Carbide Lamp
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Carbide lamps, or acetylene gas lamps, are simple lamps that produce and burn acetylene (C2H2) which is created by the reaction of
calcium carbide Calcium carbide, also known as calcium acetylide, is a chemical compound with the chemical formula of Ca C2. Its main use industrially is in the production of acetylene and calcium cyanamide. The pure material is colorless, while pieces of te ...
(CaC2) with
water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a ...
(H2O). Acetylene gas lamps were used to illuminate buildings, as
lighthouse A lighthouse is a tower, building, or other type of physical structure designed to emit light from a system of lamps and lenses and to serve as a beacon for navigational aid, for maritime pilots at sea or on inland waterways. Lighthouses mar ...
beacons, and as headlights on motor-cars and bicycles. Portable acetylene gas lamps, worn on the hat or carried by hand, were widely used in mining in the early twentieth century. They are still employed by
caver Caving – also known as spelunking in the United States and Canada and potholing in the United Kingdom and Ireland – is the recreational pastime of exploring wild cave systems (as distinguished from show caves). In contrast, speleology is ...
s, hunters, and
cataphile Cataphiles are urban explorers who illegally tour the Mines of Paris, a term popularly used to describe a series of tunnels that were built as a network of stone mines, which are no longer used. The Catacombs of Paris comprise a subset of this ne ...
s. Small carbide lamps called "carbide candles" or "smokers" are used for blackening rifle sights to reduce glare. They are sometimes referred to as "smokers" because of the
soot Soot ( ) is a mass of impure carbon particles resulting from the incomplete combustion of hydrocarbons. It is more properly restricted to the product of the gas-phase combustion process but is commonly extended to include the residual pyrolysed ...
y flame produced by acetylene.


Mechanism

A mining or caving lamp has
calcium carbide Calcium carbide, also known as calcium acetylide, is a chemical compound with the chemical formula of Ca C2. Its main use industrially is in the production of acetylene and calcium cyanamide. The pure material is colorless, while pieces of te ...
placed in a lower chamber, the generator. The upper reservoir is then filled with water. A threaded valve or other mechanism is used to control the rate at which the water is allowed to drip into the chamber containing the calcium carbide. By controlling the rate of water flow, the production of acetylene gas is controlled. This, in turn, controls the flow rate of the gas and the size of the flame at the burner, and thus the amount of light it produces. This type of lamp generally has a reflector behind the flame to help project the light forward. An acetylene gas powered lamp produces a bright, broad light. Many cavers prefer this type of unfocused light as it improves peripheral vision in the complete dark. The reaction of carbide with water is exothermic and produces a fair amount of heat independent of the flame. In cold caves, carbide lamp users can use this heat to help stave off hypothermia.


Chemical reactions

Acetylene is produced by the reaction: : CaC2( s) + 2H2O( l)C2H2( g) + Ca(OH)2( aq) The acetylene combusts easily in the
atmosphere An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A s ...
: : 2 C2H2 + 5O2 → 4CO2 + 2H2O + Δ''H'' = −1300 kJ/mol When all of the carbide in a lamp has been reacted, the carbide chamber contains a wet paste of slaked lime ( Ca(OH)2) which can be used to make a
cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mix ...
. This is emptied into a waste bag and the chamber can be refilled.


History

In 1892,
Thomas Willson Thomas Leopold "Carbide" Willson (March 14, 1860 – December 20, 1915) was a Canadian inventor. He was born on a farm near Princeton, Ontario, in 1860 and went to school in Hamilton, Ontario. By the age of 21, he had designed and patented ...
discovered an economically efficient process for creating calcium carbide in an
electric arc furnace An electric arc furnace (EAF) is a furnace that heats material by means of an electric arc. Industrial arc furnaces range in size from small units of approximately one-tonne capacity (used in foundries for producing cast iron products) up to ab ...
from a mixture of lime and coke. The arc furnace provides the high temperature required to drive the reaction. Manufacture of calcium carbide was an important part of the industrial revolution in chemistry, and was made possible in the United States as a result of massive amounts of inexpensive hydroelectric power produced at
Niagara Falls Niagara Falls () is a group of three waterfalls at the southern end of Niagara Gorge, spanning the border between the province of Ontario in Canada and the state of New York in the United States. The largest of the three is Horseshoe Falls, ...
before the turn of the twentieth century. In 1895, Willson sold his patent to
Union Carbide Union Carbide Corporation is an American chemical corporation wholly owned subsidiary (since February 6, 2001) by Dow Chemical Company. Union Carbide produces chemicals and polymers that undergo one or more further conversions by customers befo ...
. Domestic lighting with acetylene gas was introduced circa 1894 and bicycle lamps from 1896. In France,
Gustave Trouvé Gustave Pierre Trouvé (2 January 1839 – 27 July 1902) was a French electrical engineer and inventor in the 19th century. Trouvé was born on 2 January 1839 in La Haye-Descartes (Indre-et-Loire, France) and died on 27 July 1902 in Paris. A pol ...
, a Parisian electrical engineer, also made domestic acetylene lamps and
gasometers A gas holder or gasholder, also known as a gasometer, is a large container in which natural gas or town gas is stored near atmospheric pressure at ambient temperatures. The volume of the container follows the quantity of stored gas, with pressu ...
. The first carbide bicycle lamp developed in the United States was
patent A patent is a type of intellectual property that gives its owner the legal right to exclude others from making, using, or selling an invention for a limited period of time in exchange for publishing an enabling disclosure of the invention."A p ...
ed in New York on August 28, 1900 by Frederick Baldwin. Another early lamp design is shown in a
patent A patent is a type of intellectual property that gives its owner the legal right to exclude others from making, using, or selling an invention for a limited period of time in exchange for publishing an enabling disclosure of the invention."A p ...
from
Duluth, Minnesota , settlement_type = City , nicknames = Twin Ports (with Superior), Zenith City , motto = , image_skyline = , image_caption = Clockwise from top: urban Duluth skyline; Minnesota ...
from October 21, 1902. In the early 1900s,
Gustaf Dalén Nils Gustaf Dalén (; 30 November 1869 – 9 December 1937) was a Swedish Nobel Laureate and industrialist, engineer, inventor and long-term CEO of the AGA AB, AGA company and inventor of the AGA cooker and the Dalén light. In 1912 he was award ...
invented the
Dalén light A Dalén light is a light produced from burning of carbide gas (acetylene), combined with a solar sensor which automatically operates the light only during darkness. Overview The technology was the predominant form of light source in lighthouse ...
. This combined two of Dalén's previous inventions: the substrate
Agamassan Agamassan is a porous substrate used to safely absorb acetylene and thus allow the transport, storage and commercial use of the otherwise unstable gas. It was developed and patented by the Swedish Nobel Laureate and industrialist Gustaf Dalén. ...
and the Sun valve. Inventions and improvements to carbide lamps continued for decades. After carbide lamp open flames were implicated in an Illinois coal-seam methane gas explosion that killed 54 miners, the 1932 Moweaqua Coal Mine disaster, carbide lamp use declined in United States coal mines. They continued to be used in the coal pits of other countries, notably
USSR The Soviet Union,. officially the Union of Soviet Socialist Republics. (USSR),. was a transcontinental country that spanned much of Eurasia from 1922 to 1991. A flagship communist state, it was nominally a federal union of fifteen nationa ...
. In the birth of the
cinema of Iquitos The cinema of Iquitos, also known as Amazonian cinema, is an important film development and one of the historic pioneering event of cinema of Peru. Due to the rubber boom and the arrival of foreigners, film interest began in the early 20th centur ...
, a carbide lamp was used as light support to
project A project is any undertaking, carried out individually or collaboratively and possibly involving research or design, that is carefully planned to achieve a particular goal. An alternative view sees a project managerially as a sequence of even ...
the first film in the Casa de Fierro, in 1900.


Lighting systems

Carbide lighting was used in rural and urban areas of the United States which were not served by
electrification Electrification is the process of powering by electricity and, in many contexts, the introduction of such power by changing over from an earlier power source. The broad meaning of the term, such as in the history of technology, economic histor ...
. Its use began shortly after 1900 and continued past 1950.
Calcium carbide Calcium carbide, also known as calcium acetylide, is a chemical compound with the chemical formula of Ca C2. Its main use industrially is in the production of acetylene and calcium cyanamide. The pure material is colorless, while pieces of te ...
pellets were placed in a container outside the home, with water piped to the container and allowed to drip on the pellets releasing acetylene. This gas was piped to lighting fixtures inside the house, where it was burned, creating a very bright flame. Carbide lighting was inexpensive but was prone to
gas leak A gas leak refers to a leak of natural gas or another gaseous product from a pipeline or other containment into any area where the gas should not be present. Gas leaks can be hazardous to health as well as the environment. Even a small leak in ...
s and explosions. Early models of the automobile, car, motorbike and bicycle used carbide lamps as
headlamp A headlamp is a lamp attached to the front of a vehicle to illuminate the road ahead. Headlamps are also often called headlights, but in the most precise usage, ''headlamp'' is the term for the device itself and ''headlight'' is the term for ...
s. Acetylene gas, derived from carbide, enabled early automobiles to drive safely at night. Thick concave mirrors combined with magnifying lenses projected the acetylene flame light. These type of lights were used until reliable batteries and dynamos became available, and manufacturers switched to electric lights. Acetylene lamps were also used on riverboats for night navigation. The
National Museum of Australia The National Museum of Australia, in the national capital Canberra, preserves and interprets Australia's social history, exploring the key issues, people and events that have shaped the nation. It was formally established by the ''National Muse ...
has a lamp made in about 1910 that was used on board , a
paddle steamer A paddle steamer is a steamship or steamboat powered by a steam engine that drives paddle wheels to propel the craft through the water. In antiquity, paddle wheelers followed the development of poles, oars and sails, where the first uses wer ...
which has been restored to working order and also in the museum's collection. They are also used for
night hunting "Night hunting", known in Bhutan as ''Bomena'', is a traditional "courtship" custom that is practiced in some parts of Bhutan. Similar customs have also existed in other cultures, namely in Japan. Practice "Night hunting", the traditional cult ...
.


Use in caving

Early
caving Caving – also known as spelunking in the United States and Canada and potholing in the United Kingdom and Ireland – is the recreational pastime of exploring wild cave systems (as distinguished from show caves). In contrast, speleology i ...
enthusiasts, not yet having the advantage of light-weight electrical illumination, introduced the carbide lamp to their hobby. While increasingly replaced by more modern choices, a substantial percentage of cavers still use this method. Many cavers favour carbide lamps for their durability and quality of illumination. They were once favoured for their relative illumination per mass of fuel compared to battery powered devices. Before the advent of high-intensity
LED A light-emitting diode (LED) is a semiconductor Electronics, device that Light#Light sources, emits light when Electric current, current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy i ...
illumination with lithium ion batteries, carbide also had two important advantages over the alternative of miners electric lamps. Miners lamps were intended to last for the duration of a standard working shift, whilst major caving explorations could be much longer, so the carbide could be replenished during the trip. Expeditions involving camping over several days in remote regions might not have access to electricity for recharging. Lamps used in such circumstances would consist of a belt mounted gas generator linked by flexible pipe to a headset. The acetylene producing reaction is exothermic, which means that the lamp's reactor vessel will become quite warm to the touch; this can be used to warm the hands. The heat from the flame can also be used to warm the body by allowing the exhaust gases to flow under a shirt or poncho pulled out from the body, a technique discovered almost immediately by cold miners, and nicknamed by cavers the "Palmer furnace". The lamps are sometimes called "stinkies" because of their odour.


See also

*
Dalén light A Dalén light is a light produced from burning of carbide gas (acetylene), combined with a solar sensor which automatically operates the light only during darkness. Overview The technology was the predominant form of light source in lighthouse ...
* Flashlight * Headlamps (Lamps worn affixed to the head) * Trouble light


Notes


References

* * * *


External links


acethylene.com
A comprehensive guide to the care and maintenance of acetylene gas lamps
A User's Guide to Carbide Cap Lamps.
Has many good pictures & videos.
Carbide lamp
Demonstration experiment: Instruction and video
The Carbide Caver
A website on the history, restoration, and use of carbide lamps for caving. {{Authority control Types of lamp Caving equipment Gas technologies Industrial gases Synthetic fuel technologies