Dry etching refers to the removal of material, typically a masked pattern of
semiconductor
A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glas ...
material, by exposing the material to a bombardment of
ions
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
(usually a
plasma
Plasma or plasm may refer to:
Science
* Plasma (physics), one of the four fundamental states of matter
* Plasma (mineral), a green translucent silica mineral
* Quark–gluon plasma, a state of matter in quantum chromodynamics
Biology
* Blood pla ...
of reactive gases such as
fluorocarbons
Fluorocarbons are chemical compounds with carbon-fluorine bonds. Compounds that contain many C-F bonds often has distinctive properties, e.g., enhanced stability, volatility, and hydrophobicity. Fluorocarbons and their derivatives are commerci ...
,
oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
,
chlorine
Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
,
boron trichloride
Boron trichloride is the inorganic compound with the formula BCl3. This colorless gas is a reagent in organic synthesis. It is highly reactive toward water.
Production and structure
Boron reacts with halogens to give the corresponding trihalides. ...
; sometimes with addition of
nitrogen
Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
,
argon
Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
,
helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
and other gases) that dislodge portions of the material from the exposed surface. A common type of dry etching is
reactive-ion etching
Reactive-ion etching (RIE) is an etching technology used in microfabrication. RIE is a type of dry etching which has different characteristics than wet etching. RIE uses chemically reactive plasma to remove material deposited on wafers. The pla ...
. Unlike with many (but not all, see
isotropic etching) of the wet chemical etchants used in
wet etching, the dry etching process typically etches directionally or anisotropically.
Applications
Dry etching is used in conjunction with
photolithographic
In integrated circuit manufacturing, photolithography or optical lithography is a general term used for techniques that use light to produce minutely patterned thin films of suitable materials over a substrate, such as a silicon wafer, to protect ...
techniques to attack certain areas of a semiconductor surface in order to form recesses in material.
Applications include contact holes (which are contacts to the underlying
semiconductor substrate
In electronics, a wafer (also called a slice or substrate) is a thin slice of semiconductor, such as a crystalline silicon (c-Si), used for the fabrication of integrated circuits and, in photovoltaics, to manufacture solar cells. The wafer serv ...
),
via holes (which are holes that are formed to provide an interconnect path between conductive layers in the layered
semiconductor device
A semiconductor device is an electronic component that relies on the electronic properties of a semiconductor material (primarily silicon, germanium, and gallium arsenide, as well as organic semiconductors) for its function. Its conductivity li ...
), transistor gates for FinFET technology, or to otherwise remove portions of semiconductor layers where predominantly vertical sides are desired. Along with
semiconductor
A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glas ...
manufacturing,
micromachining and display production, the removal of organic residues by oxygen plasmas is sometimes correctly described as a dry etch process. The term
plasma ashing
In semiconductor manufacturing plasma ashing is the process of removing the photoresist (light sensitive coating) from an etched wafer. Using a plasma source, a monatomic (single atom) substance known as a reactive species is generated. Oxygen or ...
can be used instead.
Dry etching is particularly useful for materials and semiconductors which are chemically resistant and could not be wet etched, such as
silicon carbide
Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal sin ...
or
gallium nitride
Gallium nitride () is a binary III/ V direct bandgap semiconductor commonly used in blue light-emitting diodes since the 1990s. The compound is a very hard material that has a Wurtzite crystal structure. Its wide band gap of 3.4 eV affords it ...
.
Low density plasma (LDP) is able to produce high energy reactions at a low energy cost in thanks to its low pressure, meaning dry etch requires a relatively small quantity of chemicals and electricity to function. Additionally, dry etch equipment tends to be an order of magnitude cheaper than photolithography equipment, so many manufacturers rely on dry etching strategies such as pitch doubling or quartering to gain advanced resolutions (14nm+) while needing less advanced photolithography tools.
High aspect ratio structures
Dry etching is currently used in semiconductor fabrication processes due to its unique ability over wet etch to do
anisotropic etching (removal of material) to create high aspect ratio structures (e.g. deep holes or capacitor trenches).
Hardware design
The dry etching hardware design basically involves a
vacuum chamber
A vacuum chamber is a rigid enclosure from which air and other gases are removed by a vacuum pump. This results in a low-pressure environment within the chamber, commonly referred to as a vacuum. A vacuum environment allows researchers to condu ...
, special gas delivery system,
radio frequency
Radio frequency (RF) is the oscillation rate of an alternating electric current or voltage or of a magnetic, electric or electromagnetic field or mechanical system in the frequency range from around to around . This is roughly between the upp ...
(RF)
waveform generator
A signal generator is one of a class of electronic devices that generates electrical signals with set properties of amplitude, frequency, and wave shape. These generated signals are used as a stimulus for electronic measurements, typically used i ...
to supply power to the plasma, heated chuck to seat the wafer, and an exhaust system.
Design varies from manufacturers such as Tokyo Electronic, Applied Materials, and Lam. While all designs follow the same physical principles, the variety of designs target more specialized processing characteristics. For example, dry etch steps that come into contact with or form critical parts of the device may require higher levels of directionality, selectivity, and uniformity. The tradeoff is that more complex dry etch equipment comes at a higher cost to purchase and is more difficult to understand, more expensive to maintain, and may operate more slowly.
Dry etch equipment can control for process uniformity with several knobs. The chuck temperature can be varied to control the heat of the wafer across the radius of the wafer, which influences the rate of reactions and thus the etch rate across different regions of the wafer. The plasma uniformity can be controlled with plasma confinement, which may be controlled with a high speed magnet rotating around the chamber, variations in gas flow into the chamber and pump out of the chamber, or RF braiding around the chamber. These strategies vary per equipment manufacturer and intended application.
History
Dry etching process was invented by Stephen M. Irving who also invented the
plasma etching process. The anisotropic dry etching process was developed by Hwa-Nien Yu at the
IBM T.J. Watson Research Center in the early 1970s. It was used by Yu with
Robert H. Dennard
Robert Heath Dennard (born September 5, 1932) is an American electrical engineer and inventor.
Biography
Dennard was born in Terrell, Texas, U.S. He received his B.S. and M.S. degrees in Electrical Engineering from Southern Methodist University, ...
to
fabricate the first
micron-scale MOSFET
The metal–oxide–semiconductor field-effect transistor (MOSFET, MOS-FET, or MOS FET) is a type of field-effect transistor (FET), most commonly fabricated by the controlled oxidation of silicon. It has an insulated gate, the voltage of which d ...
s (metal-oxide-semiconductor field-effect transistors) in the 1970s.
See also
*
Plasma etcher
*
Etching (microfabrication)
Etching is used in microfabrication to chemically remove layers from the surface of a wafer during manufacturing. Etching is a critically important process module, and every wafer undergoes many etching steps before it is complete.
For many etch ...
References
{{chem-stub
Semiconductor device fabrication
Microtechnology
Etching_(microfabrication)