Cuprous Nitrate
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Copper(I) nitrate is a proposed
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
with formula of CuNO3. It has not been characterized by
X-ray crystallography X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles ...
. It is the focus of one publication, which describes unsuccessful efforts to isolate the compound. Another nonexistent simple copper(I) compound derived from an oxyanion is cuprous perchlorate. On the other hand, cuprous sulfate is known.


Derivatives

The nitrate salt of the
acetonitrile complex Transition metal nitrile complexes are coordination compounds containing nitrile ligands. Because nitriles are weakly basic, the nitrile ligands in these complexes are often labile. Scope of nitriles Typical nitrile ligands are acetonitrile, prop ...
, i.e., u(MeCN)4O3, is generated by the reaction of silver nitrate with a suspension of copper metal in acetonitrile. :Cu + AgNO3 + 4 CH3CN → u(CH3CN)4/sub>NO3 + Ag Tertiary phosphine complexes of the type u(P(C6H5)3)3O3 are prepared by the reduction of
copper(II) nitrate Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu( NO3)2(H2O)x. The hydrates are blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 °C. Common hy ...
by the phosphine.


References

Copper(I) compounds {{inorganic-compound-stub