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EDTMP or ethylenediamine tetra(methylene phosphonic acid) is a phosphonic acid. It has
chelating Chelation is a type of bonding of ions and molecules to metal ions. It involves the formation or presence of two or more separate coordinate bonds between a polydentate (multiple bonded) ligand and a single central metal atom. These ligands are ...
and anti corrosion properties. EDTMP is the phosphonate analog of
EDTA Ethylenediaminetetraacetic acid (EDTA) is an aminopolycarboxylic acid with the formula H2N(CH2CO2H)2sub>2. This white, water-soluble solid is widely used to bind to iron (Fe2+/Fe3+) and calcium ions (Ca2+), forming water-soluble complexes eve ...
.Svara, J.; Weferling, N.; Hofmann, T. "Phosphorus Compounds, Organic," In 'Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2008. {{doi, 10.1002/14356007.a19_545.pub2. It is classified as a nitrogenous organic polyphosphonic acid.


Properties and applications

EDTMP is normally delivered as its sodium salt, which exhibits good solubility in water. Used in
Water treatment Water treatment is any process that improves the Water quality, quality of water to make it appropriate for a specific end-use. The end use may be drinking water, drinking, industrial water supply, irrigation, river flow maintenance, water recrea ...
as an anti
scaling Scaling may refer to: Science and technology Mathematics and physics * Scaling (geometry), a linear transformation that enlarges or diminishes objects * Scale invariance, a feature of objects or laws that do not change if scales of length, energ ...
and
anti corrosion In chemistry, a corrosion inhibitor or anti-corrosive is a chemical compound that, when added to a liquid or gas, decreases the corrosion rate of a material, typically a metal or an alloy, that comes into contact with the fluid. The effectiveness ...
agent, the corrosion inhibition of EDTMP is 3–5 times better than that of inorganic
polyphosphate Polyphosphates are salts or esters of polymeric oxyanions formed from tetrahedral PO4 (phosphate) structural units linked together by sharing oxygen atoms. Polyphosphates can adopt linear or a cyclic ring structures. In biology, the polyphosphate e ...
. It has good chemical stability and thermal tolerance. It shows excellent scale inhibition ability under temperature 200 °C. It functions by chelating with many metal ions. The anti-cancer drug Samarium (153Sm) lexidronam is also derived from EDTMP.


References

Phosphonic acids Chelating agents Tertiary amines Ethyleneamines Corrosion inhibitors Water treatment Hexadentate ligands