Detonator (1992 Film)
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A detonator, sometimes called a blasting cap in the US, is a small sensitive device used to
provoke Provocation, provoke or provoked may refer to: * Provocation (legal), a type of legal defense in court which claims the "victim" provoked the accused's actions * Agent provocateur, a (generally political) group that tries to goad a desired res ...
a larger, more powerful but relatively insensitive
secondary explosive An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An expl ...
of an
explosive device An explosive device is a device that relies on the exothermic reaction of an explosive material to provide a violent release of energy. Applications of explosive devices include: *Building implosion (demolition) * Excavation *Explosive forming ...
used in commercial mining, excavation,
demolition Demolition (also known as razing, cartage, and wrecking) is the science and engineering in safely and efficiently tearing down of buildings and other artificial structures. Demolition contrasts with deconstruction, which involves taking a ...
, etc. Detonators come in a variety of types, depending on the way they are initiated (chemically, mechanically, or electrically) and details of their inner working, which often involve several stages. They include non-electric caps, electric caps, and fuse caps, the last two being the most common. Electric types are set off by a short burst of current sent to the cap, by a
blasting machine A blasting machine or shot exploder is a portable source of electric current to reliably fire a blasting cap to trigger a main explosive charge. It is mostly used in mining and demolition. The use of the term "machine" dates from early designs ...
via a long wire or a radio controlled source to ensure safety. Traditional fuse caps have a
fuse Fuse or FUSE may refer to: Devices * Fuse (electrical), a device used in electrical systems to protect against excessive current ** Fuse (automotive), a class of fuses for vehicles * Fuse (hydraulic), a device used in hydraulic systems to protect ...
which is ignited by a flame source, such as a match or a lighter. Old detonators used
mercury fulminate Mercury(II) fulminate, or Hg(CNO)2, is a primary explosive. It is highly sensitive to friction, heat and shock and is mainly used as a trigger for other explosives in percussion caps and detonators. Mercury(II) cyanate, though its chemical formula ...
as the
primary explosive An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An expl ...
, often mixed with
potassium chlorate Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In its pure form, it is a white crystalline substance. After sodium chlorate, it is the second most common chlorate in industrial use. It ...
to yield better performance. This compound was superseded by others:
lead azide Lead(II) azide is an inorganic compound. More so than other azides, is explosive. It is used in detonators to initiate secondary explosives. In a commercially usable form, it is a white to buff powder. Preparation and handling Lead(II) azide is ...
,
lead styphnate Lead styphnate (lead 2,4,6- trinitroresorcinate, C6HN3O8Pb ), whose name is derived from styphnic acid, is an explosive used as a component in primer and detonator mixtures for less sensitive secondary explosives. Lead styphnate is only slightly ...
, some
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
, or other materials such as DDNP (
diazo dinitro phenol Diazodinitrophenol (DDNP) was the first diazo compound produced; it was subsequently used to make dyes and explosives. It forms yellow crystals in pure form; however, the color of impure forms may vary from dark yellow to green to dark brown. It ...
) to reduce the amount of lead emitted into the atmosphere by mining and quarrying operations. They also often use a small amount of
TNT Trinitrotoluene (), more commonly known as TNT, more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene, is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagen ...
or
tetryl 2,4,6-Trinitrophenylmethylnitramine commonly referred to as tetryl ( C7 H5 N5 O8) is an explosive compound used to make detonators and explosive booster charges. Tetryl is a nitramine booster explosive, though its use has been largely superseded ...
in military detonators and
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, PENTA, (ПЕНТА, primarily in Russian) TEN, corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythri ...
in commercial detonators.


History

The first blasting cap or detonator was demonstrated in 1745 when British physician and apothecary
William Watson William, Willie, Bill or Billy Watson may refer to: Entertainment * William Watson (songwriter) (1794–1840), English concert hall singer and songwriter * William Watson (poet) (1858–1935), English poet * Billy Watson (actor) (1923–2022), Ame ...
showed that the
electric spark An electric spark is an abrupt electrical discharge that occurs when a sufficiently high electric field creates an ionized, electrically conductive channel through a normally-insulating medium, often air or other gases or gas mixtures. Michael F ...
of a friction machine could ignite black powder, by way of igniting a flammable substance mixed in with the black powder. In 1750,
Benjamin Franklin Benjamin Franklin ( April 17, 1790) was an American polymath who was active as a writer, scientist, inventor, statesman, diplomat, printer, publisher, and political philosopher. Encyclopædia Britannica, Wood, 2021 Among the leading inte ...
in Philadelphia made a commercial blasting cap consisting of a paper tube full of
black powder Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). Th ...
, with wires leading in both sides and wadding sealing up the ends. The two wires came close but did not touch, so a large electric spark discharge between the two wires would fire the cap. In 1832, a hot wire detonator was produced by American chemist Robert Hare, although attempts along similar lines had earlier been attempted by the Italians Volta and Cavallo. Hare constructed his blasting cap by passing a multistrand wire through a charge of gunpowder inside a tin tube; he had cut all but one fine strand of the multistrand wire so that the fine strand would serve as the hot bridgewire. When a strong current from a large battery (which he called a "deflagrator" or "calorimotor") was passed through the fine strand, it became incandescent and ignited the charge of gunpowder. In 1863,
Alfred Nobel Alfred Bernhard Nobel ( , ; 21 October 1833 – 10 December 1896) was a Swedes, Swedish chemist, engineer, inventor, businessman, and Philanthropy, philanthropist. He is best known for having bequeathed his fortune to establish the Nobel ...
realized that although nitroglycerin could not be detonated by a fuse, it could be detonated by the explosion of a small charge of gunpowder, which in turn was ignited by a fuse. Within a year, he was adding
mercury fulminate Mercury(II) fulminate, or Hg(CNO)2, is a primary explosive. It is highly sensitive to friction, heat and shock and is mainly used as a trigger for other explosives in percussion caps and detonators. Mercury(II) cyanate, though its chemical formula ...
to the gunpowder charges of his detonators, and by 1867 he was using small copper capsules of mercury fulminate, triggered by a fuse, to detonate nitroglycerin. In 1868, Henry Julius Smith of Boston introduced a cap that combined a spark gap ignitor and mercury fulminate, the first electric cap able to detonate dynamite. In 1875, Smith—and then in 1887, Perry G. Gardner of North Adams, Massachusetts—developed electric detonators that combined a hot wire detonator with mercury fulminate explosive. These were the first generally modern type blasting caps. Modern caps use different explosives and separate primary and secondary explosive charges, but are generally very similar to the Gardner and Smith caps. Smith also invented the first satisfactory portable power supply for igniting blasting caps: a high-voltage magneto that was driven by a
rack and pinion A rack and pinion is a type of linear actuator that comprises a circular gear (the '' pinion'') engaging a linear gear (the ''rack''). Together, they convert rotational motion into linear motion. Rotating the pinion causes the rack to be driven ...
, which in turn was driven by a T-handle that was pushed downwards. Electric match caps were developed in the early 1900s in Germany, and spread to the US in the 1950s when ICI International purchased Atlas Powder Co. These match caps have become the predominant world standard cap type.


Purpose

The need for detonators such as blasting caps came from the development of safer explosives, that would not explode if accidentally dropped, mishandled, or exposed to fire or electric fields. This required them to have high
activation energy In chemistry and physics, activation energy is the minimum amount of energy that must be provided for compounds to result in a chemical reaction. The activation energy (''E''a) of a reaction is measured in joules per mole (J/mol), kilojoules pe ...
to detonate, and in turn made them correspondingly difficult to detonate intentionally. Then comes the detonator, with its role to provide the required activation energy with a small initiating explosion. As a small device, it is easy to safely store and handle, and, while still hazardous, would do little damage even if it accidentally fired. The detonator and the main explosive device can be kept separated, and only joined just before use, keeping the main charge safe.


Design

A detonator is usually a multi stage device, with three parts: # at the first stage, the initiation mean (fire, electricity, etc.) provide enough energy (as heat or mechanical shock) to activate # an easy-to-ignite
primary explosive An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An expl ...
, which in turn detonates # a small amount of a more powerful
secondary explosive An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An expl ...
, directly in contact with the primary, and called "base" or "output" explosive, able to carry out the detonation through the casing of the detonator to the main explosive device to activate it. Explosives commonly used as primary in detonators include
lead azide Lead(II) azide is an inorganic compound. More so than other azides, is explosive. It is used in detonators to initiate secondary explosives. In a commercially usable form, it is a white to buff powder. Preparation and handling Lead(II) azide is ...
,
lead styphnate Lead styphnate (lead 2,4,6- trinitroresorcinate, C6HN3O8Pb ), whose name is derived from styphnic acid, is an explosive used as a component in primer and detonator mixtures for less sensitive secondary explosives. Lead styphnate is only slightly ...
,
tetryl 2,4,6-Trinitrophenylmethylnitramine commonly referred to as tetryl ( C7 H5 N5 O8) is an explosive compound used to make detonators and explosive booster charges. Tetryl is a nitramine booster explosive, though its use has been largely superseded ...
, and
DDNP Diazodinitrophenol (DDNP) was the first diazo compound produced; it was subsequently used to make dyes and explosives. It forms yellow crystals in pure form; however, the color of impure forms may vary from dark yellow to green to dark brown. It ...
. Early blasting caps also used silver fulminate, but it has been replaced with cheaper and safer primary explosives. Silver azide is still used sometimes, but very rarely due to its high price. As secondary "base" or "output" explosive, you usually find
TNT Trinitrotoluene (), more commonly known as TNT, more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene, is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagen ...
or
tetryl 2,4,6-Trinitrophenylmethylnitramine commonly referred to as tetryl ( C7 H5 N5 O8) is an explosive compound used to make detonators and explosive booster charges. Tetryl is a nitramine booster explosive, though its use has been largely superseded ...
in military detonators and
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, PENTA, (ПЕНТА, primarily in Russian) TEN, corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythri ...
in commercial detonators. While detonators make explosive handling safer, they are hazardous to handle since, despite their small size, they contain enough primary explosive to injure people; untrained personnel might not recognize them as explosives or wrongly deemed them not dangerous due to their appearance and handle them without the required care.


Types

Ordinary detonators usually take the form of ignition-based explosives. While they are mainly used in commercial operations, ordinary detonators are still used in military operations. This form of detonator is most commonly initiated using a
safety fuse The safety fuse is a type of fuse invented and patented by English inventor William Bickford in 1831. Originally it consisted of a "tube" of gunpowder surrounded by a waterproofed varnished jute "rope." It replaced earlier and less reliable metho ...
, and used in non time-critical detonations e.g. conventional munitions disposal. Well known detonators are
lead azide Lead(II) azide is an inorganic compound. More so than other azides, is explosive. It is used in detonators to initiate secondary explosives. In a commercially usable form, it is a white to buff powder. Preparation and handling Lead(II) azide is ...
b(N3)2
silver azide Silver azide is the chemical compound with the formula . It is a silver(I) salt of hydrazoic acid. It forms a colorless crystals. It is a well-known explosive. Structure and chemistry Silver azide can be prepared by treating an aqueous solution ...
gN3and
mercury fulminate Mercury(II) fulminate, or Hg(CNO)2, is a primary explosive. It is highly sensitive to friction, heat and shock and is mainly used as a trigger for other explosives in percussion caps and detonators. Mercury(II) cyanate, though its chemical formula ...
g(ONC)2 There are three categories of electrical detonators: instantaneous electrical detonators (IED), short period delay detonators (SPD) and long period delay detonators (LPD). SPDs are measured in milliseconds and LPDs are measured in seconds. In situations where nanosecond accuracy is required, specifically in the implosion charges in
nuclear weapon A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions ( thermonuclear bomb), producing a nuclear explosion. Both bom ...
s,
exploding-bridgewire detonator The exploding-bridgewire detonator (EBW, also known as exploding wire detonator) is a type of detonator used to initiate the detonation reaction in explosive materials, similar to a blasting cap because it is fired using an electric current. EB ...
s are employed. The initial shock wave is created by vaporizing a length of a thin wire by an
electric discharge An electric discharge is the release and transmission of electricity in an applied electric field through a medium such as a gas (ie., an outgoing flow of electric current through a non-metal medium).American Geophysical Union, National Research C ...
. A new development is a
slapper detonator A slapper detonator, also called exploding foil initiator (EFI), is a relatively recent kind of a detonator developed by Lawrence Livermore National Laboratory, US Patent No. 4,788,913. It is an improvement of the earlier exploding-bridgewire det ...
, which uses thin plates accelerated by an electrically exploded wire or foil to deliver the initial shock. It is in use in some modern weapons systems. A variant of this concept is used in mining operations, when the foil is exploded by a
laser A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The fir ...
pulse delivered to the foil by
optical fiber An optical fiber, or optical fibre in Commonwealth English, is a flexible, transparent fiber made by drawing glass (silica) or plastic to a diameter slightly thicker than that of a human hair. Optical fibers are used most often as a means to ...
. File:Trimming platinum wires at Hercules Port Ewen plant 2012 017 b2f37 gb19f642h.tiff , Trimming platinum wires for use in blasting caps, 1955 File:Dorothy Locke Production of blasting caps 2012 017 b2f37 x346d4806.tiff , Production of blasting caps,
Hercules Powder Company Hercules, Inc. was a chemical and munitions manufacturing company based in Wilmington, Delaware, United States, incorporated in 1912 as the Hercules Powder Company following the breakup of the DuPont explosives monopoly by the U.S. Circuit ...
, 1955 File:Insertion of plug and bridge wire into electric blasting caps 2012 017 b2f37 8623hz26t.tiff , Inserting plug and bridge wire into electric blasting caps, 1955
A non-electric detonator is a shock tube detonator designed to initiate explosions, generally for the purpose of demolition of buildings and for use in the blasting of rock in mines and quarries. Instead of electric wires, a hollow plastic tube delivers the firing impulse to the detonator, making it immune to most of the hazards associated with stray electric current. It consists of a small diameter, three-layer plastic tube coated on the innermost wall with a reactive explosive compound, which, when ignited, propagates a low energy signal, similar to a dust explosion. The reaction travels at approximately 6,500 ft/s (2,000 m/s) along the length of the tubing with minimal disturbance outside of the tube. Non-electric detonators were invented by the Swedish company Nitro Nobel in the 1960s and 1970s, and launched to the demolitions market in 1973. In civil mining, electronic detonators have a better precision for delays. Electronic detonators are designed to provide the precise control necessary to produce accurate and consistent blasting results in a variety of blasting applications in the mining, quarrying, and construction industries. Electronic detonators may be programmed in millisecond or sub-millisecond increments using a dedicated programming device. Wireless electronic detonators are beginning to be available in the civil mining market. Encrypted radio signals are used to communicate the blast signal to each detonator at the correct time. While currently expensive, wireless detonators can enable new mining techniques as multiple blasts can be loaded at once and fired in sequence without putting humans in harm's way. A number 8 test blasting cap is one containing 2 grams of a mixture of 80 percent mercury fulminate and 20 percent potassium chlorate, or a blasting cap of equivalent strength. An equivalent strength cap comprises 0.40-0.45 grams of PETN base charge pressed in an aluminum shell with bottom thickness not to exceed to 0.03 of an inch, to a specific gravity of not less than 1.4 g/cc, and primed with standard weights of primer depending on the manufacture


Blasting caps

The oldest and simplest type of cap, fuse caps are a metal cylinder, closed at one end. From the open end inwards, there is first an empty space into which a pyrotechnic
fuse Fuse or FUSE may refer to: Devices * Fuse (electrical), a device used in electrical systems to protect against excessive current ** Fuse (automotive), a class of fuses for vehicles * Fuse (hydraulic), a device used in hydraulic systems to protect ...
is inserted and crimped, then a pyrotechnic ignition mix, a
primary explosive An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An expl ...
, and then the main detonating explosive charge. The primary hazard of pyrotechnic blasting caps is that for proper usage, the fuse must be inserted and then crimped into place by crushing the base of the cap around the fuse. If the tool used to crimp the cap is used too close to the explosives, the primary explosive compound can detonate during crimping. A common hazardous practice is crimping caps with one's teeth; an accidental detonation can cause serious injury to the mouth. Fuse type blasting caps are still in active use today. They are the safest type to use around certain types of electromagnetic interference, and they have a built in time delay as the fuse burns down. Solid pack electric blasting caps use a thin
bridgewire A bridgewire or bridge wire, also known as a hot bridge wire (HBW), is a relatively thin resistance wire used to set off a pyrotechnic composition serving as pyrotechnic initiator. By passing of electric current it is heated to a high temperature t ...
in direct contact (hence solid pack) with a primary explosive, which is heated by electric current and causes the detonation of the primary explosive. That primary explosive then detonates a larger charge of secondary explosive. Some solid pack fuses incorporate a small pyrotechnic delay element, up to a few hundred milliseconds, before the cap fires. Match type blasting caps use an
electric match An electric match is a device that uses an externally applied electric current to ignite a combustible compound. Electric matches use a bridgewire consisting of a heating element to ignite a pyrogen, which is a quantity of readily ignited pyrotec ...
(insulating sheet with electrodes on both sides, a thin bridgewire soldered across the sides, all dipped in ignition and output mixes) to initiate the primary explosive, rather than direct contact between the bridgewire and the primary explosive. The match can be manufactured separately from the rest of the cap and only assembled at the end of the process. Match type caps are now the most common type found worldwide. The
exploding-bridgewire detonator The exploding-bridgewire detonator (EBW, also known as exploding wire detonator) is a type of detonator used to initiate the detonation reaction in explosive materials, similar to a blasting cap because it is fired using an electric current. EB ...
was invented in the 1940s as part of the
Manhattan Project The Manhattan Project was a research and development undertaking during World War II that produced the first nuclear weapons. It was led by the United States with the support of the United Kingdom and Canada. From 1942 to 1946, the project w ...
to develop nuclear weapons. The design goal was to produce a detonator which acted very rapidly and predictably. Both Match and Solid Pack type electric caps take a few milliseconds to fire, as the bridgewire heats up and heats the explosive to the point of detonation. Explosive bridgewire or EBW detonators use a higher voltage electric charge and a very thin bridgewire, .04 inch long, .0016 diameter, (1 mm long, 0.04 mm diameter). Instead of heating up the explosive, the EBW detonator wire is heated so quickly by the high firing current that the wire actually vaporizes and explodes due to electric resistance heating. That electrically driven explosion then fires the detonator's initiator explosive (usually
PETN Pentaerythritol tetranitrate (PETN), also known as PENT, PENTA, (ПЕНТА, primarily in Russian) TEN, corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythri ...
). Some similar detonators use a thin metal foil instead of a wire, but operate in the same manner as true bridgewire detonators. In addition to firing very quickly when properly activated, EBW detonators are safe from stray static electricity and other electric current. Enough current will melt the bridgewire, but it cannot detonate the initiator explosive without the full high-voltage high-current charge passing through the bridgewire. EBW detonators are used in many civilian applications where radio signals, static electricity, or other electrical hazards might cause accidents with conventional electric detonators.
Slapper detonator A slapper detonator, also called exploding foil initiator (EFI), is a relatively recent kind of a detonator developed by Lawrence Livermore National Laboratory, US Patent No. 4,788,913. It is an improvement of the earlier exploding-bridgewire det ...
s are an improvement on EBW detonators. Slappers, instead of directly using the exploding foil to detonate the initiator explosive, use the electrical vaporization of the foil to drive a small circle of insulating material such as PET film or
kapton Structure of poly-oxydiphenylene-pyromellitimide Kapton insulating pads for mounting electronic parts on a heat sink Kapton is a polyimide film used in flexible printed circuits (flexible electronics) and space blankets, which are used on spac ...
down a circular hole in an additional disc of insulating material. At the far end of that hole is a pellet of conventional initiator explosive. The conversion efficiency of energy from electricity into kinetic energy of the flying disk or slapper can be 20–40%. Since the slapper impacts a wide area—40 thousandths of an inch (roughly one mm) across—of the explosive, rather than a thin line or point as in an exploding foil or bridgewire detonator, the detonation is more regular and requires less energy. Reliable detonation requires raising a minimum volume of explosive to temperatures and pressures at which detonation starts. If energy is deposited at a single point, it can radiate away in the explosive in all directions in rarefaction or expansion waves, and only a small volume is efficiently heated or compressed. The flier disc loses impact energy at its sides to rarefaction waves, but a conical volume of explosive is efficiently shock compressed. Slapper detonators are used in
nuclear weapons A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions (thermonuclear bomb), producing a nuclear explosion. Both bomb ...
. These components require large quantities of energy to initiate, making them extremely unlikely to accidentally discharge. In laser ordnance initiators, a pulse from a
laser A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The fir ...
passes down an
optical fiber An optical fiber, or optical fibre in Commonwealth English, is a flexible, transparent fiber made by drawing glass (silica) or plastic to a diameter slightly thicker than that of a human hair. Optical fibers are used most often as a means to ...
to strike and thus initiate a carbon-doped explosive. These initiators are highly reliable. Unintentional initiation is very difficult as the explosive can only be detonated by the attached laser, which is precisely tuned to do so, or a completely independent laser that matches.


See also

* * * *


References


Further reading

* Cooper, Paul W. ''Explosives Engineering''. New York: Wiley-VCH, 1996. .


External links


1956 safety film "Blasting Cap - Danger!"
from
Prelinger Archives The Prelinger Archives is a collection of films relating to U.S. cultural history, the evolution of the American landscape, everyday life, and social history. It was in New York City from 1982 to 2002 and is now in San Francisco. History The Arc ...

Modelling and Simulation of Burst Phenomenon in Electrically Exploded Foils
{{Authority control Bombs Explosives Pyrotechnic initiators