A chemical depilatory is a
cosmetic preparation used to
remove hair from the
skin
Skin is the layer of usually soft, flexible outer tissue covering the body of a vertebrate animal, with three main functions: protection, regulation, and sensation.
Other animal coverings, such as the arthropod exoskeleton, have different d ...
. Common active ingredients are salts of
thioglycolic acid and
thiolactic acids. These compounds break the
disulfide bond
In biochemistry, a disulfide (or disulphide in British English) refers to a functional group with the structure . The linkage is also called an SS-bond or sometimes a disulfide bridge and is usually derived by the coupling of two thiol groups. In ...
s in
keratin
Keratin () is one of a family of structural fibrous proteins also known as ''scleroproteins''. Alpha-keratin (α-keratin) is a type of keratin found in vertebrates. It is the key structural material making up scales, hair, nails, feathers, ...
and also
hydrolyze
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile.
Biological hydrolysis ...
the hair so that it is easily removed. Formerly,
sulfide
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...
s such as
strontium sulfide were used, but due to their unpleasant odor, they have been replaced by
thiol
In organic chemistry, a thiol (; ), or thiol derivative, is any organosulfur compound of the form , where R represents an alkyl or other organic substituent. The functional group itself is referred to as either a thiol group or a sulfhydryl grou ...
s.
The main chemical reaction effected by the thioglycolate is:
:
Chemical depilatories contain 5–6%
calcium thioglycolate in a
cream
Cream is a dairy product composed of the higher-fat layer skimmed from the top of milk before homogenization. In un-homogenized milk, the fat, which is less dense, eventually rises to the top. In the industrial production of cream, this process ...
base (to avoid runoff).
Calcium hydroxide
Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca( OH)2. It is a colorless crystal or white powder and is produced when quicklime ( calcium oxide) is mixed or slaked with water. It has ...
or
strontium hydroxide
Strontium hydroxide, Sr(OH)2, is a caustic alkali composed of one strontium ion and two hydroxide ions. It is synthesized by combining a strontium salt with a strong base. Sr(OH)2 exists in anhydrous, monohydrate, or octahydrate form.
Preparatio ...
maintain a pH of about 12. Hair destruction requires about 10 minutes. Depilation is followed by careful rinsing with water, and various conditioners are applied to restore the skin's pH to normal. Depilation does not destroy the
dermal papilla, and the hair grows back.
Chemical depilatories are available in
gel,
cream
Cream is a dairy product composed of the higher-fat layer skimmed from the top of milk before homogenization. In un-homogenized milk, the fat, which is less dense, eventually rises to the top. In the industrial production of cream, this process ...
,
lotion
Lotion is a low-viscosity topical preparation intended for application to the skin. By contrast, creams and gels have higher viscosity, typically due to lower water content. Lotions are applied to external skin with bare hands, a brush, a clean ...
,
aerosol
An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthr ...
, roll-on, and
powder
A powder is a dry, bulk solid composed of many very fine particles that may flow freely when shaken or tilted. Powders are a special sub-class of granular materials, although the terms ''powder'' and '' granular'' are sometimes used to disti ...
forms. Common brands include
Nair
The Nair , also known as Nayar, are a group of Indian Hindu castes, described by anthropologist Kathleen Gough as "not a unitary group but a named category of castes". The Nair include several castes and many subdivisions, not all of whom histo ...
,
Magic Shave, and
Veet.
Chemical depilatories are indicated in the treatment of hirsutism in
polycystic ovary syndrome
Polycystic ovary syndrome, or PCOS, is the most common endocrine disorder in women of reproductive age. The syndrome is named after the characteristic cysts which may form on the ovaries, though it is important to note that this is a sign and no ...
.
Depilatory ointments, or plasters, were known to Greek and Roman authors as ''psilothrum''. In Jewish lore,
King Solomon
King is the title given to a male monarch in a variety of contexts. The female equivalent is queen, which title is also given to the consort of a king.
*In the context of prehistory, antiquity and contemporary indigenous peoples, the ti ...
is said to have discovered a chemical depilatory made from a mixture of lime and water and
orpiment
Orpiment is a deep-colored, orange-yellow arsenic sulfide mineral with formula . It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and is formed both by sublimation and as a byproduct of the decay of another a ...
(
arsenic trisulfide).
[ Colloquy of the Queen of Sheba, taken from the Aramaic ''Targum Sheni of Megillat Esther''.]
References
{{DEFAULTSORT:Chemical Depilatory
Hair removal