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For a given temperature, the critical field refers to the maximum magnetic field strength below which a material remains superconducting.
Superconductivity Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike ...
is characterized both by perfect conductivity (zero resistance) and by the complete expulsion of magnetic fields (the
Meissner effect The Meissner effect (or Meissner–Ochsenfeld effect) is the expulsion of a magnetic field from a superconductor during its transition to the superconducting state when it is cooled below the critical temperature. This expulsion will repel a n ...
). Changes in either temperature or
magnetic flux density A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
can cause the
phase transition In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of ...
between normal and superconducting states.High Temperature Superconductivity, Jeffrey W. Lynn Editor, Springer-Verlag (1990) The highest temperature under which the superconducting state is seen is known as the critical temperature. At that temperature even the weakest external magnetic field will destroy the superconducting state, so the strength of the critical field is zero. As temperature decreases, the critical field increases generally to a maximum at absolute zero. For a
type-I superconductor The interior of a bulk superconductor cannot be penetrated by a weak magnetic field, a phenomenon known as the Meissner effect. When the applied magnetic field becomes too large, superconductivity breaks down. Superconductors can be divided int ...
the discontinuity in heat capacity seen at the superconducting transition is generally related to the slope of the critical field (H_\text) at the critical temperature (T_\text):Superconductivity of Metals and Alloys, P. G. de Gennes, Addison-Wesley (1989) :C_\text - C_\text = \left(\frac\right)^2_ There is also a direct relation between the critical field and the critical current – the maximum electric current density that a given superconducting material can carry, before switching into the normal state. According to Ampère's law any electric current induces a magnetic field, but superconductors exclude that field. On a microscopic scale, the magnetic field is not quite zero at the edges of any given sample – a
penetration depth Penetration depth is a measure of how deep light or any electromagnetic radiation can penetrate into a material. It is defined as the depth at which the intensity of the radiation inside the material falls to 1/e (about 37%) of its original valu ...
applies. For a type-I superconductor, the current must remain zero within the superconducting material (to be compatible with zero magnetic field), but can then go to non-zero values at the edges of the material on this penetration-depth length-scale, as the magnetic field rises. As long as the induced magnetic field at the edges is less than the critical field, the material remains superconducting, but at higher currents, the field becomes too strong and the superconducting state is lost. This limit on current density has important practical implications in applications of superconducting materials – despite zero resistance they cannot carry unlimited quantities of electric power. The geometry of the superconducting sample complicates the practical measurement of the critical field – the critical field is defined for a cylindrical sample with the field parallel to the axis of radial symmetry. With other shapes (spherical, for example), there may be a mixed state with partial penetration of the exterior surface by the magnetic field (and thus partial normal state), while the interior of the sample remains superconducting.
Type-II superconductor In superconductivity, a type-II superconductor is a superconductor that exhibits an intermediate phase of mixed ordinary and superconducting properties at intermediate temperature and fields above the superconducting phases. It also features the ...
s allow a different sort of mixed state, where the magnetic field (above the lower critical field H_) is allowed to penetrate along cylindrical "holes" through the material, each of which carries a
magnetic flux quantum The magnetic flux, represented by the symbol , threading some contour or loop is defined as the magnetic field multiplied by the loop area , i.e. . Both and can be arbitrary, meaning can be as well. However, if one deals with the superconducti ...
. Along these flux cylinders, the material is essentially in a normal, non-superconducting state, surrounded by a superconductor where the magnetic field goes back to zero. The width of each cylinder is on the order of the penetration depth for the material. As the magnetic field increases, the flux cylinders move closer together, and eventually at the upper critical field H_\text, they leave no room for the superconducting state and the zero-resistivity property is lost.


Upper critical field

The upper critical field is the
magnetic flux density A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
(usually expressed with the unit tesla (T)) that completely suppresses superconductivity in a type-II superconductor at 0 K (
absolute zero Absolute zero is the lowest limit of the thermodynamic temperature scale, a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value, taken as zero kelvin. The fundamental particles of nature have minimum vibration ...
). More properly, the upper critical field is a function of temperature (and pressure) and if these are not specified, absolute zero and standard pressure are implied.
Werthamer–Helfand–Hohenberg theory This theory was proposed in 1966 to go beyond BCS theory of superconductivity and it provides predictions A prediction (Latin ''præ-'', "before," and ''dicere'', "to say"), or forecast, is a statement about a future event or data. They are ...
predicts the upper critical field () at 0 K from and the slope of at . The upper critical field (at 0 K) can also be estimated from the
coherence length In physics, coherence length is the propagation distance over which a coherent wave (e.g. an electromagnetic wave) maintains a specified degree of coherence. Wave interference is strong when the paths taken by all of the interfering waves differ ...
() using the Ginzburg–Landau expression: .
Introduction to Solid State Physics ''Introduction to Solid State Physics'', known colloquially as ''Kittel'', is a classic condensed matter physics textbook written by American physicist Charles Kittel in 1953. The book has been highly influential and has seen widespread adoption ...
, Charles Kittel, John Wiley and Sons, Inc.
Articles on superconductivity use or interchangeably since superconducting materials often exhibit perfect diamagnetism with susceptibility , resulting in equal magnitudes for and .


Lower critical field

The lower critical field is the magnetic flux density at which the magnetic flux starts to penetrate a type-II superconductor.


References

{{reflist Superconductivity