Carroll Chatham
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Carroll Chatham (1914–1983) was an American chemist who developed the flux method for synthesizing
emerald Emerald is a gemstone and a variety of the mineral beryl (Be3Al2(SiO3)6) colored green by trace amounts of chromium or sometimes vanadium.Hurlbut, Cornelius S. Jr. and Kammerling, Robert C. (1991) ''Gemology'', John Wiley & Sons, New York, p ...
s. He was the first person to develop a method for creating man-made emeralds that was able to make them commercially available. He founded the jewelry company Chatham which is still selling Chatham emeralds to this day.


Early life

Carroll Chatham grew up in San Francisco, California and he developed an interest in
gemology Gemology or gemmology is the science dealing with natural and artificial gemstone materials. It is a geoscience and a branch of mineralogy. Some jewelers (and many non-jewelers) are academically trained gemologists and are qualified to identify a ...
at an early age. As a teenager, he was already experimenting in his garage. His goal was to synthesize diamonds but after an explosion during one of these attempts, which caused his father to make Chatham change his experiments. This change led him to attempt to synthesize emeralds instead, but this included the challenge of there not being a known method for developing emeralds like the flame fusion method used for creating rubies and sapphires. His first successful experiment was the development of a colorless gem in 1930. This gem was made of beryl, which is a significant development since emeralds are a part of the beryl family. Only 5 years later Chatham synthesized a 1-carat emerald.


Career

Chatham attended the
California Institute of Technology The California Institute of Technology (branded as Caltech or CIT)The university itself only spells its short form as "Caltech"; the institution considers other spellings such a"Cal Tech" and "CalTech" incorrect. The institute is also occasional ...
and received a chemistry degree in 1938. After graduating he spent a few years in the industry before owning his own laboratory. This laboratory is where he continued to work on developing his synthetic gems. Using this lab, he was able to create the first commercially marketable emerald. These Chatham emeralds are still sold to this day and because of his flux method, they do not have the inclusions or fractures that are common in natural emeralds. He then built up his Chatham jewelry company and continued to develop more synthetic gems. These gems include rubies and sapphires.


Legacy

Chatham was not the first person to make man-made gems, but he was the first to create emeralds. Before him, both
rubies A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sap ...
and
sapphire Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sapphir ...
s were created using the
Verneuil method The Verneuil method (or Verneuil process or Verneuil technique), also called flame fusion, was the first commercially successful method of manufacturing synthetic gemstones, developed in the late 1883 by the French chemist Auguste Verneuil. It ...
, developed by French chemist Auguste Victor Louis Verneuil. This method involves melting aluminum oxide at high temperatures, adding colors so that they take on the colors of the natural gems, and then allowing them to cool so that form the natural
crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pat ...
. This is a well-known process that is in stark contrast to Chatham's
flux method The flux method of crystal growth is a method where the components of the desired substance are dissolved in a solvent (flux). The method is particularly suitable for crystals needing to be free from thermal strain. It takes place in a crucible ma ...
. He guarded his flux recipe carefully since it was the key to the emeralds forming properly. This is because before he discovered the flux method, it was not possible to make synthetic emeralds because the different materials had different
melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends ...
s which caused them to not combine in order to form the gem. This method involves beryl
seed crystal A seed crystal is a small piece of single crystal or polycrystal material from which a large crystal of typically the same material is grown in a laboratory. Used to replicate material, the use of seed crystal to promote growth avoids the otherwi ...
s being suspended in the flux solution while it crystalizes into the full gem. This is not a quick process and can take a year for the crystals to grow to a point where they become marketable. Carroll Chatham died in 1983 but before his death, his sons Tom and John Chatham took over running the company. John took over the laboratory and manufacturing side of the company while Tom works on the marketing end. They continue the work that their father started as a boy and after Carroll's death, the Chatham company developed its first synthetic diamond which was Carroll's dream since he was a boy that caused an explosion in his garage lab.


References

{{DEFAULTSORT:Chatham, Carroll Wikipedia Student Program 1914 births 1983 deaths 20th-century American chemists People from San Francisco Place of birth missing Chemists from California California Institute of Technology alumni