Coercive Force
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Coercivity, also called the magnetic coercivity, coercive field or coercive force, is a measure of the ability of a
ferromagnetic Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...
material to withstand an external
magnetic field A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
without becoming demagnetized. Coercivity is usually measured in oersted or
ampere The ampere (, ; symbol: A), often shortened to amp,SI supports only the use of symbols and deprecates the use of abbreviations for units. is the unit of electric current in the International System of Units (SI). One ampere is equal to elect ...
/meter units and is denoted . An analogous property in
electrical engineering Electrical engineering is an engineering discipline concerned with the study, design, and application of equipment, devices, and systems which use electricity, electronics, and electromagnetism. It emerged as an identifiable occupation in the l ...
and materials science, electric coercivity, is the ability of a ferroelectric material to withstand an external
electric field An electric field (sometimes E-field) is the physical field that surrounds electrically charged particles and exerts force on all other charged particles in the field, either attracting or repelling them. It also refers to the physical field fo ...
without becoming
depolarized In biology, depolarization or hypopolarization is a change within a cell, during which the cell undergoes a shift in electric charge distribution, resulting in less negative charge inside the cell compared to the outside. Depolarization is esse ...
. Ferromagnetic materials with high coercivity are called magnetically ''hard'', and are used to make
permanent magnet A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nickel, ...
s. Materials with low coercivity are said to be magnetically ''soft''. The latter are used in transformer and inductor cores,
recording head A recording head is the physical interface between a recording apparatus and a moving recording medium. Recording heads are generally classified according to the physical principle that allows them to impress their data upon their medium. A record ...
s, microwave devices, and magnetic shielding.


Definitions

Coercivity in a ferromagnetic material is the intensity of the applied
magnetic field A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
(''H'' field) required to demagnetize that material, after the magnetization of the sample has been driven to saturation by a strong field. This demagnetizing field is applied opposite to the original saturating field. There are however different definitions of coercivity, depending on what counts as 'demagnetized', thus the bare term "coercivity" may be ambiguous: * The ''normal coercivity'', , is the ''H'' field required to reduce the
magnetic flux In physics, specifically electromagnetism, the magnetic flux through a surface is the surface integral of the normal component of the magnetic field B over that surface. It is usually denoted or . The SI unit of magnetic flux is the weber ( ...
(average ''B'' field inside the material) to zero. * The ''intrinsic coercivity'', , is the ''H'' field required to reduce the
magnetization In classical electromagnetism, magnetization is the vector field that expresses the density of permanent or induced magnetic dipole moments in a magnetic material. Movement within this field is described by direction and is either Axial or Di ...
(average ''M'' field inside the material) to zero. * The ''remanence coercivity'', , is the ''H'' field required to reduce the
remanence Remanence or remanent magnetization or residual magnetism is the magnetization left behind in a ferromagnetic material (such as iron) after an external magnetic field is removed. Colloquially, when a magnet is "magnetized", it has remanence. The ...
to zero, meaning that when the ''H'' field is finally returned to zero, then both ''B'' and ''M'' also fall to zero (the material reaches the origin in the hysteresis curve). The distinction between the normal and intrinsic coercivity is negligible in soft magnetic materials, however it can be significant in hard magnetic materials. The strongest
rare-earth magnet Rare-earth magnets are strong permanent magnets made from alloys of rare-earth elements. Developed in the 1970s and 1980s, rare-earth magnets are the strongest type of permanent magnets made, producing significantly stronger magnetic fields than ...
s lose almost none of the magnetization at ''H''Cn.


Experimental determination

Typically the coercivity of a magnetic material is determined by measurement of the magnetic hysteresis loop, also called the ''magnetization curve'', as illustrated in the figure above. The apparatus used to acquire the data is typically a vibrating-sample or alternating-gradient
magnetometer A magnetometer is a device that measures magnetic field or magnetic dipole moment. Different types of magnetometers measure the direction, strength, or relative change of a magnetic field at a particular location. A compass is one such device, o ...
. The applied field where the data line crosses zero is the coercivity. If an antiferromagnet is present in the sample, the coercivities measured in increasing and decreasing fields may be unequal as a result of the
exchange bias Exchange bias or exchange anisotropy occurs in bilayers (or multilayers) of magnetic materials where the hard magnetization behavior of an antiferromagnetic thin film causes a shift in the soft magnetization curve of a ferromagnetic film. The ex ...
effect. The coercivity of a material depends on the time scale over which a magnetization curve is measured. The magnetization of a material measured at an applied reversed field which is nominally smaller than the coercivity may, over a long time scale, slowly relax to zero. Relaxation occurs when reversal of magnetization by domain wall motion is thermally activated and is dominated by
magnetic viscosity Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particle ...
. The increasing value of coercivity at high frequencies is a serious obstacle to the increase of data rates in high- bandwidth magnetic recording, compounded by the fact that increased storage density typically requires a higher coercivity in the media.


Theory

At the coercive field, the vector component of the magnetization of a ferromagnet measured along the applied field direction is zero. There are two primary modes of
magnetization reversal In classical electromagnetism, magnetization is the vector field that expresses the density of permanent or induced magnetic dipole moments in a magnetic material. Movement within this field is described by direction and is either Axial or Dia ...
: single-domain rotation and
domain wall A domain wall is a type of topological soliton that occurs whenever a discrete symmetry is spontaneously broken. Domain walls are also sometimes called kinks in analogy with closely related kink solution of the sine-Gordon model or models with pol ...
motion. When the magnetization of a material reverses by rotation, the magnetization component along the applied field is zero because the vector points in a direction orthogonal to the applied field. When the magnetization reverses by domain wall motion, the net magnetization is small in every vector direction because the moments of all the individual domains sum to zero. Magnetization curves dominated by rotation and magnetocrystalline anisotropy are found in relatively perfect magnetic materials used in fundamental research. Domain wall motion is a more important reversal mechanism in real engineering materials since defects like grain boundaries and
impurities In chemistry and materials science, impurities are chemical substances inside a confined amount of liquid, gas, or solid, which differ from the chemical composition of the material or compound. Firstly, a pure chemical should appear thermodynam ...
serve as
nucleation In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that deter ...
sites for reversed-magnetization domains. The role of domain walls in determining coercivity is complicated since defects may ''pin'' domain walls in addition to nucleating them. The dynamics of domain walls in ferromagnets is similar to that of grain boundaries and
plasticity Plasticity may refer to: Science * Plasticity (physics), in engineering and physics, the propensity of a solid material to undergo permanent deformation under load * Neuroplasticity, in neuroscience, how entire brain structures, and the brain it ...
in
metallurgy Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the sc ...
since both domain walls and grain boundaries are planar defects.


Significance

As with any
hysteretic Hysteresis is the dependence of the state of a system on its history. For example, a magnet may have more than one possible magnetic moment in a given magnetic field, depending on how the field changed in the past. Plots of a single component of ...
process, the area inside the magnetization curve during one cycle represents the work that is performed on the material by the external field in reversing the magnetization, and is dissipated as heat. Common dissipative processes in magnetic materials include magnetostriction and domain wall motion. The coercivity is a measure of the degree of magnetic hysteresis and therefore characterizes the lossiness of soft magnetic materials for their common applications. The saturation remanence and coercivity are figures of merit for hard magnets, although maximum energy product is also commonly quoted. The 1980s saw the development of
rare-earth magnet Rare-earth magnets are strong permanent magnets made from alloys of rare-earth elements. Developed in the 1970s and 1980s, rare-earth magnets are the strongest type of permanent magnets made, producing significantly stronger magnetic fields than ...
s with high energy products but undesirably low Curie temperatures. Since the 1990s new exchange spring hard magnets with high coercivities have been developed.


See also

*
Magnetic susceptibility In electromagnetism, the magnetic susceptibility (Latin: , "receptive"; denoted ) is a measure of how much a material will become magnetized in an applied magnetic field. It is the ratio of magnetization (magnetic moment per unit volume) to the ap ...
*
Remanence Remanence or remanent magnetization or residual magnetism is the magnetization left behind in a ferromagnetic material (such as iron) after an external magnetic field is removed. Colloquially, when a magnet is "magnetized", it has remanence. The ...


References

* * * * *


External links


Magnetization reversal applet (coherent rotation)
*For a table of coercivities of various magnetic recording media, see
Degaussing Data Storage Tape Magnetic Media
(
PDF Portable Document Format (PDF), standardized as ISO 32000, is a file format developed by Adobe in 1992 to present documents, including text formatting and images, in a manner independent of application software, hardware, and operating systems. ...
), at fujifilmusa.com. {{Authority control Physical quantities Magnetic hysteresis