Dorrite is a silicate

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...

that is isostructural to the

aenigmatite Aenigmatite, also known as ''Cossyrite'' after Cossyra, the ancient name of Pantelleria, is a sodium, iron, titanium inosilicate mineral. The chemical formula is Na2Fe2+5TiSi6O20 and its structure consists of single tetrahedral chains with a repe ...

group. It is most chemically similar to the mineral rhönite a₂Mg₅Ti(Al₂Si₄)O₂₀ made distinct by a lack of titanium (Ti) and the presence of Fe³⁺. Dorrite is named for Dr. John (Jack) A. Dorr, a late professor at the

University of Michigan , mottoeng = "Arts, Knowledge, Truth" , former_names = Catholepistemiad, or University of Michigania (1817–1821) , budget = $10.3 billion (2021) , endowment = $17 billion (2021)As o ...

that researched in outcrops where dorrite was found in 1982. This mineral is sub-metallic resembling colors of brownish-black, dark brown, to reddish brown.

Discovery

Dorrite was first reported in 1982 by A. Havette in a basalt-limestone

contact Contact may refer to: Interaction Physical interaction * Contact (geology), a common geological feature * Contact lens or contact, a lens placed on the eye * Contact sport, a sport in which players make contact with other players or objects * ...

on Réunion Island off of the coast of Africa. The second report of dorrite was made by Franklin Foit and his associates while examining a paralava from the Powder River Basin, Wyoming in 1987. Analyses determined that this newly found mineral was surprisingly similar to the mineral rhönite, lacking Ti but presenting dominant Fe³⁺ in its octahedral sites. Other minerals that coexist with this phase are

plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more prope ...

gehlenite Gehlenite, (Ca2Al lSiO7, is a sorosilicate, Al-rich endmember of the melilite complete solid solution series with akermanite.Deer et al., 1993 The type locality is in the Monzoni Mountains, Fassa Valley in Trentino in Italy, and is named after ...

- akermanite,

magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With the ...

-magnesioferrite-spinel solid solutions,

esseneite Esseneite is a relative rare mineral of the pyroxene group, with formula CaFeAlSiO6. It is the ferric-iron-dominant member. Esseneite is an iron-analogue of other pyroxene-group members, davisite, grossmanite, and kushiroite. It is a metamorphic ...

nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites ...

, wollastonite, Ba-rich

feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldsp ...

apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common e ...

, ulvöspinel, ferroan sahamalite, and secondary

barite Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...

, and

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

Occurrence

Dorrite can be found in mineral reactions that relate dorrite +

+ clinopyroxene, rhönite +

olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickl ...

+ clinopyroxene, and

pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...

assemblages in nature. These assemblages favor low pressures and high temperatures. Dorrite is stable in strongly oxidizing, high-temperature, low-pressure environments. It occurs in paralava, pyrometamorphic melt rock, formed from the burning of

coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dea ...

beds.

Crystallography

Researchers conclusively determined that dorrite is triclinic-pseudomonoclinic and twinned by a twofold rotation about the pseudomonoclinic b axis. The parameters for dorrite are a=10.505, b=10.897, c=9.019 Å, α=106.26°, β=95.16°, γ=124.75°.

Chemical Composition

Calcium 8.97%
Magnesium 5.44%
Aluminum 6.04%
Iron 37.48%
Silicon 6.28%
Oxygen 35.79%

Oxides

CaO 12.55%
MgO 9.02%
Al₂O₃ 11.41%
Fe₂O₃ 53.59%
SiO₂ 13.44%

References

{{reflist Natural materials Inosilicates Triclinic minerals