astronomy Astronomy () is a natural science that studies astronomical object, celestial objects and phenomena. It uses mathematics, physics, and chemistry in order to explain their origin and chronology of the Universe, evolution. Objects of interest ...

and

atomic physics Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nucleus. Atomic physics typically refers to the study of atomic structure and the interaction between atoms. It is primarily concerned wit ...

, doubly ionized oxygen is the

ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...

O²⁺ (O III in

spectroscopic notation Spectroscopic notation provides a way to specify atomic ionization states, atomic orbitals, and molecular orbitals. Ionization states Spectroscopists customarily refer to the spectrum arising from a given ionization state of a given element by ...

). Its emission

forbidden line In spectroscopy, a forbidden mechanism (forbidden transition or forbidden line) is a spectral line associated with absorption or emission of photons by atomic nuclei, atoms, or molecules which undergo a transition that is not allowed by a particu ...

s in the

visible spectrum The visible spectrum is the portion of the electromagnetic spectrum that is visual perception, visible to the human eye. Electromagnetic radiation in this range of wavelengths is called ''visible light'' or simply light. A typical human eye wil ...

fall primarily at the wavelength 500.7 nm, and secondarily at 495.9 nm. Before spectra of oxygen ions became known, these lines once led to a spurious identification of the substance as a new

chemical element A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...

. Concentrated levels of O III are found in

diffuse Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical p ...

and

planetary nebulae A planetary nebula (PN, plural PNe) is a type of emission nebula consisting of an expanding, glowing shell of ionized gas ejected from red giant stars late in their lives. The term "planetary nebula" is a misnomer because they are unrelated t ...

. Consequently, narrow

band-pass filter A band-pass filter or bandpass filter (BPF) is a device that passes frequencies within a certain range and rejects (attenuates) frequencies outside that range. Description In electronics and signal processing, a filter is usually a two-por ...

s that isolate the 500.7 nm and 495.9 nm wavelengths of light, that correspond to

green Green is the color between cyan and yellow on the visible spectrum. It is evoked by light which has a dominant wavelength of roughly 495570 Nanometre, nm. In subtractive color systems, used in painting and color printing, it is created by ...

turquoise Turquoise is an opaque, blue-to-green mineral that is a hydrated phosphate of copper and aluminium, with the chemical formula . It is rare and valuable in finer grades and has been prized as a gemstone and ornamental stone for thousands of yea ...

cyan Cyan () is the color between green and blue on the visible spectrum of light. It is evoked by light with a predominant wavelength between 490 and 520 nm, between the wavelengths of green and blue. In the subtractive color system, or CMYK color ...

spectral colors A spectral color is a color that is evoked by ''monochromatic light'', i.e. either a single wavelength of light in the visible spectrum, or by a relatively narrow band of wavelengths (e.g. lasers). Every wavelength of visible light is percei ...

, are useful in observing these objects, causing them to appear at higher contrast against the filtered and consequently blacker background of space (and possibly light-polluted terrestrial atmosphere) where the frequencies of IIIare much less pronounced. These

emission line A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to iden ...

s were first discovered in the spectra of

in the 1860s. At that time, they were thought to be due to a new element which was named ''

nebulium Nebulium was a proposed element found in astronomical observation of a nebula by William Huggins in 1864. The strong green emission lines of the Cat's Eye Nebula, discovered using spectroscopy, led to the postulation that an as yet unknown e ...

''. In 1927,

Ira Sprague Bowen Ira Sprague Bowen (December 21, 1898 – February 6, 1973) was an American physicist and astronomer. In 1927 he discovered that nebulium was not really a chemical element but instead doubly ionized oxygen. Life and work Bowen was born in Sen ...

published the current explanation identifying their source as doubly ionized oxygen. Other transitions include the forbidden 88.4 μm and 51.8 μm transitions in the far

infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...

region. Permitted lines of O III lie in the middle

ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than ...

band and are hence inaccessible to terrestrial astronomy.

References

{{Allotropes of oxygen

O III In astronomy and atomic physics, doubly ionized oxygen is the ion O2+ (O III in spectroscopic notation). Its emission forbidden lines in the visible spectrum fall primarily at the wavelength 500.7 nm, and secondarily at 495.9 nm. Befor ...

Oxygen

See also

References