Desert varnish or rock varnish is an orange-yellow to black coating found on exposed
rock surfaces in
arid
A region is arid when it severely lacks available water, to the extent of hindering or preventing the growth and development of plant and animal life. Regions with arid climates tend to lack vegetation and are called xeric or desertic. Most ...
environments. Desert
varnish
Varnish is a clear transparent hard protective coating or film. It is not a stain. It usually has a yellowish shade from the manufacturing process and materials used, but it may also be pigmented as desired, and is sold commercially in variou ...
is approximately one
micrometer Micrometer can mean:
* Micrometer (device), used for accurate measurements by means of a calibrated screw
* American spelling of micrometre
The micrometre ( international spelling as used by the International Bureau of Weights and Measures; ...
thick and exhibits
nanometer
330px, Different lengths as in respect to the molecular scale.
The nanometre (international spelling as used by the International Bureau of Weights and Measures; SI symbol: nm) or nanometer (American and British English spelling differences#-re, ...
-scale layering. Rock rust and desert patina are other terms which are also used for the condition, but less often.
Formation
Desert varnish forms only on physically stable rock surfaces that are no longer subject to frequent
precipitation
In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls under gravitational pull from clouds. The main forms of precipitation include drizzle, rain, sleet, snow, ice pellets, graupel and hail. ...
, fracturing or
wind abrasion. The varnish is primarily composed of particles of
clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4).
Clays develop plasticity when wet, due to a molecular film of water surrounding the clay pa ...
along with
oxides
An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...
of
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
and
manganese
Manganese is a chemical element with the Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of ...
. There is also a host of trace elements and almost always some
organic matter
Organic matter, organic material, or natural organic matter refers to the large source of carbon-based compounds found within natural and engineered, terrestrial, and aquatic environments. It is matter composed of organic compounds that have c ...
. The color of the varnish varies from shades of brown to black.
It has been suggested that desert varnish should be investigated as a potential candidate for a "
shadow biosphere
A shadow biosphere is a hypothetical microbial biosphere of Earth that would use radically different biochemical and molecular processes from that of currently known life. Although life on Earth is relatively well studied, if a shadow biosphere ex ...
". However, a 2008 microscopy study posited that desert varnish has already been reproduced with chemistry not involving life in the lab, and that the main component is actually silica and not clay as previously thought. The study notes that desert varnish is an excellent fossilizer for microbes and indicator of water. Desert varnish appears to have been observed by rovers on Mars, and if examined may contain fossilized life from Mars's wet period.
Composition
Originally scientists thought that the varnish was made from substances drawn out of the rocks it coats. Microscopic and microchemical observations, however, show that a major part of varnish is clay, which could only arrive by wind. Clay, then, acts as a
substrate to catch additional substances that chemically react together when the rock reaches high temperatures in the
desert
A desert is a barren area of landscape where little precipitation occurs and, consequently, living conditions are hostile for plant and animal life. The lack of vegetation exposes the unprotected surface of the ground to denudation. About on ...
sun. Wetting by
dew is also important in the process.
[
An important characteristic of black desert varnish is that it has an unusually high concentration of ]manganese
Manganese is a chemical element with the Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of ...
. Manganese is relatively rare in the Earth's crust, making up only 0.12% of its weight. In black desert varnish, however, manganese is 50 to 60 times more abundant. One proposal for a mechanism of desert varnish formation is that it is caused by manganese-oxidizing microbe
A microorganism, or microbe,, ''mikros'', "small") and ''organism'' from the el, ὀργανισμός, ''organismós'', "organism"). It is usually written as a single word but is sometimes hyphenated (''micro-organism''), especially in olde ...
s (mixotroph A mixotroph is an organism that can use a mix of different sources of energy and carbon, instead of having a single trophic mode on the continuum from complete autotrophy at one end to heterotrophy at the other. It is estimated that mixotrophs comp ...
s) which are common in environments poor in organic nutrients. A micro-environment pH above 7.5 is inhospitable for manganese-concentrating microbes. In such conditions, orange varnishes develop, poor in manganese (Mn) but rich in iron (Fe). An alternative hypothesis for Mn/Fe fluctuation has been proposed that considers Mn-rich and Fe-rich varnishes to be related to humid and arid climate
The desert climate or arid climate (in the Köppen climate classification ''BWh'' and ''BWk''), is a dry climate sub-type in which there is a severe excess of evaporation over precipitation. The typically bald, rocky, or sandy surfaces in deser ...
s, respectively.
Even though it contains high concentrations of iron and manganese, there are no significant modern uses of desert varnish. However, some Native American peoples created petroglyph
A petroglyph is an image created by removing part of a rock surface by incising, picking, carving, or abrading, as a form of rock art. Outside North America, scholars often use terms such as "carving", "engraving", or other descriptions ...
s by scraping or chipping away the dark varnish to expose the lighter rock beneath.
Desert varnish often obscures the identity of the underlying rock, and different rocks have varying abilities to accept and retain varnish. Limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms w ...
s, for example, typically do not have varnish because they are too water-soluble and therefore do not provide a stable surface for varnish to form. Shiny, dense and black varnishes form on basalt
Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
, fine quartzite
Quartzite is a hard, non- foliated metamorphic rock which was originally pure quartz sandstone.Essentials of Geology, 3rd Edition, Stephen Marshak, p 182 Sandstone is converted into quartzite through heating and pressure usually related to tect ...
s and metamorphosed
Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causin ...
shale
Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
s due to these rocks' relatively high resistance to weathering.
Its presence has been cited as a key factor in the preservation of a large number of petroglyphs dating back to the Iron Age
The Iron Age is the final epoch of the three-age division of the prehistory and protohistory of humanity. It was preceded by the Stone Age (Paleolithic, Mesolithic, Neolithic) and the Bronze Age (Chalcolithic). The concept has been mostly appl ...
and earlier in areas such as the Wadi Saham Wadi Saham is a seasonal watercourse in the Hajar Mountains of Fujairah, in the United Arab Emirates. It is notable for its petroglyphs, including a single rock bearing 26 petroglyphs across four faces.
Petroglyphs and other finds
The Wadi Saham ...
in the United Arab Emirates
The United Arab Emirates (UAE; ar, اَلْإِمَارَات الْعَرَبِيَة الْمُتَحِدَة ), or simply the Emirates ( ar, الِْإمَارَات ), is a country in Western Asia (The Middle East). It is located at th ...
.
See also
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References
External links
Desert Varnish
by Ronald I. Dorn, Professor of Geography Arizona State University
— Space.com
{{Webarchive, url=https://web.archive.org/web/20060825232537/http://archives.cnn.com/2001/TECH/space/07/02/mars.rocks/index.html , date=August 25, 2006
Rock Varnish As A Habitat For Extant Life On Mars
Deposition (geology)
Sedimentology
Deserts
Rocks