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The Cleveland Shale, also referred to as the Cleveland Member, is a
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
geologic formation A geological formation, or simply formation, is a body of rock having a consistent set of physical characteristics ( lithology) that distinguishes it from adjacent bodies of rock, and which occupies a particular position in the layers of rock exp ...
in the eastern United States.


Identification and name

The Cleveland Shale was identified in 1870 and named for the city of
Cleveland Cleveland ( ), officially the City of Cleveland, is a city in the U.S. state of Ohio and the county seat of Cuyahoga County. Located in the northeastern part of the state, it is situated along the southern shore of Lake Erie, across the U.S. ...
,
Ohio Ohio () is a state in the Midwestern region of the United States. Of the fifty U.S. states, it is the 34th-largest by area, and with a population of nearly 11.8 million, is the seventh-most populous and tenth-most densely populated. The sta ...
.
John Strong Newberry John Strong Newberry (December 22, 1822 – December 7, 1892) was an American physician, geologist and paleontologist. He participated as a naturalist and surgeon on three expeditions to explore and survey the western United States. During the C ...
, director of the Ohio State Geological Survey, first identified the formation in 1870. He called it the "Cleveland Shale" and designated its type locality at Doan Brook near Cleveland. Details of the type locality and of stratigraphic nomenclature for this unit as used by the U.S. Geological Survey are available on-line at the National Geologic Map Database.


Description

The primary minerals in the Cleveland Shale are
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous ac ...
,
illite Illite is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina ...
,
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...
, and
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
. Underground, the Cleveland Shale is black, dull grayish-black, bluish-black, or brownish-black in color. In exposed outcrops, it weathers to red, reddish-brown, or medium brown. Highly weathered rock turns gray. It is fairly
fissile In nuclear engineering, fissile material is material capable of sustaining a nuclear fission chain reaction. By definition, fissile material can sustain a chain reaction with neutrons of thermal energy. The predominant neutron energy may be typ ...
, breaking into thin, irregularly shaped sheets or flakes that occasionally display crystals of
pickeringite Pickeringite is a magnesium aluminium sulfate mineral with formula MgAl2(SO4)4·22(H2O). It forms a series with halotrichite. It forms as an alteration product of pyrite in aluminium rich rocks and in coal seams. It also occurs in pyrite rich hyd ...
. Relieved of stress once exposed, the Cleveland Shale is nonplastic and can appear as if fragmented into blocks due to jointing.


Pyrite basal boundary

There is a sharp and clear distinction between the Cleveland Shale and underlying
Chagrin Shale The Chagrin Shale is a shale geologic formation in the eastern United States that is approximately 365 million years old. The Chagrin Shale is a gray shale that begins thin and deep underground in north-central Ohio. As it proceeds east, the for ...
. At the very bottom of the Cleveland Shale there is a thin, discontinuous layer of
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...
. This pyrite layer is discontinuous because after this rock was laid down, it was eroded. The erosion increases as one moves south along the valley of the
Cuyahoga River The Cuyahoga River ( , or ) is a river located in Northeast Ohio that bisects the City of Cleveland and feeds into Lake Erie. As Cleveland emerged as a major manufacturing center, the river became heavily affected by industrial pollution, so mu ...
and east to the Grand River. Portions of the pyrite layer, known as Skinner's Run Bed, contain fragments of
petrified wood Petrified wood, also known as petrified tree (from Ancient Greek meaning 'rock' or 'stone'; literally 'wood turned into stone'), is the name given to a special type of ''fossilized wood'', the fossilized remains of terrestrial vegetation. ''P ...
and fossilized fish bones worn smooth by the action of water. Above the pyrite layer, a
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
layer is found in west-central (but not eastern) Ohio. The remainder of the Cleveland Shale generally consists of a relatively hard, organic rich
oil shale Oil shale is an organic-rich fine-grained sedimentary rock containing kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons can be produced. In addition to kerogen, general composition of oil shales constitute ...
. It has both an upper and lower part.


Lower part

A clay shale, described as bluish or bluish-gray and as olive-black to brownish-black, forms the lower part. The lower part can be anywhere from a few inches to several feet in thickness. This layer is sometimes referred to as the Olmstead shale. This layer has been dated to between 362.6 and 361.0 million years old based on conodont biozones (Bispathodus aculeatus aculeatus to Bispathodus ultimus ultimus zones). Thin beds of gray or brown
siltstone Siltstone, also known as aleurolite, is a clastic sedimentary rock that is composed mostly of silt. It is a form of mudrock with a low clay mineral content, which can be distinguished from shale by its lack of fissility.Blatt ''et al.'' 1980, p ...
, lumps of pyrite, and layers of
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
-heavy limestone with cone-in-cone structures are found in the lower part. In eastern Ohio, thin gray veins ("stringers") of siltstone appear. In western Ohio, the Cleveland Shale appears to interbed with the Chagrin Shale below it, erasing the clear boundary between the two rock formations.


Upper part

The upper part of the Cleveland Shale is a black to brownish black silty shale with occasional thin beds of gray shale and siltstone. The upper part is much richer in petroleum and
kerogen Kerogen is solid, insoluble organic matter in sedimentary rocks. Comprising an estimated 1016 tons of carbon, it is the most abundant source of organic compounds on earth, exceeding the total organic content of living matter 10,000-fold. It ...
. When broken open, fresh samples smell like crude oil. Where the upper part is thick, and particularly in northeast Ohio, the shale has a distinctive "rippled" appearance. The upper of the Cleveland Shale contains abundant nodules of
phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phospho ...
, nodules and bands (extremely thin beds) of pyrite, bands of
calcisiltite Calcisiltite is a type of limestone that is composed predominantly, more than 50 percent, of detrital (transported) silt-size carbonate grains. These grains consist either of the silt-size particles of ooids, fragments of fossil shells, fragments of ...
, and
lamination Lamination is the technique/process of manufacturing a material in multiple layers, so that the composite material achieves improved strength, stability, sound insulation, appearance, or other properties from the use of the differing materials ...
. Almost no
concretion A concretion is a hard, compact mass of matter formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular ...
s are found in the upper part.


Geographic extent

The Cleveland Shale is a
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
geologic formation A geological formation, or simply formation, is a body of rock having a consistent set of physical characteristics ( lithology) that distinguishes it from adjacent bodies of rock, and which occupies a particular position in the layers of rock exp ...
in
Ohio Ohio () is a state in the Midwestern region of the United States. Of the fifty U.S. states, it is the 34th-largest by area, and with a population of nearly 11.8 million, is the seventh-most populous and tenth-most densely populated. The sta ...
in the United States. The Cleveland Shale underlies much of northeast Ohio in beds of varying thickness. In northeast Ohio, the member does not appear east of the Grand River. Measurements taken in northeast Ohio show the Cleveland Shale to be to thick. It is thickest around the Rocky River north of
Berea, Ohio Berea ( ) is a city in Cuyahoga County in the U.S. state of Ohio and is a western suburb of Cleveland. The population was 19,093 at the 2010 census. Berea is home to Baldwin Wallace University, as well as the training facility for the Cleveland ...
, and thins to the east, west, and south. The Cleveland Shale is found in east-central
Kentucky Kentucky ( , ), officially the Commonwealth of Kentucky, is a state in the Southeastern region of the United States and one of the states of the Upper South. It borders Illinois, Indiana, and Ohio to the north; West Virginia and Virginia to ...
. In east-central Kentucky, the Cleveland Shale is more uniform in thickness, ranging from , and increases in thickness toward the east. The unit is also present in West Virginia and in southwest Virginia, where it is mapped as the Cleveland Member of the Ohio Shale.


Stratigraphic Setting

The Cleveland Shale (or Cleveland Member) is a sub-unit of the Ohio Shale Formation. The
Chagrin Shale The Chagrin Shale is a shale geologic formation in the eastern United States that is approximately 365 million years old. The Chagrin Shale is a gray shale that begins thin and deep underground in north-central Ohio. As it proceeds east, the for ...
underlies the Cleveland Shale. The
Bedford Shale The Bedford Shale is a shale geologic formation in the states of Ohio, Michigan, Pennsylvania, Kentucky, West Virginia, and Virginia in the United States. Identification and name John Strong Newberry, director of the Ohio State Geological Sur ...
generally overlies the Cleveland Shale, with a sharp distinction between the two. In west-central Ohio, more than of Bedford Shale may lie above the Cleveland Shale. In places, red and grey shale may intertongue (interlock) with the Cleveland Shale extensively. In far eastern Ohio, the Bedford Shale thins by more than . Where the Cussewago Shale is also present, the Bedford Shale is usually less than and may be locally absent. In some areas, the Cleveland Shale is described as
overstep An overstep is a geological form that has a deposition of a stratum across inclined, progressively older rocks.Alistair F. Pitty ''Structure and Relief'' 1985 Page 28 "An overstep is a geological term describing the deposition of a stratum across ...
ped or
unconformably An unconformity is a buried erosional or non-depositional surface separating two rock masses or strata of different ages, indicating that sediment deposition was not continuous. In general, the older layer was exposed to erosion for an interval ...
overlaid gradationally by Berea Siltstone and sharply by Berea Sandstone. It is the regional equivalent of the Hangenberg Black Shale and the
Bakken Shale The Bakken Formation () is a rock unit from the Late Devonian to Early Mississippian age occupying about of the subsurface of the Williston Basin, underlying parts of Montana, North Dakota, Saskatchewan and Manitoba. The formation was initi ...
.


Fossils

Exceptional marine animal
fossil A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
s are found in the formation. The Cleveland Shale is generally considered to be fossil-poor, but there are exceptions. The basal pyrite layer contains petrified wood and fossilized fish bones. The lower part is famous for its extensive and well-preserved fossil
Chondrichthyans Chondrichthyes (; ) is a class that contains the cartilaginous fishes that have skeletons primarily composed of cartilage. They can be contrasted with the Osteichthyes or ''bony fishes'', which have skeletons primarily composed of bone tissue. C ...
(including ''
Cladoselache ''Cladoselache'' is an extinct genus of shark-like chondrichthyan (cartilaginous fish) from the Late Devonian (Famennian) of North America. It was similar in body shape to modern lamnid sharks (such as mako sharks and the great white shark), bu ...
''),
Conodont Conodonts (Greek ''kōnos'', "cone", + ''odont'', "tooth") are an extinct group of agnathan (jawless) vertebrates resembling eels, classified in the class Conodonta. For many years, they were known only from their tooth-like oral elements, which ...
s,
Placodermi Placodermi (from Greek πλάξ 'plate' and δέρμα 'skin', literally 'Plate (animal anatomy), plate-skinned') is a Class (biology), class of armoured prehistoric fish, known from fossils, which lived from the Silurian to the end of the Devoni ...
, and palaeoniscinoids
ray-finned fishes Actinopterygii (; ), members of which are known as ray-finned fishes, is a class of bony fish. They comprise over 50% of living vertebrate species. The ray-finned fishes are so called because their fins are webs of skin supported by bony or hor ...
. The giant predatory placoderms ''Dunkleosteus terrelli'', '' Gorgonichthys clarki'', '' Gymnotrachelus hydei'', '' Heintzichthys gouldii'', and five subspecies (including the type specimen) of ''
Titanichthys ''Titanichthys'' is an extinct genus of giant, aberrant marine placoderm from shallow seas of the Late Devonian of Morocco, Eastern North America, and possibly Europe. Many of the species approached ''Dunkleosteus'' in size and build. Unlike ...
'' were all discovered in the Cleveland Shale. The Cleveland Shale is classified as a konservatte-lagerstatten, which means it often preserves complete body fossils. Typical early shark preservation includes soft tissue outlines and impressions, fin rays, gill musculature, cartilage, and stomach contents. Placoderms in the Cleveland Shale typically do not show any good soft-tissue preservation. Faunal list follows Carr and Jackson (2008) and Carr 2018


Placodermi


Chondrichthyes


Osteichthyans


Age

The Cleveland Shale is approximately 362.6 to 360.1 million years old, daing to the very latest part of the
Devonian The Devonian ( ) is a geologic period and system of the Paleozoic era, spanning 60.3 million years from the end of the Silurian, million years ago (Mya), to the beginning of the Carboniferous, Mya. It is named after Devon, England, whe ...
period, the Fammenian, based on biostratigraphy from conodonts and plant spores. The Cleveland Shale extends all the way to the Hangenberg mass extinction that ended the Devonian but does not reach the very end of the Devonian period. Unlike the Permian-Triassic extinction and Cretaceous-Paleogene extinction the Devonian-Carboniferous boundary does not correlate with the mass extinction event at the end of this period. The
Bedford Shale The Bedford Shale is a shale geologic formation in the states of Ohio, Michigan, Pennsylvania, Kentucky, West Virginia, and Virginia in the United States. Identification and name John Strong Newberry, director of the Ohio State Geological Sur ...
and Berea Sandstone represent Devonian layers that post-date the Devonian-Carboniferous extinction but were deposited on top of the Cleveland Shale, and encompass some of the recovery fauna otherwise typical of the Carboniferous in the aftermath of the
Hangenberg Event The Hangenberg event, also known as the Hangenberg crisis or end-Devonian extinction, is a mass extinction that occurred at the end of the Famennian stage, the last stage in the Devonian Period (roughly 358.9 ± 0.4 million years ago). It is usuall ...
. The upper 2.5 m of the Cleveland Shale has been chemostratigraphically correlated with the
Hangenberg Event The Hangenberg event, also known as the Hangenberg crisis or end-Devonian extinction, is a mass extinction that occurred at the end of the Famennian stage, the last stage in the Devonian Period (roughly 358.9 ± 0.4 million years ago). It is usuall ...
and the type stratigraphy in Germany, suggesting that the Cleveland Shale preserves the second of the two mass extinction events that together comprise the
late Devonian extinction The Late Devonian extinction consisted of several extinction events in the Late Devonian Epoch, which collectively represent one of the five largest mass extinction events in the history of life on Earth. The term primarily refers to a major exti ...


Interpretation of depositional environments

The Cleveland Shale is likely the regional expression of the Dasberg event, a major extinction event that occurred near the end of the
Devonian The Devonian ( ) is a geologic period and system of the Paleozoic era, spanning 60.3 million years from the end of the Silurian, million years ago (Mya), to the beginning of the Carboniferous, Mya. It is named after Devon, England, whe ...
period Period may refer to: Common uses * Era, a length or span of time * Full stop (or period), a punctuation mark Arts, entertainment, and media * Period (music), a concept in musical composition * Periodic sentence (or rhetorical period), a concept ...
. The Cleveland Shale is interpreted as having accumulated in an
anaerobic environment Hypoxia refers to low oxygen conditions. Normally, 20.9% of the gas in the atmosphere is oxygen. The partial pressure of oxygen in the atmosphere is 20.9% of the total barometric pressure. In water, oxygen levels are much lower, approximately 7 p ...
. Evidence exists to suggest that the Cleveland Shale was laid down during the Dasberg event, an Upper Famennian extinction event that devastated land-based flora and marine-based fauna. This led to a significant drop in marine oxygen (an
anoxic event Oceanic anoxic events or anoxic events ( anoxia conditions) describe periods wherein large expanses of Earth's oceans were depleted of dissolved oxygen (O2), creating toxic, euxinic (anoxic and sulfidic) waters. Although anoxic events have not ...
) and atmospheric carbon dioxide, and then a brief
glaciation A glacial period (alternatively glacial or glaciation) is an interval of time (thousands of years) within an ice age that is marked by colder temperatures and glacier advances. Interglacials, on the other hand, are periods of warmer climate betw ...
. The global environment recovered, only to suffer another extinction, the
Hangenberg event The Hangenberg event, also known as the Hangenberg crisis or end-Devonian extinction, is a mass extinction that occurred at the end of the Famennian stage, the last stage in the Devonian Period (roughly 358.9 ± 0.4 million years ago). It is usuall ...
, close to the Devonian-
Carboniferous The Carboniferous ( ) is a geologic period and system of the Paleozoic that spans 60 million years from the end of the Devonian Period million years ago ( Mya), to the beginning of the Permian Period, million years ago. The name ''Carbonifero ...
boundary. While the Cleveland Shale was being deposited, extensive organic matter from the land was swept into the sea then lying over Ohio. Although there is dispute over how deep this sea was, the Dasberg event meant that oceans could support few to no bottom-dwelling animals. This explains why the Cleveland Shale largely lacks fossils of benthic organisms and has a high carbon content that colors the shale very dark gray to black. The contact between the Chagrin Shale and Cleveland Shale has been described as
interbedding In geology, interbedding occurs when beds (layers of rock) of a particular lithology lie between or alternate with beds of a different lithology. For example, sedimentary rocks may be interbedded if there were sea level variations in their sedimen ...
. This feature is interpreted as having been caused when two different depositional environments (in this case, the oxygenated sea which laid down the Chagrin Shale and the anaerobic sea rich in organic matter which laid down the Cleveland Shale) moved repeatedly back and forth over the same area. Geologist Horace R. Collins called the boundary area intercalated, but it is unclear what meaning he intended. Different hypotheses have been suggested as the cause of the regional, irregular contact between the Cleveland Shale and Bedford Formation. Charles E.B. Conybeare has noted that the Cleveland Shale is siltier in the east and more
calcareous Calcareous () is an adjective meaning "mostly or partly composed of calcium carbonate", in other words, containing lime or being chalky. The term is used in a wide variety of scientific disciplines. In zoology ''Calcareous'' is used as an adje ...
in the west. He hypothesized that this indicates that silt flowed into the sea from east to west. Current eroded the Cleveland Shale and then laid down new sediment in the gullies which became the Bedford Formation. Jack C. Pashin and Frank R. Ettensohn proposed a variation on this hypothesis. They note that the region containing the Cleveland Shale was undergoing uplift when the Bedford Formation was being deposited. This likely led to exposure and erosion of the Cleveland Shale, with sediment which became the Bedford Formation filling in these
gullies A gully is a landform created by running water, mass movement, or commonly a combination of both eroding sharply into soil or other relatively erodible material, typically on a hillside or in river floodplains or terraces. Gullies resemble lar ...
. They also observe that there is evidence of
diapir A diapir (; , ) is a type of igneous intrusion in which a more mobile and ductily deformable material is forced into brittle overlying rocks. Depending on the tectonic environment, diapirs can range from idealized mushroom-shaped Rayleigh–T ...
ism (the intrusion of deformable Cleveland Shale upward into the more brittle Bedford Formation), as well as intertonguing. Baird et al. note that the Cleveland Shale also tilts downward to the south. They suggest that this caused overstepping, rather than intertonguing.


Economic geology

The high organic content of the Cleveland Shale makes it eminently suitable for the formation of fossil fuels. One 1981 study found that the Cleveland Shale can yield an average of of
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
per of rock. The Cleveland Shale also contains
cannel coal Cannel coal or candle coal is a type of bituminous coal, also classified as terrestrial type oil shale. Hutton(1987) Dyni (2006), pp. 3–4 Speight (2012), pp. 6–7 Due to its physical morphology and low mineral content cannel coal is considered ...
and "true"
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dea ...
, although neither in great quantity.


See also

*
List of fossiliferous stratigraphic units in Ohio This article contains a list of fossil-bearing stratigraphic units in the state of Ohio, U.S. Sites See also * Paleontology in Ohio References * {{DEFAULTSORT:Fossiliferous stratigraphic units in Ohio Ohio Ohio () is a U.S. stat ...
*
Marcellus Formation The Marcellus Formation or the Marcellus Shale is a Middle Devonian age unit of sedimentary rock found in eastern North America. Named for a distinctive outcrop near the village of Marcellus, New York, in the United States, it extends throughou ...
* Escuminac Formation *
Floresta Formation The Floresta Formation ( es, Formación Floresta, Df) is a geological formation of the Altiplano Cundiboyacense in the Eastern Ranges of the Colombian Andes. The sequence of siltstones, shales, coquinas and sandstone beds dates to the Devonia ...
*
Hunsrück Slate The Hunsrück () is a long, triangular, pronounced upland in Rhineland-Palatinate, Germany. It is bounded by the valleys of the Moselle-Saar (north-to-west), the Nahe (south), and the Rhine (east). It is continued by the Taunus mountains, past ...
*
Rhynie Chert The Rhynie chert is a Lower Devonian sedimentary deposit exhibiting extraordinary fossil detail or completeness (a Lagerstätte). It is exposed near the village of Rhynie, Aberdeenshire, Scotland; a second unit, the Windyfield chert, is located ...
*
Gogo Formation The Gogo Formation in the Kimberley region of Western Australia is a Lagerstätte that exhibits exceptional preservation of a Devonian reef community. The formation is named after Gogo Station, a cattle station where outcrops appear and fossils ...
*
Late Devonian extinction event The Late Devonian extinction consisted of several extinction events in the Late Devonian Epoch, which collectively represent one of the five largest mass extinction events in the history of life on Earth. The term primarily refers to a major ex ...


References

;Notes ;Citations


Bibliography

* * * * * * * * * * * * * * * * * * * {{Chronostratigraphy of Kentucky Geologic formations of Ohio Geologic formations of Kentucky Devonian System of North America Famennian Stage Devonian Ohio Devonian Kentucky Shale formations of the United States Open marine deposits Source rock formations Formations Devonian southern paleotemperate deposits Lagerstätten Fossiliferous stratigraphic units of North America Paleontology in Ohio