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A dichlorodifluoroethylene (systematically named dichlorodifluoroethene) is one of three
compound Compound may refer to: Architecture and built environments * Compound (enclosure), a cluster of buildings having a shared purpose, usually inside a fence or wall ** Compound (fortification), a version of the above fortified with defensive struct ...
s with the
chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ...
. Dichlorodifluoroethylenes are colourless gases, and are some of the simplest chlorodifluoroalkenes. The
structural isomer In chemistry, a structural isomer (or constitutional isomer in the IUPAC nomenclature) of a chemical compound, compound is another compound whose molecule has the same number of atoms of each element, but with logically distinct chemical bond, b ...
s are used as intermediates or precursors in the production of other industrial chemicals.


1,1-Dichloro-2,2-difluoroethylene

1,1-Dichloro-2,2-difluoroethylene is a low-boiling liquid that is used a
refrigerant A refrigerant is a working fluid used in the heat pump and refrigeration cycle, refrigeration cycle of air conditioning systems and heat pumps where in most cases they undergo a repeated phase transition from a liquid to a gas and back again. Ref ...
. It may also be used as a
solvent A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for ...
, but has practical limitations as such, because of its low boiling point (commercial listings, 19 °C; lit. 17 °C). It is regarded as a
hazardous chemical Dangerous goods, abbreviated DG, are substances that when transported are a risk to health, safety, property or the environment. Certain dangerous goods that pose risks even when not being transported are known as hazardous materials ( syllabi ...
for being toxic by inhalation (see
MSDS A safety data sheet (SDS), material safety data sheet (MSDS), or product safety data sheet (PSDS) is a document that lists information relating to occupational safety and health for the use of various substances and products. SDSs are a widely ...
), and a low-boiling liquid, and it causes irritation when it comes into contact with the skin and mucous membranes. Its
ASHRAE The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE ) is an American professional association seeking to advance heating, ventilation, air conditioning and refrigeration (HVAC&R) systems design and constructio ...
number is R-1112a, and its CAS number is 79-35-6. Concentrated 1,1-dichloro-2,2-difluoroethylene can be ignited with ease in the laboratory.


''cis''- And ''trans''-1,2-dichloro-1,2-difluoroethylene

The diastereomers were co-isolated first in 1965, by using a combination of fractional melting and fractional distillation. The cis isomer's ASHRAE number is R-1112c, and its CAS number is 311-81-9. Its melting point is . The trans isomer's ASHRAE number is R-1112t, and its CAS number is 381-71-5. Its melting point is . The diastereomers are commercially only available as a mixtures of varying proportions.


References

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External links


MSDS
Chlorofluorocarbons Refrigerants