Elastane
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Spandex, Lycra, or elastane is a
synthetic fiber Synthetic fibers or synthetic fibres (in British English; see spelling differences) are fibers made by humans through chemical synthesis, as opposed to natural fibers that are directly derived from living organisms, such as plants (like cotton) ...
known for its exceptional
elasticity Elasticity often refers to: *Elasticity (physics), continuum mechanics of bodies that deform reversibly under stress Elasticity may also refer to: Information technology * Elasticity (data store), the flexibility of the data model and the cl ...
. It is a
polyether In organic chemistry, ethers are a class of compounds that contain an ether group—an oxygen atom connected to two alkyl or aryl groups. They have the general formula , where R and R′ represent the alkyl or aryl groups. Ethers can again be c ...
-
polyurea Polyurea is a type of elastomer that is derived from the reaction product of an isocyanate component and a synthetic resin blend component through step-growth polymerization. The isocyanate can be aromatic or aliphatic in nature. It can be mon ...
copolymer In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are some ...
that was invented in 1958 by chemist
Joseph Shivers Joseph Clois Shivers Jr. (November 29, 1920 – September 1, 2014) was an American textile chemist who was based in West Chester, Pennsylvania, best known for his role in the structural development of Spandex, a thermoplastic elastomer, in the 195 ...
at
DuPont DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...
's Benger Laboratory in
Waynesboro, Virginia Waynesboro (formerly Flack) is an independent city in the Commonwealth of Virginia. It is a principal city of the Staunton-Waynesboro Metropolitan Statistical Area. Waynesboro is located in the Shenandoah Valley and is surrounded by Augusta Cou ...
, US. The generic name "spandex", which is an
anagram An anagram is a word or phrase formed by rearranging the letters of a different word or phrase, typically using all the original letters exactly once. For example, the word ''anagram'' itself can be rearranged into ''nag a ram'', also the word ...
of the word "expands", is the preferred name in
North America North America is a continent in the Northern Hemisphere and almost entirely within the Western Hemisphere. It is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the southeast by South America and the Car ...
. In
continental Europe Continental Europe or mainland Europe is the contiguous continent of Europe, excluding its surrounding islands. It can also be referred to ambiguously as the European continent, – which can conversely mean the whole of Europe – and, by ...
, it is referred to by variants of "elastane", including (France), (Germany, Sweden), (Spain), (Italy), and (Netherlands); and in the UK, Ireland, Portugal, Spain, Latin America, Australia, and New Zealand, it is primarily known as "Lycra". Brand names for spandex include Lycra (made by The Lycra Company, previously a division of
DuPont Textiles and Interiors DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...
), Elaspan (The Lycra Company), Acepora (
Taekwang Group Taekwang Group is a large South Korean ''chaebol'' (conglomerate), producing clothing, apparel, chemical, industry, and financial services products. Subsidiaries *Taekwang Industry *Taekwang Synthetic Fiber (ChangShu, China) *Taekwang Swimwear ...
), Creora (
Hyosung Hyosung Corporation is a South Korean industrial Chaebol, founded in 1966. It operates in various fields, including the chemical industry, industrial machinery, IT, trade, and construction. It is known in Korea mostly for high-end apartments ...
), INVIYA (
Indorama Corporation Indorama Corporation is a Singapore-based corporate group with origins as Indorama Synthetics, established in 1975 in Indonesia. It manufactures polyethylene, polypropylene, polyester fibre, Spandex filament, spun yarns, fabrics, and other produ ...
), ROICA and Dorlastan (
Asahi Kasei is a multinational Japanese chemical company. Its main products are chemicals and materials science. It was founded in May 1931, using the paid in capital of Nobeoka Ammonia Fiber Co., Ltd, a Nobeoka, Miyazaki based producer of ammonia, nit ...
), Linel (Fillattice), and ESPA (
Toyobo is one of Japan's top makers of fibers and textiles, including synthetic fibers (polyester, nylon and acrylics) and natural fibers, such as cotton and wool. History Toyobo was established in 1882 by Eiichi Shibusawa as a cotton-spinning com ...
).


History

In the
post-World War II The aftermath of World War II was the beginning of a new era started in late 1945 (when World War II ended) for all countries involved, defined by the decline of all colonial empires and simultaneous rise of two superpowers; the Soviet Union (US ...
era, DuPont Textiles Fibers Department, formed in 1952, became the most profitable division of DuPont, dominating the
synthetic fiber Synthetic fibers or synthetic fibres (in British English; see spelling differences) are fibers made by humans through chemical synthesis, as opposed to natural fibers that are directly derived from living organisms, such as plants (like cotton) ...
market worldwide. At this time, women began to emerge as a significant group of consumers because of their need for underwear and
hosiery Hosiery, also referred to as legwear, describes garments worn directly on the feet and legs. The term originated as the collective term for products of which a maker or seller is termed a hosier; and those products are also known generically as h ...
. After conducting
market research Market research is an organized effort to gather information about target markets and customers: know about them, starting with who they are. It is an important component of business strategy and a major factor in maintaining competitiveness. Mark ...
to find out what women wanted from textiles, DuPont began developing fibers to meet such needs—including a better fiber for women's
girdles A belt, especially if a cord or rope, is called a girdle if it is worn as part of Christian liturgical vestments, or in certain historical, literary or sports contexts. Girdles are used to close a cassock in Christian denominations, including ...
, which were commonly made of rubber at the time. By the 1930s, DuPont became interested in developing a synthetic elastic fiber. DuPont made its first breakthrough in the early 1950s when chemist Joseph C. Shivers used an intermediate substance to modify
Dacron Polyethylene terephthalate (or poly(ethylene terephthalate), PET, PETE, or the obsolete PETP or PET-P), is the most common thermoplastic polymer resin of the polyester family and is used in fibres for clothing, containers for liquids and foods ...
polyester, producing a stretchy fiber that could withstand high temperatures. Determined to find a fiber to replace rubber in garments, after nearly a decade of research, Shivers perfected the fiber in 1958 at
DuPont DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...
's Benger Laboratory in
Waynesboro, Virginia Waynesboro (formerly Flack) is an independent city in the Commonwealth of Virginia. It is a principal city of the Staunton-Waynesboro Metropolitan Statistical Area. Waynesboro is located in the Shenandoah Valley and is surrounded by Augusta Cou ...
. Moreover, the nature of spandex allowed it to be incorporated into other garments besides girdles and
undergarments Undergarments, underclothing, or underwear are items of clothing worn beneath outer clothes, usually in direct contact with the skin, although they may comprise more than a single layer. They serve to keep outer garments from being soiled o ...
.


Lycra brand

To distinguish its brand of spandex fiber, DuPont chose the
trade name A trade name, trading name, or business name, is a pseudonym used by companies that do not operate under their registered company name. The term for this type of alternative name is a "fictitious" business name. Registering the fictitious name w ...
''Lycra'' (originally called ''Fiber K''). DuPont launched an extensive publicity campaign for its Lycra brand, taking advertisements and full-page ads in top women's magazines such as ''
Vogue Vogue may refer to: Business * ''Vogue'' (magazine), a US fashion magazine ** British ''Vogue'', a British fashion magazine ** ''Vogue Arabia'', an Arab fashion magazine ** ''Vogue Australia'', an Australian fashion magazine ** ''Vogue China'', ...
'', '' Glamour'', ''
Harper's Bazaar ''Harper's Bazaar'' is an American monthly women's fashion magazine. It was first published in New York City on November 2, 1867, as the weekly ''Harper's Bazar''. ''Harper's Bazaar'' is published by Hearst and considers itself to be the st ...
'', '' Mademoiselle'', ''
McCall's ''McCall's'' was a monthly American women's magazine, published by the McCall Corporation, that enjoyed great popularity through much of the 20th century, peaking at a readership of 8.4 million in the early 1960s. It was established as a small-f ...
'', ''
Ladies' Home Journal ''Ladies' Home Journal'' was an American magazine last published by the Meredith Corporation. It was first published on February 16, 1883, and eventually became one of the leading women's magazines of the 20th century in the United States. In 18 ...
'', and ''
Good Housekeeping ''Good Housekeeping'' is an American women's magazine featuring articles about women's interests, product testing by The Good Housekeeping Institute, recipes, diet, and health, as well as literary articles. It is well known for the "Good House ...
''.
Audrey Hepburn Audrey Hepburn (born Audrey Kathleen Ruston; 4 May 1929 – 20 January 1993) was a British actress and humanitarian. Recognised as both a film and fashion icon, she was ranked by the American Film Institute as the AFI's 100 Years...100 Stars, t ...
helped catapult the brand on and off-screen during this time; models and actresses like
Joan Collins Dame Joan Henrietta Collins (born 23 May 1933) is an English actress, author and columnist. Collins is the recipient of several accolades, including a Golden Globe Award, a People's Choice Award, two Soap Opera Digest Awards and a Primetime ...
and
Ann-Margret Ann-Margret Olsson (born April 28, 1941) is a Swedish–American actress, singer, and dancer. As an actress and singer, she is credited as Ann-Margret. She is known for her roles in ''Pocketful of Miracles'' (1961), ''State Fair'' (1962), ''B ...
followed Hepburn's aesthetic by posing in Lycra clothing for photo shoots and magazine covers. By the mid-1970s, with the emergence of the
women's liberation movement The women's liberation movement (WLM) was a political alignment of women and feminist intellectualism that emerged in the late 1960s and continued into the 1980s primarily in the industrialized nations of the Western world, which effected great ...
, girdle sales began to drop as they came to be associated with anti-independence and emblematic of an era that was quickly passing away. In response, DuPont reimagined Lycra as the
aerobic Aerobic means "requiring air," in which "air" usually means oxygen. Aerobic may also refer to * Aerobic exercise, prolonged exercise of moderate intensity * Aerobics, a form of aerobic exercise * Aerobic respiration, the aerobic process of cellu ...
fitness movement emerged in the 1970s. The association of Lycra with fitness had been established at the
1968 Winter Olympic Games The 1968 Winter Olympics, officially known as the X Olympic Winter Games (french: Les Xes Jeux olympiques d'hiver), were a winter multi-sport event held from 6 to 18 February 1968 in Grenoble, France. Thirty-seven countries participated. Frenchm ...
, when the French ski team wore Lycra garments to compete. This popularized the brand as essential athletic wear because of its flexible and lightweight material. The fiber came to be especially popular in mid-thigh-length shorts worn by cyclists. By the 1980s, the fitness trend had reached its height in popularity and fashionistas began wearing shorts on the street. Spandex proved such a popular fiber in the garment industry that, by 1987, DuPont had trouble meeting worldwide demand. In the 1990s a variety of other items made with spandex proved popular, including a successful line of body-shaping foundation garments sold under the trade name ''Bodyslimmers''. As the decade progressed, shirts, pants, dresses, and even shoes were being made with spandex blends, and mass-market retailers like
Banana Republic In political science, the term banana republic describes a politically unstable country with an economy dependent upon the export of natural resources. In 1904, the American author O. Henry coined the term to describe Honduras and neighboring ...
were even using it for menswear.


Environmental impact

In 2014, it was noted that most clothes containing spandex end up as non-recyclable waste once they have been worn out, because fabric blends containing spandex are difficult to recycle. This contributes to the pollution of the environment.


Production

Spandex fibers are produced in four ways: melt extrusion, reaction spinning, solution dry spinning, and solution wet spinning. All of these methods include the initial step of reacting
monomer In chemistry, a monomer ( ; ''mono-'', "one" + '' -mer'', "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or three-dimensional network in a process called polymerization. Classification Mo ...
s to produce a pre
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
. Once the
prepolymer In polymer chemistry, the term prepolymer or pre-polymer, refers to a monomer or system of monomers that have been reacted to an intermediate-molecular mass state. This material is capable of further polymerization by reactive groups to a fully c ...
is formed, it is reacted further in various ways and drawn out to make the fibers. The solution dry spinning method is used to produce over 94.5% of the world's spandex fibers."How spandex is made"
from How Products Are Made
The process has five steps: #The first step is to produce the prepolymer. This is done by mixing a macro
glycol A diol is a chemical compound containing two hydroxyl groups ( groups). An Aliphatic compound, aliphatic diol is also called a glycol. This pairing of functional groups is pervasive, and many subcategories have been identified. The most common ...
with a
diisocyanate In organic chemistry, isocyanate is the functional group with the formula . Organic compounds that contain an isocyanate group are referred to as isocyanates. An organic compound with two isocyanate groups is known as a diisocyanate. Diisocyan ...
monomer. The two compounds are mixed in a reaction vessel to produce a prepolymer. A typical ratio of glycol to diisocyanate is 1:2. #The prepolymer is further reacted with an equal amount of
diamine A diamine is an amine with exactly two amino groups. Diamines are used as monomers to prepare polyamides, polyimides, and polyureas. The term ''diamine'' refers mostly to primary diamines, as those are the most reactive. In terms of quantities p ...
. This reaction is known as '' chain extension reaction.'' The resulting solution is diluted with a solvent ( dimethylacetamide) to produce the spinning solution. The solvent helps make the solution thinner and more easily handled, and then it can be pumped into the fiber production cell. #The spinning solution is pumped into a cylindrical spinning cell. In this cell, the
polymer solution Polymer solutions are solutions containing dissolved polymers. These may be (e.g. in ), or solid solutions (e.g. a substance which has been plasticized). The introduction into the polymer of small amounts of a solvent (plasticizer) reduces the te ...
is forced through a metal plate called a
spinneret A spinneret is a silk-spinning organ of a spider or the larva of an insect. Some adult insects also have spinnerets, such as those borne on the forelegs of Embioptera. Spinnerets are usually on the underside of a spider's opisthosoma, and are ...
. This causes the solution to be aligned in strands of liquid polymer. As the strands pass through the cell, they are heated in the presence of a
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
and solvent gas. This process causes the liquid polymer to react chemically and form solid strands. #As the fibers exit the cell, an amount of solid strands are bundled together to produce the desired thickness. #The resulting fibers are then treated with a finishing agent which can be
magnesium stearate Magnesium stearate is the chemical compound with the formula . It is a soap, consisting of salt containing two equivalents of stearate (the anion of stearic acid) and one magnesium cation (Mg2+). Magnesium stearate is a white, water-insoluble pow ...
or a polymer. This treatment prevents the fibers' sticking together and aids in
textile manufacture Textile Manufacturing or Textile Engineering is a major industry. It is largely based on the conversion of fibre into yarn, then yarn into fabric. These are then dyed or printed, fabricated into cloth which is then converted into useful goods ...
. The fibers are then transferred through a series of rollers onto a spool.


Function

The exceptional elasticity of spandex fibers increases the clothing's pressure comfort, enhancing the ease of body movements. Pressure comfort is the response towards clothing by the human body's pressure receptors (
mechanoreceptor A mechanoreceptor, also called mechanoceptor, is a sensory receptor that responds to mechanical pressure or distortion. Mechanoreceptors are innervated by sensory neurons that convert mechanical pressure into electrical signals that, in animals, ...
s present in skin sensory cells). The sensation response is affected mainly by the stretch, snug, loose, heavy, lightweight, soft, and stiff structure of the material. The elasticity and strength (stretching up to five times its length) of spandex has been incorporated into a wide range of garments, especially in
skin-tight garments A skin-tight garment is a garment that is held to the skin usually by elasticity (solid mechanics), elastic tension using some type of stretch fabric. Commercial stretch fabrics ('elastomerics') such as spandex or elastane (widely branded as 'L ...
. A benefit of spandex is its significant strength and elasticity and its ability to return to the original shape after stretching and faster drying than ordinary fabrics. For clothing, spandex is usually mixed with
cotton Cotton is a soft, fluffy staple fiber that grows in a boll, or protective case, around the seeds of the cotton plants of the genus ''Gossypium'' in the mallow family Malvaceae. The fiber is almost pure cellulose, and can contain minor perce ...
or
polyester Polyester is a category of polymers that contain the ester functional group in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include natural ...
, and accounts for a small percentage of the final fabric, which therefore retains most of the look and feel of the other fibers. An estimated 80% of clothing sold in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...
contained spandex in 2010.


Gallery

Athlete.png, A
road cyclist Road cycling is the most widespread form of cycling in which cyclists ride on paved roadways. It includes Recreational cycling, recreational, Road bicycle racing, racing, Bicycle commuting, commuting, and utility cycling. As users of the road, ...
wearing
compression garment Compression garments are pieces of clothing that fit tightly around the skin. In medical contexts, compression garments provide support for people who have to stand for long periods or have poor circulation. These come in varying degrees of co ...
s Hurdler.jpg, A
hurdler Hurdling is the act of jumping over an obstacle at a high speed or in a sprint. In the early 19th century, hurdlers ran at and jumped over each hurdle (sometimes known as 'burgles'), landing on both feet and checking their forward motion. Today, ...
in a uniform


References


External links


"What's That Stuff: Spandex"
''Chemical and Engineering News'' {{Clothing materials and parts Products introduced in 1958 1970s fashion 1980s fashion 2000s fashion 2010s fashion Copolymers Elastomers Synthetic fibers Technical fabrics Woven fabrics