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Dynamic modulus (sometimes complex modulusThe Open University (UK), 2000. ''T838 Design and Manufacture with Polymers: Solid properties and design'', page 30. Milton Keynes: The Open University.) is the ratio of stress to strain under ''vibratory conditions'' (calculated from data obtained from either free or forced vibration tests, in shear, compression, or elongation). It is a property of
viscoelastic In materials science and continuum mechanics, viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like water, resist shear flow and strain linear ...
materials.


Viscoelastic stress–strain phase-lag

Viscoelasticity In materials science and continuum mechanics, viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like water, resist shear flow and strain linear ...
is studied using dynamic mechanical analysis where an oscillatory force (stress) is applied to a material and the resulting displacement (strain) is measured. *In purely elastic materials the stress and strain occur in phase, so that the response of one occurs simultaneously with the other. *In purely viscous materials, there is a phase difference between stress and strain, where strain lags stress by a 90 degree (\pi/2
radian The radian, denoted by the symbol rad, is the unit of angle in the International System of Units (SI) and is the standard unit of angular measure used in many areas of mathematics. The unit was formerly an SI supplementary unit (before tha ...
) phase lag. *Viscoelastic materials exhibit behavior somewhere in between that of purely viscous and purely elastic materials, exhibiting some phase lag in strain.Meyers and Chawla (1999): "Mechanical Behavior of Materials," 98-103. Stress and strain in a viscoelastic material can be represented using the following expressions: *Strain: \varepsilon = \varepsilon_0 \sin(\omega t) *Stress: \sigma = \sigma_0 \sin(\omega t+ \delta) \, where : \omega =2 \pi f where f is frequency of strain oscillation, :t is time, : \delta is phase lag between stress and strain. The stress relaxation modulus G\left(t\right) is the ratio of the stress remaining at time t after a step strain \varepsilon was applied at time t=0: G\left(t\right) = \frac, which is the time-dependent generalization of
Hooke's law In physics, Hooke's law is an empirical law which states that the force () needed to extend or compress a spring by some distance () scales linearly with respect to that distance—that is, where is a constant factor characteristic of ...
. For visco-elastic solids, G\left(t\right) converges to the equilibrium shear modulusG: :G=\lim_ G(t). The
fourier transform A Fourier transform (FT) is a mathematical transform that decomposes functions into frequency components, which are represented by the output of the transform as a function of frequency. Most commonly functions of time or space are transformed, ...
of the shear relaxation modulus G(t) is \hat(\omega)=\hat'(\omega) +i\hat''(\omega) (see below).


Storage and loss modulus

The storage and loss modulus in viscoelastic materials measure the stored energy, representing the elastic portion, and the energy dissipated as heat, representing the viscous portion. The tensile storage and loss moduli are defined as follows: *Storage: E' = \frac \cos \delta *Loss: E'' = \frac \sin \delta Similarly we also define shear storage and shear loss moduli, G' and G''. Complex variables can be used to express the moduli E^* and G^* as follows: :E^* = E' + iE'' \, :G^* = G' + iG'' \, where i is the
imaginary unit The imaginary unit or unit imaginary number () is a solution to the quadratic equation x^2+1=0. Although there is no real number with this property, can be used to extend the real numbers to what are called complex numbers, using addition a ...
.


Ratio between loss and storage modulus

The ratio of the loss modulus to storage modulus in a viscoelastic material is defined as the \tan \delta , (cf.
loss tangent Dielectric loss quantifies a dielectric material's inherent dissipation of electromagnetic energy (e.g. heat). It can be parameterized in terms of either the loss angle ''δ'' or the corresponding loss tangent tan ''δ''. Both refer to the ...
), which provides a measure of damping in the material. \tan \delta can also be visualized as the tangent of the phase angle ( \delta ) between the storage and loss modulus. Tensile: \tan \delta = \frac Shear: \tan \delta = \frac {G'} For a material with a \tan \delta greater than 1, the energy-dissipating, viscous component of the complex modulus prevails.


See also

* Dynamic mechanical analysis * Elastic modulus *
Palierne equation Palierne equation connects the dynamic modulus of emulsions with the dynamic modulus of the two phases, size of the droplets and the interphase surface tension. The equation can also be used for suspensions of viscoelastic solid particles in visco ...


References

Physical quantities Solid mechanics Non-Newtonian fluids