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In physics, the term clusters denotes small, polyatomic particles. As a rule of thumb, any particle made of between 3×100 and 3×107 atoms is considered a cluster. The term can also refer to the organization of protons and neutrons within an atomic nucleus, e.g. the
alpha particle Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be produce ...
(also known as "α-cluster"Extreme α-clustering in the 18O nucleus.
/ref>), consisting of two protons and two neutrons (as in a helium nucleus).


Overview

Although first reports of cluster species date back to the 1940s, cluster science emerged as a separate direction of research in the 1980s, One purpose of the research was to study the gradual development of collective phenomena which characterize a bulk solid. For example, these are the color of a body, its electrical conductivity, its ability to absorb or reflect light, and magnetic phenomena such as ferro-, ferri-, or antiferromagnetism. These are typical collective phenomena which only develop in an aggregate of a large number of atoms. It was found that collective phenomena break down for very small cluster sizes. It turned out, for example, that small clusters of a ferromagnetic material are super-paramagnetic rather than ferromagnetic.
Paramagnetism Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, ...
is not a collective phenomenon, which means that the ferromagnetism of the macrostate was not conserved by going into the nanostate. The question then was asked for example, “How many atoms do we need in order to obtain the collective metallic or magnetic properties of a solid?” Soon after the first cluster sources had been developed in 1980, an ever larger community of cluster scientists was involved in such studies. This development led to the discovery of fullerenes in 1986 and
carbon nanotubes A scanning tunneling microscopy image of a single-walled carbon nanotube Rotating single-walled zigzag carbon nanotube A carbon nanotube (CNT) is a tube made of carbon with diameters typically measured in nanometers. ''Single-wall carbon nan ...
a few years later. In science, a lot is known about properties of the
gas Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...
phase; however, comparatively little is known about the
condense Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to ...
d phases (the liquid phase and solid phase.) The study of clusters attempts to bridge this gap of knowledge by clustering
atoms Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, and ...
together and studying their characteristics. If enough atoms were clustered together, eventually one would obtain a liquid or solid. The study of atomic and molecular clusters also benefits the developing field of nanotechnology. If new materials are to be made out of nanoscale particles, such as
nanocatalyst Nanomaterial-based catalysts are usually heterogeneous catalysts broken up into metal nanoparticles in order to enhance the catalytic process. Metal nanoparticles have high surface area, which can increase catalytic activity. Nanoparticle catalysts ...
s and quantum computers, the properties of the nanoscale particles (the clusters) must first be understood.


See also

* Cluster chemistry * Nanoparticle *
Nanocluster Nanoclusters are atomically precise, crystalline materials most often existing on the 0-2 nanometer scale. They are often considered kinetically stable intermediates that form during the synthesis of comparatively larger materials such as semico ...


References


External links


Scientific community portal
for clusters, fullerenes, nanotubes, nanostructures, and similar small systems. Nanomaterials {{nano-tech-stub