Dysprosium(III) Fluoride
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Dysprosium(III) fluoride is an
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
of
dysprosium Dysprosium is the chemical element with the symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it ...
with a
chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ...
DyF3.


Production

Dysprosium(III) fluoride can be produced by mixing
dysprosium(III) chloride Dysprosium(III) chloride (DyCl3), also known as dysprosium trichloride, is a compound of dysprosium and chlorine. It is a white to yellow solid which rapidly absorbs water on exposure to moist air to form a hexa hydrate, DyCl3·6H2O. Simple rapi ...
or dysprosium(III) carbonate into 40%
hydrofluoric acid Hydrofluoric acid is a Solution (chemistry), solution of hydrogen fluoride (HF) in water. Solutions of HF are colourless, acidic and highly Corrosive substance, corrosive. It is used to make most fluorine-containing compounds; examples include th ...
. : : DyF3 can also be produced by hydrothermal reaction of dysprosium nitrate and
sodium tetrafluoroborate Sodium tetrafluoroborate is an inorganic compound with formula NaBF4. It is a salt that forms colorless or white water-soluble rhombic crystals and is soluble in water (108 g/100 mL) but less soluble in organic solvents. Sodium tetrafluoroborate ...
at 200 °C. DyF3 can also be produced when
dysprosium oxide Dysprosium oxide (Dy2O3) is a sesquioxide compound of the rare earth metal dysprosium. It is a pastel yellowish-greenish, slightly hygroscopic powder having specialized uses in ceramics, glass, phosphors, lasers, as a Faraday rotator and dysprosium ...
and ammonium bifluoride are mixed and heated to 300 °C until the oxide is porous, and continued to heat to 700 °C. When
hydrogen fluoride Hydrogen fluoride (fluorane) is an inorganic compound with the chemical formula . This colorless gas or liquid is the principal industrial source of fluorine, often as an aqueous solution called hydrofluoric acid. It is an important feedstock i ...
is introduced, a reaction occurs: :


Properties

Dysprosium(III) fluoride is a white, odorless solid that is insoluble in water. It has an
orthorhombic crystal structure In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a r ...
with the space group Pnma ( space group no. 62).


References

Fluorides Dysprosium compounds Lanthanide halides {{inorganic-compound-stub