direction, angle, and relative phase and energy as the beam interacts with the material. Microscopists can record these changes in the electron beam to produce atomically resolved images of the material. In blue light, conventional
optical microscope The optical microscope, also referred to as a light microscope, is a type of microscope that commonly uses visible light and a system of lenses to generate magnified images of small objects. Optical microscopes are the oldest design of microsc ...
s have a diffraction-limited resolution of about 200 nm. By comparison, electron microscopes are limited by the
de Broglie wavelength Matter waves are a central part of the theory of quantum mechanics, being an example of wave–particle duality. All matter exhibits wave-like behavior. For example, a beam of electrons can be diffracted just like a beam of light or a water wave ...
of the electron. This wavelength, for example, is equal to 0.0037 nm for electrons accelerated across a 100,000-
volt The volt (symbol: V) is the unit of electric potential, electric potential difference (voltage), and electromotive force in the International System of Units (SI). It is named after the Italian physicist Alessandro Volta (1745–1827). Defin ...
potential. The Transmission Electron Aberration-Corrected Microscope is capable of sub-0.05 nm resolution, which is more than enough to resolve individual atoms. This capability makes the electron microscope a useful laboratory instrument for high resolution imaging. However, electron microscopes are expensive instruments that are costly to maintain. Two main types of electron microscopes exist: transmission and scanning. Transmission electron microscopes function like
overhead projector An overhead projector (often abbreviated to OHP), like a film or slide projector, uses light to project an enlarged image on a screen, allowing the view of a small document or picture to be shared with a large audience. In the overhead projec ...
s, with a beam of electrons passing through a slice of material then being projected by lenses on a
photographic slide In photography, reversal film or slide film is a type of photographic film that produces a positive image on a transparent base. Instead of negatives and prints, reversal film is processed to produce transparencies or diapositives (abbreviat ...
or a
charge-coupled device A charge-coupled device (CCD) is an integrated circuit containing an array of linked, or coupled, capacitors. Under the control of an external circuit, each capacitor can transfer its electric charge to a neighboring capacitor. CCD sensors are a ...
. Scanning electron microscopes rasteri a finely focused electron beam, as in a TV set, across the studied sample to produce the image. Magnifications range from 100× to 1,000,000× or higher for both microscope types. The
scanning tunneling microscope A scanning tunneling microscope (STM) is a type of microscope used for imaging surfaces at the atomic level. Its development in 1981 earned its inventors, Gerd Binnig and Heinrich Rohrer, then at IBM Zürich, the Nobel Prize in Physics in 1986 ...
uses quantum tunneling of electrons from a sharp metal tip into the studied material and can produce atomically resolved images of its surface.


Other applications

In the
free-electron laser A free-electron laser (FEL) is a (fourth generation) light source producing extremely brilliant and short pulses of radiation. An FEL functions and behaves in many ways like a laser, but instead of using stimulated emission from atomic or molecula ...
(FEL), a
relativistic electron beam Relativistic electron beams are streams of electrons moving at relativistic speeds. They are the lasing medium in free electron lasers to be used in atmospheric research conducted at entities such as the Pan-oceanic Environmental and Atmospheric ...
passes through a pair of undulators that contain arrays of
dipole magnet A dipole magnet is the simplest type of magnet. It has two poles, one north and one south. Its magnetic field lines form simple closed loops which emerge from the north pole, re-enter at the south pole, then pass through the body of the magnet. ...
s whose fields point in alternating directions. The electrons emit synchrotron radiation that coherently interacts with the same electrons to strongly amplify the radiation field at the
resonance Resonance describes the phenomenon of increased amplitude that occurs when the frequency of an applied Periodic function, periodic force (or a Fourier analysis, Fourier component of it) is equal or close to a natural frequency of the system ...
frequency. FEL can emit a coherent high- brilliance electromagnetic radiation with a wide range of frequencies, from
microwave Microwave is a form of electromagnetic radiation with wavelengths ranging from about one meter to one millimeter corresponding to frequencies between 300 MHz and 300 GHz respectively. Different sources define different frequency ra ...
s to soft X-rays. These devices are used in manufacturing, communication, and in medical applications, such as soft tissue surgery. Electrons are important in cathode-ray tubes, which have been extensively used as display devices in laboratory instruments, computer monitors and
television set A television set or television receiver, more commonly called the television, TV, TV set, telly, tele, or tube, is a device that combines a tuner, display, and loudspeakers, for the purpose of viewing and hearing television broadcasts, or using ...
s. In a
photomultiplier A photomultiplier is a device that converts incident photons into an electrical signal. Kinds of photomultiplier include: * Photomultiplier tube, a vacuum tube converting incident photons into an electric signal. Photomultiplier tubes (PMTs for sh ...
tube, every photon striking the photocathode initiates an avalanche of electrons that produces a detectable current pulse.
Vacuum tube A vacuum tube, electron tube, valve (British usage), or tube (North America), is a device that controls electric current flow in a high vacuum between electrodes to which an electric potential difference has been applied. The type known as ...
s use the flow of electrons to manipulate electrical signals, and they played a critical role in the development of electronics technology. However, they have been largely supplanted by solid-state devices such as the
transistor upright=1.4, gate (G), body (B), source (S) and drain (D) terminals. The gate is separated from the body by an insulating layer (pink). A transistor is a semiconductor device used to Electronic amplifier, amplify or electronic switch, switch ...
.


See also


Notes


References


External links

* * * * {{Featured article Leptons Elementary particles Quantum electrodynamics Spintronics Charge carriers 1897 in science