Defoliants, Chemical
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A defoliant is any herbicidal chemical sprayed or dusted on plants to cause their
leaves A leaf (plural, : leaves) is any of the principal appendages of a vascular plant plant stem, stem, usually borne laterally aboveground and specialized for photosynthesis. Leaves are collectively called foliage, as in "autumn foliage", wh ...
to fall off. Defoliants are widely used for the selective removal of weeds in managing croplands and lawns. Worldwide use of defoliants, along with the development of other herbicides and
pesticide Pesticides are substances that are meant to control pests. This includes herbicide, insecticide, nematicide, molluscicide, piscicide, avicide, rodenticide, bactericide, insect repellent, animal repellent, microbicide, fungicide, and lampri ...
s, allowed for the Green Revolution, an increase in agricultural production in mid-20th century. Defoliants have also been used in warfare as a means to deprive an enemy of food crops and/or hiding cover, most notably by the United Kingdom during the
Malayan Emergency The Malayan Emergency, also known as the Anti–British National Liberation War was a guerrilla war fought in British Malaya between communist pro-independence fighters of the Malayan National Liberation Army (MNLA) and the military forces o ...
and the United States in the Vietnam War. Defoliants were also used by Indonesian forces in various internal security operations.


Use and application

A primary application of defoliants is the selective killing of plants. Two of the oldest chemical
herbicide Herbicides (, ), also commonly known as weedkillers, are substances used to control undesired plants, also known as weeds.EPA. February 201Pesticides Industry. Sales and Usage 2006 and 2007: Market Estimates. Summary in press releasMain page fo ...
s used as defoliants are 2,4-Dichlorophenoxyacetic acid (2,4-D) and 2,4,5-Trichlorophenoxyacetic acid (2,4,5-T). 2,4-D and 2,4,5-T are absorbed by broad-leafed plants, killing them by causing excessive hormonal growth. These phenoxy herbicides were designed to selectively kill weeds and unwanted plants in croplands. They were first introduced at the beginning of World War II and became widespread in use in agriculture following the end of the War. Defoliants have a practical use in the harvesting of certain crops, particularly cotton, in the United States as well as a number of other cotton-producing countries. The use of defoliants aids in the effective harvesting of cotton and finer lint quality. The effectiveness of defoliant use in cotton harvesting depends on the type of defoliant(s) used, the number of applications, the amount applied, and environmental variables. Common harvest-aiding chemical defoliants include tribufos, dimethipin, and
thidiazuron Thidiazuron (TDZ) is a plant growth regulator. Applications Plant growth regulator The synthesis routes and their use as plant growth regulating agent were patented in the early 1980s by the German company Schering AG. Thidiazuron is taken up by ...
. According to a 1998 report by the U.S. Department of Agriculture
National Agricultural Statistics Service The National Agricultural Statistics Service (NASS) is the statistical branch of the U.S. Department of Agriculture and a principal agency of the U.S. Federal Statistical System. NASS has 12 regional offices throughout the United States and Puer ...
(NASS), tribufos and thidiazuron accounted for 60% of crop area that was treated by defoliants during that crop year.


List of defoliants

In Southeast Asia during the Vietnam War, the Rainbow Herbicides were a group of tactical-use chemicals used by the United States military.


Health and environmental effects

In 1998, the U.S. Environmental Protection Agency (U.S. EPA) concluded that the use of agricultural defoliants led to increased risks of water contamination and dangers to freshwater and
marine life Marine life, sea life, or ocean life is the plants, animals and other organisms that live in the salt water of seas or oceans, or the brackish water of coastal estuaries. At a fundamental level, marine life affects the nature of the planet. M ...
. High doses of tribufos were labeled as a possible carcinogen and a toxin to freshwater and marine invertebrates. Dimethipin has also been labeled as a possible human carcinogen. A published study in the ''Journal of Agricultural and Food Chemistry'' reported that through successive
surface runoff Surface runoff (also known as overland flow) is the flow of water occurring on the ground surface when excess rainwater, stormwater, meltwater, or other sources, can no longer sufficiently rapidly infiltrate in the soil. This can occur when th ...
events in defoliated cotton fields, defoliant concentrations decreased exponentially within the test area and could negatively affect marine life in the runoff zones.
Agent Orange Agent Orange is a chemical herbicide and defoliant, one of the "tactical use" Rainbow Herbicides. It was used by the U.S. military as part of its herbicidal warfare program, Operation Ranch Hand, during the Vietnam War from 1961 to 1971. It ...
, a defoliant used by the United Kingdom during the
Malayan Emergency The Malayan Emergency, also known as the Anti–British National Liberation War was a guerrilla war fought in British Malaya between communist pro-independence fighters of the Malayan National Liberation Army (MNLA) and the military forces o ...
in the 1950s and the United States during the Vietnam War to defoliate regions of Vietnam from 1961 to 1971, has been linked to several long-term health issues. Agent Orange contains a mixture of 2,4-D and 2,4,5-T as well as
dioxin Dioxin may refer to: * 1,2-Dioxin or 1,4-Dioxin, two unsaturated heterocyclic 6-membered rings where two carbon atoms have been replaced by oxygen atoms, giving the molecular formula C4H4O2 *Dibenzo-1,4-dioxin, the parent compound also known as ...
contaminants. Members of the Air Force Ranch Hand and the Army Chemical Corps who served in the Vietnam War were occupationally exposed to
Agent Orange Agent Orange is a chemical herbicide and defoliant, one of the "tactical use" Rainbow Herbicides. It was used by the U.S. military as part of its herbicidal warfare program, Operation Ranch Hand, during the Vietnam War from 1961 to 1971. It ...
have a higher incidence of diabetes, heart disease, hypertension, and chronic respiratory diseases. Among other occupations, farmers are at a significantly higher risk of developing
Alzheimer's disease Alzheimer's disease (AD) is a neurodegeneration, neurodegenerative disease that usually starts slowly and progressively worsens. It is the cause of 60–70% of cases of dementia. The most common early symptom is difficulty in short-term me ...
due to a greater chance of defoliant exposure.


See also

* Rainbow Herbicides *
Crop destruction Crop destruction is the deliberate destruction of crops or agricultural products to render it useless for consumption or processing. It can be made by burning, grinding, dumping into water, or application of chemicals. It should not be confused w ...
* Index of environmental articles


References


External links


Defoliants and Desiccants
by Frederick M Fishel, Pesticide Information Office,
Institute of Food and Agricultural Sciences The University of Florida Institute of Food and Agricultural Sciences (UF/IFAS) is a teaching, research and Extension scientific organization focused on agriculture and natural resources. It is a partnership of federal, state, and county governmen ...
, University of Florida {{Authority control Environmental science Environmental chemistry Soil science Herbicides Pesticides