Essexite (), also called nepheline monzogabbro (), is a dark gray or black
holocrystalline
Crystallinity refers to the degree of structural order in a solid. In a crystal, the atoms or molecules are arranged in a regular, periodic manner. The degree of crystallinity has a big influence on hardness, density, transparency and diffusion ...
plutonic
Intrusive rock is formed when magma penetrates existing rock, crystallizes, and solidifies underground to form '' intrusions'', such as batholiths, dikes, sills, laccoliths, and volcanic necks.Intrusive RocksIntrusive rocks accessdate: March ...
igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma o ...
. Its name is derived from the type locality in
Essex County,
Massachusetts
Massachusetts (Massachusett: ''Muhsachuweesut Massachusett_writing_systems.html" ;"title="nowiki/> məhswatʃəwiːsət.html" ;"title="Massachusett writing systems">məhswatʃəwiːsət">Massachusett writing systems">məhswatʃəwiːsət'' En ...
, in the
United States
The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territori ...
.
Modern
petrology identifies rocks according to mineralogical criteria. Utilising the
IUGS QAPF diagram
A QAPF diagram is a double ternary diagram which is used to classify igneous rocks based on mineralogic composition. The acronym QAPF stands for "Quartz, Alkali feldspar, Plagioclase, Feldspathoid (Foid)". These are the mineral groups used f ...
of Streckeisen (1974) "essexite" is more formally known as
nepheline
Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatite ...
monzodiorite or nepheline monzogabbro depending on the ratio of
orthoclase
Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles ...
to
plagioclase
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...
and the abundance of nepheline.
Petrology
In order to produce a
magma
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
composition suitable for forming essexite the
partial melting
Partial melting occurs when only a portion of a solid is melted. For mixed substances, such as a rock containing several different minerals or a mineral that displays solid solution, this melt can be different from the bulk composition of the soli ...
of the source
rocks must be restricted, generally to less than 10% partial melting. This favors producing a melt rich in large-ion lithophile elements (LILE) such as K,
Ba, Rb, Cs, Sr.
The source melts of essexites contain more
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
and alkali ions than available silica tetrahedra, which is why essexites crystallise nepheline instead of plagioclase. Higher than normal
potassium
Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...
favors the production of orthoclase, which is usually absent from most mafic igneous rocks.
Mineralogy
Essexite can be considered as an alkali
gabbro
Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ch ...
or monzodiorite primarily composed of
nepheline
Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatite ...
,
plagioclase
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...
, with lesser amounts of alkali
feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
, with mafic minerals composed of any of the following;
titanium
Titanium is a chemical element with the Symbol (chemistry), symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resista ...
augite (
pyroxene),
hornblende
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rock ...
and
biotite.
Trace mineralogy may include
magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With th ...
,
ilmenite
Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...
and accessory
olivine
The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickl ...
(<5%).
Essexite grades into a nepheline monzogabbro with a decrease in
potassium feldspar Potassium feldspar refers to a number of minerals in the feldspar group, and containing potassium:
*Orthoclase ( endmember formula K Al Si3 O8), an important tectosilicate mineral that forms igneous rock
*Microcline, chemically the same as orthocla ...
and an increase in the
feldspathoid
The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing prim ...
minerals.
Geochemistry
Essexite is an
alkaline igneous rock equivalent to an alkaline basalt. The presence of
nepheline
Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatite ...
, a
feldspathoid
The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing prim ...
mineral, indicates that essexites are silica undersaturated. The presence of orthoclase indicates that it contains sufficient potassium to favor production of orthoclase over
microcline
Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during slo ...
or potassic
oligoclase
Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite ( Na Al Si3 O8) and anorthite ( CaAl2Si2O8). The albite ...
.
Essexites are generally rich in aluminium, alkalis (sodium and calcium), potassium (>3% K
2O), LILE-enriched (
strontium,
caesium and
barium), as compared to
tholeiitic basalt
The tholeiitic magma series is one of two main magma series in subalkaline igneous rocks, the other being the calc-alkaline series. A magma series is a chemically distinct range of magma compositions that describes the evolution of a mafic magma ...
s and gabbros.
References
External links
Russian alkaline igneous rock occurrences{{Webarchive, url=https://web.archive.org/web/20080828163319/http://www.koeln.netsurf.de/~w.steffens/ruse.htm , date=2008-08-28
Plutonic rocks
Igneous petrology