Chromium(IV) Fluoride
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Chromium(IV) fluoride is an
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
with the
chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ...
CrF4. It has a dark greenish-black color when solid. It rapidly hydrolysizes in presence of moisture in air or directly in water.


Synthesis

Powdered
chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hardne ...
or CrCl3 is exposed to
fluorine Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reacti ...
gas at a temperature of 350-500 °C, which creates a mix of CrF4 and CrF5. The CrF4 settles out as varnish-like brown beads upon cooling.


Reactions

Chromium(IV) fluoride will react with water: :CrF4 + 2H2O -> CrO2 + 4HF


References

Chromium–halogen compounds Fluorides Fluorine compounds Metal halides Chromium(IV) compounds {{Inorganic-compound-stub