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1,5-Dithiacyclooctane (DTCO) is an organosulfur compound with the formula (CHCH)CHS). This cyclic di
DTCO was first prepared in 4% yield by di
thioether
In organic chemistry, an organic sulfide (British English sulphide) or thioether is an organosulfur functional group with the connectivity as shown on right. Like many other sulfur-containing compounds, volatile sulfides have foul odors. A su ...
is a colorless oil that is soluble in polar solvents. It forms a variety of transition metal thioether complex
Transition metal thioether complexes comprise coordination complexes of thioether (R2S) ligands. The inventory is extensive.
Dimethylsulfide complexes
As the simplest thioether, dimethyl sulfide forms complexes that are illustrative of the class ...
es.
DTO can be oxidized to the bicyclic dication.
DTCO was first prepared in 4% yield by dialkylation
Alkylation is the transfer of an alkyl group from one molecule to another. The alkyl group may be transferred as an alkyl carbocation, a free radical, a carbanion, or a carbene (or their equivalents). Alkylating agents are reagents for effecti ...
of 1,3-propanedithiol
1,3-Propanedithiol is the chemical compound with the formula HSCH2CH2CH2SH. This dithiol is a useful reagent in organic synthesis. This liquid, which is readily available commercially, has an intense stench.
Use in organic synthesis
1,3-Propan ...
with 1,3-dibromopropane.
References
{{DEFAULTSORT:Dithiacyclooctane, 1, 5- Thioethers Chelating agents Sulfur heterocycles Heterocyclic compounds with 1 ring