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The Coal Oil Point seep field (COP) in the
Santa Barbara Channel The Santa Barbara Channel is a portion of the Southern California Bight and separates the mainland of California from the northern Channel Islands. It is generally south of the city of Santa Barbara, and west of the Oxnard Plain in Ventura Count ...
offshore from
Goleta, California Goleta (; ; Spanish for "Schooner") is a city in southern Santa Barbara County, California, United States. It was incorporated as a city in 2002, after a long period as the largest unincorporated populated area in the county. As of the 2000 c ...
, is a marine
petroleum seep A petroleum seep is a place where natural liquid or gaseous hydrocarbons escape to the earth's atmosphere and surface, normally under low pressure or flow. Seeps generally occur above either terrestrial or offshore petroleum accumulation stru ...
area of about three square kilometres, within the Offshore South
Ellwood Oil Field Ellwood Oil Field (also spelled "Elwood") and South Ellwood Offshore Oil Field are a pair of adjacent, partially active oil fields adjoining the city of Goleta, California, about west of Santa Barbara, largely in the Santa Barbara Channel. A r ...
and stretching from the coastline southward more than . Major seeps are located in water depths from 20 to 80 meters. The seep field is among the largest and best studied areas of active marine seepage in the world. These perennial and continuous oil and gas seeps have been active on the northern edge of the Santa Barbara Channel for at least 500,000 years. The combined seeps in the field release about 40 tons of
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
per day and about 19 tons of reactive organic gas (
ethane Ethane ( , ) is an organic chemical compound with chemical formula . At standard temperature and pressure, ethane is a colorless, odorless gas. Like many hydrocarbons, ethane is isolated on an industrial scale from natural gas and as a petr ...
,
propane Propane () is a three-carbon alkane with the molecular formula . It is a gas at standard temperature and pressure, but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is commonly used a ...
,
butane Butane () or ''n''-butane is an alkane with the formula C4H10. Butane is a gas at room temperature and atmospheric pressure. Butane is a highly flammable, colorless, easily liquefied gas that quickly vaporizes at room temperature. The name but ...
and higher
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...
s); about twice the hydrocarbon air pollution released by all the cars and trucks in Santa Barbara County in 1990.J. Scott Hornafius, D. Quigley and B, P, Luyendyk, "The world's most spectacular marine hydrocarbon seeps (Coal Oil Point, California): quantification of emissions," ''Journal of Geophysical Research'', v.104, n.C9, 15 September 1999, p.20,709
/ref> The liquid
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
produces a slick that is many kilometres long and when degraded by
evaporation Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidi ...
and
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...
, produces tar balls which wash up on the beaches for miles around.UCSB Hydrocarbon Seeps project
/ref> This seep also releases on the order of of liquid petroleum per day. The field produces about 9 cubic meters of natural gas per barrel of petroleum. Leakage from the natural seeps near Platform Holly, the production platform for the South Ellwood Offshore oilfield, has decreased substantially, probably from the decrease in reservoir pressure due to the oil and gas produced at the platform.


History

Written records, dating from as early as 1792, describe effects of offshore seeps in the Santa Barbara Channel. Oil and tar "slicks" have long been a trademark of the area. In 1792,
Captain Cook James Cook (7 November 1728 Old Style date: 27 October – 14 February 1779) was a British explorer, navigator, cartographer, and captain in the British Royal Navy, famous for his three voyages between 1768 and 1779 in the Pacific Ocean an ...
's navigator
George Vancouver Captain George Vancouver (22 June 1757 – 10 May 1798) was a British Royal Navy officer best known for his 1791–1795 expedition, which explored and charted North America's northwestern Pacific Coast regions, including the coasts of what a ...
recorded on passing through the channel: :The surface of the sea, which was perfectly smooth and tranquil, was covered with a thick, slimy substance, which when separated or disturbed by a little agitation, became very luminous, whilst the light breeze, which came principally from the shore, brought with it a strong smell of tar, or some such resinous substance.US Geological Survey Professional Paper 679, 1969, ''Geology, Petroleum Development, and Seismicity of the Santa Barbara Channel Region, California.''
Full text and maps online
/ref> It had been commonly assumed that the local
Chumash Chumash may refer to: *Chumash (Judaism), a Hebrew word for the Pentateuch, used in Judaism *Chumash people, a Native American people of southern California *Chumashan languages, indigenous languages of California See also * Chumash traditional ...
Native Americans used COP seep oil washed up on the beaches to seal their plank canoes and baskets. However, archaeologists assert that the mainland Chumash in fact used asphalt from nearby onshore seeps in beach cliffs. These seeps must be sourced from a similar subsurface reservoir system, but exposure to oxidation is required to make the material hard and useful. In February 2019, a rare hoodwinker sunfish (''
Mola tecta ''Mola tecta'', the hoodwinker sunfish, belongs to the family Molidae and genus ''Mola (fish), Mola''. It is closely related to the more widely known ocean sunfish (''Mola mola''). The Latin word "tecta" means hidden. The word "hidden" was adopt ...
'') washed ashore on Sands Beach in the Coal Oil Point Reserve.


Scientific Investigations

The location of the COP seep field offshore from the
University of California, Santa Barbara The University of California, Santa Barbara (UC Santa Barbara or UCSB) is a Public university, public Land-grant university, land-grant research university in Santa Barbara County, California, Santa Barbara, California with 23,196 undergraduate ...
(UCSB) has situated it as a natural laboratory for study of the phenomena of oil and gas introduced into the ocean from the sea bed, along with the role of geologic methane from seeps worldwide in the global methane budget. Since the 1990s almost a dozen UCSB researchers along with their graduate students have studied the geology, chemistry, oceanography and ecology of the marine seep system at COP. Many of these studies were in partnership with oil companies including
Mobil Mobil is a petroleum brand owned and operated by American oil and gas corporation ExxonMobil. The brand was formerly owned and operated by an oil and gas corporation of the same name, which itself merged with Exxon to form ExxonMobil in 1999. ...
and
Venoco Venoco, Inc. was a company engaged in hydrocarbon exploration. It primarily operated in the Monterey Formation in California. In 2017, the company filed bankruptcy and was liquidated. History The company was founded in September 1992 by Timothy M ...
, which produced oil from reservoirs below the seeps, and the
U.S. Geological Survey The United States Geological Survey (USGS), formerly simply known as the Geological Survey, is a scientific agency of the United States government. The scientists of the USGS study the landscape of the United States, its natural resources, and ...
and
California State Lands Commission The California State Lands Commission is a unit of state government that is responsible for management and protection of natural and cultural resources, as well as public access rights, on some of California's publicly owned lands. The members of ...
.


Mapping and quantification of discharge

The marine hydrocarbon seep system comprises a seabed source (vent) of oil and gas bubbles coated with oil, that transit the shallow water column while partially dissolving into the ocean. At the surface, various gases are discharged to the atmosphere and the oil volatilizes as it is transported by currents, leaving a tarry residue at the sea surface. At the sea surface the seeps are marked by oil slicks, and in places, bubble froth. Since the 1970s and later, oil slicks from COP and others in the Santa Barbara Channel have been successfully mapped by remote sensing. Because the COP seeps are characterized by large visible gas bubble plumes they can be detected and mapped by sonar backscatter. The first attempts at this were made by Peter Fischer and colleagues of
California State University, Northridge California State University, Northridge (CSUN or Cal State Northridge) is a public university in the Northridge neighborhood of Los Angeles, California. With a total enrollment of 38,551 students (as of Fall 2021), it has the second largest un ...
in the early 1970s. They produced reconnaissance level maps of bubble plumes at COP and at other locations in the
Santa Barbara Channel The Santa Barbara Channel is a portion of the Southern California Bight and separates the mainland of California from the northern Channel Islands. It is generally south of the city of Santa Barbara, and west of the Oxnard Plain in Ventura Count ...
. They noted that because the COP seeps were associated with a producing oil platform then operated by
ARCO ARCO ( ) is a brand of gasoline stations currently owned by Marathon Petroleum after BP sold its rights. BP commercializes the brand in Northern California, Oregon and Washington, while Marathon has rights for the rest of the United States an ...
, continued oil production might result in a decrease in volume of seep discharge. Scott Hornafius and Bruce Luyendyk, along with graduate student Derek Quigley made sonar surveys of the COP field two decades later using 50 kHz sonar and 3.5 kHz sonar equipment that matched that used by Fischer and colleagues. They calibrated the sonar data with seafloor artificial sources to estimate the volume of gas discharge cited above. Using an estimate of the gas/oil ratio along with capture of oil with a floating boom, they also estimated the volume of oil discharge (above). Comparing the surveys made in the mid 1990s with the early 1970s data of Fischer and colleagues they determined that seepage near the producing platform Holly had decreased by half. This observation was supported by gas capture data recorded by two sea floor tent structures that covered one large seepage area. Surveys continued over the 1990s and 2000s using more sophisticated sonars including
chirp A chirp is a signal in which the frequency increases (''up-chirp'') or decreases (''down-chirp'') with time. In some sources, the term ''chirp'' is used interchangeably with sweep signal. It is commonly applied to sonar, radar, and laser system ...
and multibeam sonars. These repeat sonar surveys did not detect further decrease in seepage, while during the same period oil production continued.


See also

*
Refugio oil spill The Refugio oil spill on May 19, 2015, deposited of crude oil onto one of the most biologically diverse areas of the West Coast of the United States. The corroded pipeline blamed for the spill closed indefinitely, resulting in financial impac ...
*
University of California Natural Reserve System The University of California Natural Reserve System (UCNRS) is a system of protected areas throughout California California is a U.S. state, state in the Western United States, located along the West Coast of the United States, Pacific Co ...
*
Bruce P. Luyendyk Bruce Peter Luyendyk (born 1943 in Freeport, New York) is an American geophysicist and oceanographer, currently professor emeritus of marine geophysics at the University of California, Santa Barbara. His work spans marine geology of the major oc ...
* Tessa M. Hill


References


Further reading

*


External links


UCSB Hydrocarbon Seeps
– University of California Santa Barbara
Bathymetry of Groundhog Reservoir, Dolores County, Colorado, 2011
United States Geological Survey The United States Geological Survey (USGS), formerly simply known as the Geological Survey, is a scientific agency of the United States government. The scientists of the USGS study the landscape of the United States, its natural resources, ...
{{Coord, 34, 24, 0, N, 119, 53, 0, W, display=title Petroleum geology Geography of Santa Barbara County, California Santa Barbara, California Nature reserves in California Ocean pollution Oil fields in Santa Barbara County, California